Zinc-based electrolyte compositions, and related electrochemical processes and articles

Kniajanski, Sergei; Soloveichik, Grigorii Lev

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Title: Zinc-based electrolyte compositions, and related electrochemical processes and articles

Abstract

An aqueous electrolyte composition is described, including a zinc salt based on zinc acetate or zinc glocolate. The saturation concentration of zinc in the electrolyte composition is in the range of about 2.5M to about 3.5M. The composition also contains at least one salt of a monovalent cation. The molar ratio of zinc to the monovalent cation is about 1:2. An aqueous zinc electroplating bath, containing the aqueous electrolyte composition, is also disclosed, along with a method for the electrochemical deposition of zinc onto a substrate surface, using the electroplating bath. Related flow batteries are also described, including a catholyte, as well as an anolyte based on the aqueous electrolyte composition, with a membrane between the catholyte and the anolyte.

Inventors:: Kniajanski, Sergei; Soloveichik, Grigorii Lev

Issue Date:: 2018-02-20

Research Org.:: General Electric Co., Schenectady, NY (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1422728

Patent Number(s):: 9899695

Application Number:: 14/720,005

Assignee:: GENERAL ELECTRIC COMPANY (Schenectady, NY)

Patent Classifications (CPCs):: C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25D - PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Show more

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25D - PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS
C25D17/10 - Electrodes {, e.g. composition, counter electrode}
C25D3/22 - of zinc

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M2250/10 - Fuel cells in stationary systems, e.g. emergency power source in plant
H01M2250/20 - Fuel cells in motive systems, e.g. vehicle, ship, plane
H01M8/188 - {by recharging of redox couples containing fluids

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02B - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
Y02B90/10 - Applications of fuel cells in buildings

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/50 - Fuel cells

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T90/40 - Application of hydrogen technology to transportation

Show less

DOE Contract Number:: AR0000381

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 May 22

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Kniajanski, Sergei, and Soloveichik, Grigorii Lev. Zinc-based electrolyte compositions, and related electrochemical processes and articles.  United States: N. p., 2018. 
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                    Kniajanski, Sergei, & Soloveichik, Grigorii Lev. Zinc-based electrolyte compositions, and related electrochemical processes and articles.  United States.

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                    Kniajanski, Sergei, and Soloveichik, Grigorii Lev. Tue .  
        "Zinc-based electrolyte compositions, and related electrochemical processes and articles".  United States.  https://www.osti.gov/servlets/purl/1422728.

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@article{osti_1422728,

  title        = {Zinc-based electrolyte compositions, and related electrochemical processes and articles},

  author       = {Kniajanski, Sergei and Soloveichik, Grigorii Lev},

  abstractNote = {An aqueous electrolyte composition is described, including a zinc salt based on zinc acetate or zinc glocolate. The saturation concentration of zinc in the electrolyte composition is in the range of about 2.5M to about 3.5M. The composition also contains at least one salt of a monovalent cation. The molar ratio of zinc to the monovalent cation is about 1:2. An aqueous zinc electroplating bath, containing the aqueous electrolyte composition, is also disclosed, along with a method for the electrochemical deposition of zinc onto a substrate surface, using the electroplating bath. Related flow batteries are also described, including a catholyte, as well as an anolyte based on the aqueous electrolyte composition, with a membrane between the catholyte and the anolyte.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {2}

}

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Works referenced in this record:

Rapid Zinc Depositing Bath
patent, May 1947

Hogaboom, George B.
US Patent Document 2421265
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/2421265

Dendrite-Inhibiting Additive for Battery Cell Having Zinc Electrode
patent, May 1972

Rampel, Guy
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Electrolytic Solution for Zinc Plating
patent, August 1972

Sakurai, Katumi; Odajima, Kenji
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Electroplating Bath for Depositing Bright Zinc Plates
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Korpium, Joachim; Steeg, Joachim
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Method to Improve Zinc Deposition Employing Multi-Nitrogen Quaternaries
patent, December 1974

Creutz, Hans-Gerhard
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Zinc-bromide secondary cell
patent, December 1975

Leddy, James; Gritzner, Gerhard
US Patent Document 3,929,506
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Method for manufacturing an electro-galvanized steel sheet excellent in bare corrosion resistance and adaptability to chromating, and product thereof
patent, September 1977

Adaniya, Takeshi; Ohmura, Masaki
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Leveling agent for acid zinc electroplating baths and method
patent, February 1978

Huebner, Karen
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Acid zinc plating baths and methods for electrodepositing bright zinc deposits
patent, July 1979

Canaris, Valerie M.
US Patent Document 4,162,947
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Electroplating bath and process
patent, October 1979

Creutz, deceased, Hans-Gerhard; Herr, Roy W.
US Patent Document 4,170,526
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Rechargeable zinc halogen battery
patent, January 1980

Spaziante, Placido M.; Nidola, Antonio
US Patent Document 4,181,777
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Process for manufacturing electro-galvanized steel strip
patent, April 1982

Adaniya, Takeshi; Ohmura, Masaki
US Patent Document 4,325,790
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4325790

Zinc dendrite inhibitor
patent, October 1984

Ando, Yasuo
US Patent Document 4,479,856
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4479856

Redox battery
patent, June 1994

Kaneko, Hiroko; Negishi, Akira; Nozaki, Ken
US Patent Document 5,318,865
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5318865

Electroconversion cell
patent, September 1998

Amendola, Steven
US Patent Document 5,804,329
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Stabilized electrolyte solutions, methods of preparation thereof and redox cells and batteries containing stabilized electrolyte solutions
patent, November 2000

Kazacos, Maria Skyllas; Kazacos, Michael
US Patent Document 6,143,443
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6143443

Lead-zinc storage battery
patent, March 2010

Stauffer, John E.
US Patent Document 7,682,737
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Galvanic bath and process for depositing zinc-based layers
patent, October 2012

Fuhrmann, Axel
US Patent Document 8,282,806
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Multiple-membrane multiple-electrolyte redox flow battery design
patent, May 2017

Yan, Yushan; Gu, Shuang; Gong, Ke
US Patent Document 9,640,826
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Battery with bifunctional electrolyte
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Clarke, Robert Lewis; Dougherty, Brian J.; Harrison, Stephen
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Perchlorate destruction
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Clarke, Robert Lwis; Harrison, Stephen; Dougherty, Brian J.
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Fuel cell with flow-through porous electrodes
patent-application, April 2009

Kjeang, Erik; Sinton, David; Djilali, Nedjib
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Redox Battery
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Composite Alkali Ion Conductive Solid Electrolyte
patent-application, July 2013

Joshi, Ashok V.; Bhavaraju, Sai
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Composite Alkali Ion Conductive Solid Electrolyte
patent-application, July 2013

Joshi, Ashok V.; Bhavaraju, Sai
US Patent Application 13/742184; 20130183546
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Rechargeable Electrochemical Zinc-Oxygen Cells
patent-application, March 2014

Urban, Tobias; Giesenberg, Thomas; Mutoro, Eva
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System and Method for Sensing and Mitigating Hydrogen Evolution Within a Flow Battery System
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Zaffon, Rachid; Pandy, Arun; Perry, Michael L.
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Ito, Yasumasa; Nyce, Michael; Plivelich, Robert
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Electrolyte additives for zinc-anoded secondary cells I. Brighteners, levellers and complexants
journal, December 1989

Wilcox, G. D.; Mitchell, P. J.
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Similar Records

Title: Zinc-based electrolyte compositions, and related electrochemical processes and articles

Abstract

Citation Formats

Rapid Zinc Depositing Bath patent, May 1947

Dendrite-Inhibiting Additive for Battery Cell Having Zinc Electrode patent, May 1972

Electrolytic Solution for Zinc Plating patent, August 1972

Electroplating Bath for Depositing Bright Zinc Plates patent, September 1972

Method to Improve Zinc Deposition Employing Multi-Nitrogen Quaternaries patent, December 1974

Zinc-bromide secondary cell patent, December 1975

Method for manufacturing an electro-galvanized steel sheet excellent in bare corrosion resistance and adaptability to chromating, and product thereof patent, September 1977

Leveling agent for acid zinc electroplating baths and method patent, February 1978

Acid zinc plating baths and methods for electrodepositing bright zinc deposits patent, July 1979

Electroplating bath and process patent, October 1979

Rechargeable zinc halogen battery patent, January 1980

Process for manufacturing electro-galvanized steel strip patent, April 1982

Zinc dendrite inhibitor patent, October 1984

Redox battery patent, June 1994

Electroconversion cell patent, September 1998

Stabilized electrolyte solutions, methods of preparation thereof and redox cells and batteries containing stabilized electrolyte solutions patent, November 2000

Lead-zinc storage battery patent, March 2010

Galvanic bath and process for depositing zinc-based layers patent, October 2012

Multiple-membrane multiple-electrolyte redox flow battery design patent, May 2017

Battery with bifunctional electrolyte patent-application, February 2004

Perchlorate destruction patent-application, October 2005

Fuel cell with flow-through porous electrodes patent-application, April 2009

Redox Battery patent-application, August 2010

Composite Alkali Ion Conductive Solid Electrolyte patent-application, July 2013

Composite Alkali Ion Conductive Solid Electrolyte patent-application, July 2013

Rechargeable Electrochemical Zinc-Oxygen Cells patent-application, March 2014

System and Method for Sensing and Mitigating Hydrogen Evolution Within a Flow Battery System patent-application, May 2014

Zinc morphology in zinc–nickel flow assisted batteries and impact on performance journal, February 2011

Electrolyte additives for zinc-anoded secondary cells I. Brighteners, levellers and complexants journal, December 1989

Rapid Zinc Depositing Bath
patent, May 1947

Dendrite-Inhibiting Additive for Battery Cell Having Zinc Electrode
patent, May 1972

Electrolytic Solution for Zinc Plating
patent, August 1972

Electroplating Bath for Depositing Bright Zinc Plates
patent, September 1972

Method to Improve Zinc Deposition Employing Multi-Nitrogen Quaternaries
patent, December 1974

Zinc-bromide secondary cell
patent, December 1975

Method for manufacturing an electro-galvanized steel sheet excellent in bare corrosion resistance and adaptability to chromating, and product thereof
patent, September 1977

Leveling agent for acid zinc electroplating baths and method
patent, February 1978

Acid zinc plating baths and methods for electrodepositing bright zinc deposits
patent, July 1979

Electroplating bath and process
patent, October 1979

Rechargeable zinc halogen battery
patent, January 1980

Process for manufacturing electro-galvanized steel strip
patent, April 1982

Zinc dendrite inhibitor
patent, October 1984

Redox battery
patent, June 1994

Electroconversion cell
patent, September 1998

Stabilized electrolyte solutions, methods of preparation thereof and redox cells and batteries containing stabilized electrolyte solutions
patent, November 2000

Lead-zinc storage battery
patent, March 2010

Galvanic bath and process for depositing zinc-based layers
patent, October 2012

Multiple-membrane multiple-electrolyte redox flow battery design
patent, May 2017

Battery with bifunctional electrolyte
patent-application, February 2004

Perchlorate destruction
patent-application, October 2005

Fuel cell with flow-through porous electrodes
patent-application, April 2009

Redox Battery
patent-application, August 2010

Composite Alkali Ion Conductive Solid Electrolyte
patent-application, July 2013

Composite Alkali Ion Conductive Solid Electrolyte
patent-application, July 2013

Rechargeable Electrochemical Zinc-Oxygen Cells
patent-application, March 2014

System and Method for Sensing and Mitigating Hydrogen Evolution Within a Flow Battery System
patent-application, May 2014

Zinc morphology in zinc–nickel flow assisted batteries and impact on performance
journal, February 2011

Electrolyte additives for zinc-anoded secondary cells I. Brighteners, levellers and complexants
journal, December 1989