Redox flow batteries having multiple electroactive elements
Abstract
Introducing multiple redox reactions with a suitable voltage range can improve the energy density of redox flow battery (RFB) systems. One example includes RFB systems utilizing multiple redox pairs in the positive half cell, the negative half cell, or in both. Such RFB systems can have a negative electrolyte, a positive electrolyte, and a membrane between the negative electrolyte and the positive electrolyte, in which at least two electrochemically active elements exist in the negative electrolyte, the positive electrolyte, or both.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1437259
- Patent Number(s):
- 9960443
- Application Number:
- 13/246,444
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2011 Sep 27
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE
Citation Formats
Wang, Wei, Li, Liyu, Yang, Zhenguo, and Nie, Zimin. Redox flow batteries having multiple electroactive elements. United States: N. p., 2018.
Web.
Wang, Wei, Li, Liyu, Yang, Zhenguo, & Nie, Zimin. Redox flow batteries having multiple electroactive elements. United States.
Wang, Wei, Li, Liyu, Yang, Zhenguo, and Nie, Zimin. Tue .
"Redox flow batteries having multiple electroactive elements". United States. https://www.osti.gov/servlets/purl/1437259.
@article{osti_1437259,
title = {Redox flow batteries having multiple electroactive elements},
author = {Wang, Wei and Li, Liyu and Yang, Zhenguo and Nie, Zimin},
abstractNote = {Introducing multiple redox reactions with a suitable voltage range can improve the energy density of redox flow battery (RFB) systems. One example includes RFB systems utilizing multiple redox pairs in the positive half cell, the negative half cell, or in both. Such RFB systems can have a negative electrolyte, a positive electrolyte, and a membrane between the negative electrolyte and the positive electrolyte, in which at least two electrochemically active elements exist in the negative electrolyte, the positive electrolyte, or both.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {5}
}
Works referenced in this record:
Novel Vanadium Halide Redox Flow Battery
patent-application, November 2010
- Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholas
- US Patent Document 12/843521; 20100291420
Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries
journal, June 2011
- Zhang, Jianlu; Li, Liyu; Nie, Zimin
- Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1215-1221
Redox flow batteries based on supporting solutions containing chloride
patent, September 2015
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Document 9,123,931
Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries
patent, May 2003
- Kazacos, Maria Skyllas; Kazacos, Michael
- US Patent Document 6,562,514
Redox Flow Batteries Based on Supporting Solutions Containing Chloride
patent-application, August 2014
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Document 14/261262; 20140234753
Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method
patent, March 2005
- Tanaka, Yasuyuki; Mita, Muneo; Horikawa, Ken
- US Patent Document 6,872,376
Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries
patent-application, November 2008
- Kazacos, George Christopher; Kazacos, Nicholas Michael
- US Patent Document 11/917989; 20080292964
System Dongle
patent-application, February 2012
- Parakulam, Gopalakrishnan R.
- US Patent Document 12/855059; 20120040216
A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage
journal, March 2011
- Li, Liyu; Kim, Soowhan; Wang, Wei
- Advanced Energy Materials, Vol. 1, Issue 3, p. 394-400
Flow Battery Systems
patent-application, March 2012
- Wilson, Gregory J.; Hanson, Kyle M.
- US Patent Document 12/868489; 20120052347
Electrically rechargeable REDOX flow cell
patent, December 1976
- Thaller, Lawrence H.
- US Patent Document 3,996,064
Novel vanadium chloride/polyhalide redox flow battery
journal, October 2003
- Skyllas-Kazacos, Maria
- Journal of Power Sources, Vol. 124, Issue 1, p. 299-302
Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method
patent, September 1984
- Giner, Jose D.; Stark, Herbert
- US Patent Document 4,469,760
Novel vanadium halide redox flow battery
patent-application, August 2006
- Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholasl
- US Patent Document 10/548555; 20060183016
Metal halide redox flow battery
patent-application, November 2005
- Skyllas-Kazacos, Maria; Kazacos, Michael; Mousa, Asem
- US Patent Document 10/512417; 20050244707
Electrolyte for Redox Flow Battery and Redox Flow Battery
patent-application, August 2015
- Sekine, Ryojun; Dong, Yongrong; Kubata, Michiru
- US Patent Document 14/422792; 20150221969
Redox Flow Battery Based on Supporting Solutions Containing Chloride
patent, December 2015
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Document 14/815037; 20150380757
All-vanadium redox battery
patent, November 1988
- Skyllas-Kazacos, Maria; Rychick, Miron; Robins, Robert R.
- US Patent Document 4,786,567
Investigation of the V(V)/V(IV) system for use in the positive half-cell of a redox battery
journal, October 1985
- Sum, E.; Rychcik, M.; Skyllas-kazacos, M.
- Journal of Power Sources, Vol. 16, Issue 2, p. 85-95
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
patent-application, July 2003
- Kazacos, Michael; Kazacos, Maria Skyllas
- US Patent Document 10/226751; 20030143456
Redox Flow Battery System for Distributed Energy Storage
patent-application, February 2011
- Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.
- US Patent Document 12/883511; 20110045332
Method for Storing Electrical Energy in Ionic Liquids
patent-application, May 2012
- Noack, Jens; Tubke, Jens; Pinkwart, Karsten
- US Patent Application 13/201813; 20120115069
Fe-V redox flow batteries
patent, July 2014
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Document 8,771,856
Vanadium/polyhalide redox flow battery
patent, January 2008
- Skyllas-Kazacos, Maria
- US Patent Document 7,320,844
Instrumented fluid-surfaced electrode
patent-application, February 2011
- Deane, Geoffrey F.; Ferren, Bran; Gates, William
- US Patent Document 12/803122; 20110027629
Redox Flow Batteries Based On Supporting Solutions Containing Chloride
patent-application, July 2014
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Application 14/105823; 20140199607
Redox flow batteries based on supporting solutions containing chloride
patent, January 2014
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Document 8,628,880
Redox Flow Cell Rebalancing
patent-application, April 2011
- Keshavarz, Majid; Karuppaiah, Chockkalingam; Zu, Ge
- US Patent Document 12/790573; 20110086247
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
patent, July 2006
- Kazacos, Michael; Kazacos, Maria Skyllas
- US Patent Document 7,078,123
A study of the V(II)/V(III) redox couple for redox flow cell applications
journal, June 1985
- Sum, E.; Skyllas-Kazacos, M.
- Journal of Power Sources, Vol. 15, Issue 2-3, p. 179-190
Electrolytes for redox flow batteries
patent, March 1989
- Nagashima, Ikuo; Fukui, Jun; Gotoh, Hidenori
- US Patent Document 4,814,241
Redox flow batteries based on supporting solutions containing chloride
patent, July 2015
- Li, Liyu; Kim, Soowhan; Yang, Zhenguo
- US Patent Document 9,077,011
Progress in Flow Battery Research and Development
journal, June 2011
- Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A.
- Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79