Electrolyte for stable cycling of high-energy lithium sulfur redox flow batteries
Abstract
A device comprising: a lithium sulfur redox flow battery comprising an electrolyte composition comprising: (i) a dissolved Li2Sx electroactive salt, wherein x.gtoreq.4; (ii) a solvent selected from dimethyl sulfoxide, tetrahydrofuran, or a mixture thereof; and (iii) a supporting salt at a concentration of at least 2 M, as measured by moles of supporting salt divided by the volume of the solvent without considering the volume change of the electrolyte after dissolving the supporting salt.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1436179
- Patent Number(s):
- 9954229
- Application Number:
- 14/530,442
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Oct 31
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Xiao, Jie, Liu, Jun, Pan, Huilin, and Henderson, Wesley A. Electrolyte for stable cycling of high-energy lithium sulfur redox flow batteries. United States: N. p., 2018.
Web.
Xiao, Jie, Liu, Jun, Pan, Huilin, & Henderson, Wesley A. Electrolyte for stable cycling of high-energy lithium sulfur redox flow batteries. United States.
Xiao, Jie, Liu, Jun, Pan, Huilin, and Henderson, Wesley A. Tue .
"Electrolyte for stable cycling of high-energy lithium sulfur redox flow batteries". United States. https://www.osti.gov/servlets/purl/1436179.
@article{osti_1436179,
title = {Electrolyte for stable cycling of high-energy lithium sulfur redox flow batteries},
author = {Xiao, Jie and Liu, Jun and Pan, Huilin and Henderson, Wesley A.},
abstractNote = {A device comprising: a lithium sulfur redox flow battery comprising an electrolyte composition comprising: (i) a dissolved Li2Sx electroactive salt, wherein x.gtoreq.4; (ii) a solvent selected from dimethyl sulfoxide, tetrahydrofuran, or a mixture thereof; and (iii) a supporting salt at a concentration of at least 2 M, as measured by moles of supporting salt divided by the volume of the solvent without considering the volume change of the electrolyte after dissolving the supporting salt.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 24 00:00:00 EDT 2018},
month = {Tue Apr 24 00:00:00 EDT 2018}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Organic Non-Aqueous Cation-Based Redox Flow Batteries
patent-application, August 2013
- Jansen, Andrew N.; Vaughey, John T.; Chen, Zonghai
- US Patent Application 13/407409; 20130224538
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010
- Verma, Pallavi; Maire, Pascal; Novák, Petr
- Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341
Lithium Secondary Batteries Containing Lithium Salt-ionic Liquid Solvent Electrolyte
patent-application, November 2014
- He, Hui; Jang, Bor Z.; Wang, Yanbo
- US Patent Application 13/986576; 20140342249
Manipulating surface reactions in lithium–sulphur batteries using hybrid anode structures
journal, January 2014
- Huang, Cheng; Xiao, Jie; Shao, Yuyan
- Nature Communications, Vol. 5, Issue 1, Article No. 3015
Melt-Blown Nonwoven, and Production Process and Apparatus for the Same
patent-application, October 2013
- Matsubara, Akio; Kajiyama, Shingo; Suzuki, Kenichi
- US Patent Application 13/991863; 20130266874
Positive Electrode for Lithium Batteries, Lithium Battery Including the Positive Electrode and Methods of Manufacture Thereof
patent-application, December 2014
- Choi, Won-sung; Im, Dong-min; Roev, Victor
- US Patent Application 14/248531; 20140356736
High energy density battery with dioxolane based electrolyte
patent, January 1978
- Garth, Bruce Hollis
- US Patent Document 4,071,665
Lithium-Based High Energy Density Flow Batteries
patent-application, August 2013
- Bugga, Ratnakumar V.; West, William C.; Kindler, Andrew
- US Patent Application 13/779435; 20130224550
Lithium secondary batteries containing non-flammable quasi-solid electrolyte
patent-application, December 2014
- He, Hui; Jang, Bor Z.; Wang, Yanbo
- US Patent Application 13/986814; 20140363746
On the Electrode Potentials in Lithium-Sulfur Batteries and Their Solvent-Dependence
journal, January 2014
- Schneider, H.; Gollub, C.; Weiss, T.
- Journal of the Electrochemical Society, Vol. 161, Issue 9, p. A1399-A1406
Sacrificial Anion Reduction Mechanism for Electrochemical Stability Improvement in Highly Concentrated Li-Salt Electrolyte
journal, June 2014
- Sodeyama, Keitaro; Yamada, Yuki; Aikawa, Koharu
- The Journal of Physical Chemistry C, Vol. 118, Issue 26, p. 14091-14097
General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes
journal, March 2014
- Yamada, Yuki; Usui, Kenji; Chiang, Ching Hua
- ACS Applied Materials & Interfaces, Vol. 6, Issue 14, p. 10892-10899
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy
journal, January 2013
- Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P.
- The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267
Process for producing non-flammable quasi-solid electrolyte and electrolyte-separator for lithium battery applications
patent-application, January 2015
- He, Hui; Jang, Bor Z.; Wang, Yanbo
- US Patent Application 13/987396; 20150024121
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries
journal, March 2014
- Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro
- Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046
Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate
journal, September 2002
- Xu, Kang; Zhang, Shengshui; Poese, Bruce A.
- Electrochemical and Solid-State Letters, Vol. 5, Issue 11, p. A259-A262
Performance Improvement of Li Ion Battery with Non-Flammable TMP Mixed Electrolyte by Optimization of Lithium Salt Concentration and SEI Preformation Technique on Graphite Anode
journal, January 2014
- Matsumoto, K.; Nakahara, K.; Inoue, K.
- Journal of the Electrochemical Society, Vol. 161, Issue 5, p. A831-A834
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
journal, June 2013
- Zhang, Sheng S.
- Journal of Power Sources, Vol. 231, p. 153-162
Erratum: Corrigendum: Manipulating surface reactions in lithium–sulphur batteries using hybrid anode structures
journal, February 2014
- Huang, Cheng; Xiao, Jie; Shao, Yuyan
- Nature Communications, Vol. 5, Issue 1
Low temperature lithium/sulfur secondary battery. Annual progress report, December 1, 1974--December 1, 1975. [Ambient-temperature battery with dissolved S]
report, April 1976
- Brummer, S. B.; Rauh, R. D; Marston, J. M.
- COO-2520-2
High Energy Density Redox Flow Device
patent-application, August 2011
- Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan
- US Patent Application 12/970753; 20110200848
Dynamic Formation Protocol for Lithium-Ion Battery
patent-application, March 2015
- Xu, Jeff Qiang
- US Patent Application 14/015249; 20150060290
Porous Electrode with Improved Conductivity
patent-application, January 2013
- Chang, On Kok; Kinoshita, Kimio; Mosso, Ronald James
- US Patent Application 13/349234; 20130022852
Cathode Active Material, Cathode Including The Cathode Active Material, And Sodium Secondary Battery Including The Cathode
patent-application, April 2015
- Park, Kwang-jin; Han, Dong-Wook; Kim, Hyun-jin
- US Patent Application 14/519213; 20150111097
Metal Sulfide Electrodes And Energy Storage Devices Thereof
patent-application, October 2014
- Woodford, William Henry
- US Patent Application 14/172648; 20140302370
Electrolyte for a lithium-sulfur battery and a lithium-sulfur battery using the same
patent-application, August 2002
- Hwang, Duck Chul; Choi, Yun Suk; Choi, Soo Seok
- US Patent Application 09/910952; 20020102466
Aqueous electrolyte lithium sulfur batteries
patent-application, May 2013
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 13/475324; 20130122334
Dioxolane and dimethoxyethane electrolyte solvent system
patent, April 2001
- Webber, Andrew
- US Patent Document 6,218,054
Redox Flow Battery
patent-application, May 2012
- Yoshie, Tomohisa; Nishimura, Naoto; Tsukuda, Yoshihiro
- US Patent Application 13/377223; 20120135278
Secondary Batteries Comprising Eutectic Mixture And Preparation Method Thereof
patent-application, January 2010
- Oh, Jae-Seung; Lee, Byoung-Bae; Park, Ji-Won
- US Patent Application 12/309707; 20100021815