Mixed metal iron oxides and uses thereof

Shen, Jian-ping; Lail, Marty; Turk, Brian; Mobley, Paul D.; Norman, Jason S.; Douglas, Laura; Peters, Jonathan

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Title: Mixed metal iron oxides and uses thereof

Abstract

This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO.sub.2 and the selective reaction with organic compounds.

Inventors:: Shen, Jian-ping; Lail, Marty; Turk, Brian; Mobley, Paul D.; Norman, Jason S.; Douglas, Laura; Peters, Jonathan

Issue Date:: 2018-02-06

Research Org.:: Research Triangle Institute, Research Triangle Park, NC (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1419790

Patent Number(s):: 9884313

Application Number:: 14/908,852

Assignee:: Research Triangle Institute (Research Triangle Park, NC)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J21/02 - Boron or aluminium
B01J23/002 - {Mixed oxides other than spinels, e.g. perovskite}
B01J23/74 - Iron group metals
B01J23/76 - combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
B01J23/78 - with alkali- or alkaline earth metals
B01J23/80 - with zinc, cadmium or mercury
B01J23/83 - with rare earths or actinides
B01J23/835 - with germanium, tin or lead
B01J23/8892 - {Manganese}
B01J23/8906 - {Iron and noble metals}
B01J2523/00 - Constitutive chemical elements of heterogeneous catalysts
B01J2523/13 - Potassium
B01J2523/17 - Copper
B01J2523/22 - Magnesium
B01J2523/24 - Strontium
B01J2523/27 - Zinc
B01J2523/31 - Aluminium
B01J2523/3706 - Lanthanum
B01J2523/43 - Tin
B01J2523/72 - Manganese
B01J2523/821 - Ruthenium
B01J2523/842 - Iron
B01J2523/845 - Cobalt
B01J35/002 - {Catalysts characterised by their physical properties}
B01J37/03 - Precipitation
B01J37/14 - with gases containing free oxygen
B01J37/18 - with gases containing free hydrogen

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0238 - the reforming step being a carbon dioxide reforming step
C01B2203/1047 - Group VIII metal catalysts
C01B2203/1064 - Platinum group metal catalysts
C01B2203/1088 - Non-supported catalysts
C01B2203/1235 - Hydrocarbons
C01B3/40 - characterised by the catalyst
C01B32/40 - Carbon monoxide

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/041 - {Reactors}
C07C11/02 - Alkenes
C07C11/04 - Ethylene
C07C11/06 - Propene
C07C11/22 - containing carbon-to-carbon triple bonds
C07C13/20 - with a cyclohexene ring
C07C15/46 - Styrene
C07C2/84 - catalytic
C07C2521/04 - Alumina
C07C2521/06 - Silicon, titanium, zirconium or hafnium
C07C2521/08 - Silica
C07C2523/46 - Ruthenium, rhodium, osmium or iridium
C07C2523/74 - Iron group metals
C07C2523/78 - with alkali- or alkaline earth metals or beryllium
C07C2523/80 - with zinc, cadmium or mercury
C07C2523/83 - with rare earths or actinides
C07C2523/835 - with germanium, tin or lead
C07C2523/889 - Manganese, technetium or rhenium
C07C2523/89 - combined with noble metals
C07C2601/16 - the ring being unsaturated
C07C29/156 - containing iron group metals, platinum group metals or compounds thereof
C07C31/04 - Methanol
C07C5/42 - by dehydrogenation with a hydrogen acceptor
C07C9/06 - Ethane

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D301/03 - by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2400/22 - Higher olefins
C10G2400/30 - Aromatics
C10G27/00 - Refining of hydrocarbon oils in the absence of hydrogen, by oxidation

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/0969 - Carbon dioxide
C10J2300/0986 - Catalysts
C10J2300/1653 - integrated in a gasification combined cycle [IGCC]
C10J3/463 - {in stationary fluidised beds}
C10J3/725 - {Redox processes}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E20/18 - Integrated gasification combined cycle [IGCC]
Y02E50/10 - Biofuels

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/52 - using catalysts, e.g. selective catalysts
Y02P30/00 - Technologies relating to oil refining and petrochemical industry

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DOE Contract Number:: FE0004329

Resource Type:: Patent

Resource Relation:: Patent File Date: 2018 Feb 06

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Shen, Jian-ping, Lail, Marty, Turk, Brian, Mobley, Paul D., Norman, Jason S., Douglas, Laura, and Peters, Jonathan. Mixed metal iron oxides and uses thereof.  United States: N. p., 2018. 
        Web.

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                    Shen, Jian-ping, Lail, Marty, Turk, Brian, Mobley, Paul D., Norman, Jason S., Douglas, Laura, & Peters, Jonathan. Mixed metal iron oxides and uses thereof.  United States.

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                    Shen, Jian-ping, Lail, Marty, Turk, Brian, Mobley, Paul D., Norman, Jason S., Douglas, Laura, and Peters, Jonathan. Tue .  
        "Mixed metal iron oxides and uses thereof".  United States.  https://www.osti.gov/servlets/purl/1419790.

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@article{osti_1419790,

  title        = {Mixed metal iron oxides and uses thereof},

  author       = {Shen, Jian-ping and Lail, Marty and Turk, Brian and Mobley, Paul D. and Norman, Jason S. and Douglas, Laura and Peters, Jonathan},

  abstractNote = {This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO.sub.2 and the selective reaction with organic compounds.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {2}

}

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Works referenced in this record:

Reduction of Iron Oxide for Use in the Synthesis of Hydrocarbons
patent, December 1955

McGrath, Henry G.
US Patent Document 2,728,786
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Dehydrogenation and Methanation catalyst and Process
patent, January 1969

Brewer, Charles C.; Fritz, Richard C.; Moe, James M.
US Patent Document 3,424,808
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Process for preparing acetonitrile
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Olive, Gisela; Olive, Salvador
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Catalytic oxidation
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Dehydrogenation process
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Riesser, Gregor H.
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Dehydrogenation catalyst
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Riesser, Gregor H.
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Process for the liquid phase hydrogenation of coal
patent, April 1985

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US Patent Document 4,510,039
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Catalysts for selective catalytic reduction DeNOx technology
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Process using catalysts for selective catalytic reduction denox technology
patent, December 1990

Hegedus, Louis; Beeckman, Jean W.; Pan, Wie-Hin
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Process for the preparation of a new catalyst useful for producing alkylated aromatic amines
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Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
patent, October 2000

Pelrine, Bruce P.; Comolli, Alfred G.; Lee, Lap-Keung
US Patent Document 6,139,723
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Preparation of vanadium antimony oxide based catalysts using nano-scale iron
patent, March 2005

Brazdil, James F.; Bartek, Joseph P.; Trail, Steven S.
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Method for producing carbon monoxide by reverse conversion with an adapted catalyst
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Mamedov, Aghaddin; Shaikh, Shahid N.; Rea, Clark
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Similar Records

Title: Mixed metal iron oxides and uses thereof

Abstract

Citation Formats

Reduction of Iron Oxide for Use in the Synthesis of Hydrocarbons patent, December 1955

Dehydrogenation and Methanation catalyst and Process patent, January 1969

Process for preparing acetonitrile patent, November 1977

Catalytic oxidation patent, January 1978

Dehydrogenation process patent, March 1979

Dehydrogenation catalyst patent, May 1979

Process for the liquid phase hydrogenation of coal patent, April 1985

Catalysts for selective catalytic reduction DeNOx technology patent, May 1990

Process using catalysts for selective catalytic reduction denox technology patent, December 1990

Process for the preparation of a new catalyst useful for producing alkylated aromatic amines patent, March 2000

Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds patent, October 2000

Preparation of vanadium antimony oxide based catalysts using nano-scale iron patent, March 2005

Method for producing carbon monoxide by reverse conversion with an adapted catalyst patent-application, June 2003

Process For Converting A Hydrocarbon To An Oxygenate Or A Nitrile patent-application, February 2008

Mixed Oxide Based Catalyst For The Conversion Of Carbon Dioxide To Syngas And Method Of Preparation And Use patent-application, June 2013

CeO2-Modified Fe2O3 for CO2 Utilization via Chemical Looping journal, June 2013

Tar and CO2 removal from simulated producer gas with activated carbon and charcoal journal, February 2013

Promotion of hydrocarbon selectivity in CO2 hydrogenation by Ru component journal, March 2004

Ni–Fe Catalysts Based on Perovskite-type Oxides for Dry Reforming of Methane to Syngas journal, April 2006

The effect of the nature of the support on catalytic properties of ruthenium supported catalysts in partial oxidation of methane to syn-gas journal, September 2011

Activation of carbon dioxide on Fe-catalysts journal, February 2005

Reduction of Iron Oxide for Use in the Synthesis of Hydrocarbons
patent, December 1955

Dehydrogenation and Methanation catalyst and Process
patent, January 1969

Process for preparing acetonitrile
patent, November 1977

Catalytic oxidation
patent, January 1978

Dehydrogenation process
patent, March 1979

Dehydrogenation catalyst
patent, May 1979

Process for the liquid phase hydrogenation of coal
patent, April 1985

Catalysts for selective catalytic reduction DeNOx technology
patent, May 1990

Process using catalysts for selective catalytic reduction denox technology
patent, December 1990

Process for the preparation of a new catalyst useful for producing alkylated aromatic amines
patent, March 2000

Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
patent, October 2000

Preparation of vanadium antimony oxide based catalysts using nano-scale iron
patent, March 2005

Method for producing carbon monoxide by reverse conversion with an adapted catalyst
patent-application, June 2003

Process For Converting A Hydrocarbon To An Oxygenate Or A Nitrile
patent-application, February 2008

Mixed Oxide Based Catalyst For The Conversion Of Carbon Dioxide To Syngas And Method Of Preparation And Use
patent-application, June 2013

CeO₂-Modified Fe₂O₃ for CO₂ Utilization via Chemical Looping
journal, June 2013

Tar and CO₂ removal from simulated producer gas with activated carbon and charcoal
journal, February 2013

Promotion of hydrocarbon selectivity in CO₂ hydrogenation by Ru component
journal, March 2004

Ni–Fe Catalysts Based on Perovskite-type Oxides for Dry Reforming of Methane to Syngas
journal, April 2006

The effect of the nature of the support on catalytic properties of ruthenium supported catalysts in partial oxidation of methane to syn-gas
journal, September 2011

Activation of carbon dioxide on Fe-catalysts
journal, February 2005