Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion

Hood, Zachary D.; Adhikari, Shiba P.; Wright, Marcus W.; Lachgar, Abdessadek; Li, Yunchao; Naskar, Amit K.; Paranthaman, Mariappan Parans

Title: Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion

Abstract

A method of making solid acid catalysts includes the step of sulfonating waste tire pieces in a first sulfonation step. The sulfonated waste tire pieces are pyrolyzed to produce carbon composite pieces having a pore size less than 10 nm. The carbon composite pieces are then ground to produce carbon composite powders having a size less than 50 .mu.m. The carbon composite particles are sulfonated in a second sulfonation step to produce sulfonated solid acid catalysts. A method of making biofuels and solid acid catalysts are also disclosed.

Inventors:: Hood, Zachary D.; Adhikari, Shiba P.; Wright, Marcus W.; Lachgar, Abdessadek; Li, Yunchao; Naskar, Amit K.; Paranthaman, Mariappan Parans

Issue Date:: 2018-02-06

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1419784

Patent Number(s):: 9884804

Application Number:: 15/163,434

Assignee:: UT-BATTELLE, LLC (Oak Ridge, TN); UNIVERSITY OF TENNESSEE RESEARCH FOUNDATION (Knoxville, TN)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J21/18 - Carbon
B01J2231/49 - Esterification or transesterification
B01J31/10 - sulfonated
B01J35/023 - {Catalysts characterised by dimensions, e.g. grain size}
B01J35/1057 - {less than 2 nm}
B01J35/1061 - {2-50 nm}
B01J37/0036 - {Grinding}
B01J37/084 - {Decomposition of carbon-containing compounds into carbon}
B01J37/20 - Sulfiding

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/324 - from waste materials, e.g. tyres or spent sulfite pulp liquor

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C67/08 - by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 May 24

Country of Publication:: United States

Language:: English

Subject:: 09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Hood, Zachary D., Adhikari, Shiba P., Wright, Marcus W., Lachgar, Abdessadek, Li, Yunchao, Naskar, Amit K., and Paranthaman, Mariappan Parans. Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion.  United States: N. p., 2018. 
        Web.

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                    Hood, Zachary D., Adhikari, Shiba P., Wright, Marcus W., Lachgar, Abdessadek, Li, Yunchao, Naskar, Amit K., & Paranthaman, Mariappan Parans. Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion.  United States.

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                    Hood, Zachary D., Adhikari, Shiba P., Wright, Marcus W., Lachgar, Abdessadek, Li, Yunchao, Naskar, Amit K., and Paranthaman, Mariappan Parans. Tue .  
        "Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion".  United States.  https://www.osti.gov/servlets/purl/1419784.

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@article{osti_1419784,

  title        = {Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion},

  author       = {Hood, Zachary D. and Adhikari, Shiba P. and Wright, Marcus W. and Lachgar, Abdessadek and Li, Yunchao and Naskar, Amit K. and Paranthaman, Mariappan Parans},

  abstractNote = {A method of making solid acid catalysts includes the step of sulfonating waste tire pieces in a first sulfonation step. The sulfonated waste tire pieces are pyrolyzed to produce carbon composite pieces having a pore size less than 10 nm. The carbon composite pieces are then ground to produce carbon composite powders having a size less than 50 .mu.m. The carbon composite particles are sulfonated in a second sulfonation step to produce sulfonated solid acid catalysts. A method of making biofuels and solid acid catalysts are also disclosed.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {2}

}

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Process for the preparation of a granular activated carbon, and granular activated carbons produced thereby
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Title: Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion

Abstract

Citation Formats

Composite carbon material of negative electrode in lithuim ion battery and its preparation method patent-application, May 2009

Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors journal, January 2015

Surface Functional Characteristics (C, O, S) of Waste Tire-Derived Carbon Black before and after Steam Activation journal, January 2008

Polyaniline nanotubules—anion effect on conformation and oxidation state of polyaniline studied by Raman spectroscopy journal, April 2004

A metal-oxide nanofiber-decorated three-dimensional graphene hybrid nanostructured flexible electrode for high-capacity electrochemical capacitors journal, January 2014

A review of electrode materials for electrochemical supercapacitors journal, January 2012

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Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Reduced Graphene Oxide Sheets for Supercapacitors journal, December 2013

Effects of Pore Structure on Performance of An Activated-Carbon Supercapacitor Electrode Recycled from Scrap Waste Tires journal, June 2014

Human hair-derived carbon flakes for electrochemical supercapacitors journal, January 2014

Method For Obtaining A Carbon Black Powder By Pyrolyzing Scrap Rubber, The Carbon Black Thus Obtained And The Use Thereof patent-application, December 2014

Crosslinked polyaniline nanorods with improved electrochemical performance as electrode material for supercapacitors journal, January 2014

Composite Manganese Oxide Percolating Networks As a Suspension Electrode for an Asymmetric Flow Capacitor journal, May 2014

Flexible all-solid-state high-power supercapacitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose journal, January 2013

Process of producing gasoline, diesel and carbon black with waste rubbers and/or waste plastics patent, April 1998

Pyrolysis of Tire Rubber: Porosity and Adsorption Characteristics of the Pyrolytic Chars journal, June 1998

Liquefaction of waste tires by pyrolysis for oil and chemicals—A review journal, May 2013

Mesoporous carbons and polymers patent, October 2001

Apparatus for recovering marketable products from scrap rubber patent, August 2008

Li4Ti5O12/poly(methyl)thiophene asymmetric hybrid electrochemical device journal, January 2004

Pyrolytic conversion of scrap tires to carbon products patent, March 2009

Method For Upgrade-Processing Carbon Black Produced By Performing A Pyrolysis Process On Waste Tires patent-application, October 2012

Conducting polymer/carbon nanocoil composite electrodes for efficient supercapacitors journal, January 2012

Sulfonic acid group-containing carbonaceous material patent, November 2013

Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction journal, January 2014

Carbon nano-particle and method of preparing the same and transparent conductive polymer composite containing the same patent, July 2005

Mesoporous carbons and polymers patent-application, May 2002

From dead leaves to high energy density supercapacitors journal, January 2013

Process for producing carbon anode compositions for lithium ion batteries patent, August 2011

Activity of solid acid catalysts for biodiesel production: A critical review journal, January 2014

Sulfonated Amorphous Carbon, Process for Producing the Same and Use Thereof patent-application, July 2007

Polyaniline and Polypyrrole Pseudocapacitor Electrodes with Excellent Cycling Stability journal, April 2014

Activated Carbon Spheres as a Flowable Electrode in Electrochemical Flow Capacitors journal, January 2014

Biodiesel sulfur slurry patent, October 2004

Biodiesel production: a review journal, October 1999

Green chemistry: Biodiesel made with sugar catalyst journal, November 2005

Growth of Polyaniline on Hollow Carbon Spheres for Enhancing Electrocapacitance journal, November 2010

Production of a Char Reinforcing Agent from Pyrolyzed Scrap Rubber patent, July 1974

Graphene-containing flowable electrodes for capacitive energy storage journal, October 2015

Highly Stable Supercapacitors with Conducting Polymer Core-Shell Electrodes for Energy Storage Applications journal, January 2015

Reduced-graphene oxide/molybdenum oxide/polyaniline ternary composite for high energy density supercapacitors: Synthesis and properties journal, January 2012

Thermal plasma pyrolysis of used tires for carbon black recovery journal, July 2005

Mesoporous and adsorptive properties of palm date seed activated carbon prepared via sequential hydrothermal carbonization and sodium hydroxide activation journal, June 2015

Mesoporous carbons and polymers patent, May 2004

Pyrolytic Carbon Black Composite And Method Of Making The Same patent-application, September 2016

Interconnected Carbon Nanosheets Derived from Hemp for Ultrafast Supercapacitors with High Energy journal, May 2013

Carbon-based solid acid, catalyst comprising the solid acid, and reaction using the solid acid as catalyst patent, September 2011

Solid acid catalyzed biodiesel production from waste cooking oil journal, December 2008

Carbons and Electrolytes for Advanced Supercapacitors journal, February 2014

Method for recovering carbon black from composites patent, March 1998

Activated carbon for use in electric double layer capacitors patent-application, August 2002

Sulfonated rubber compositions and processes therefor and therewith patent, April 2003

High-Density Sodium and Lithium Ion Battery Anodes from Banana Peels journal, June 2014

Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst journal, August 2010

Nanofiber Formation in the Chemical Polymerization of Aniline: A Mechanistic Study journal, November 2004

Activated carbon and process for producing the same patent, October 1999

Chloroform vapour sensor based on copper/polyaniline nanocomposite journal, June 2002

Synthesis of biodiesel from cottonseed oil and methanol using a carbon-based solid acid catalyst journal, July 2009

Polymer-Nanocarbon Composites, Methods Of Making Composites, And Energy Storage Devices Including The Composite patent-application, January 2015

Flexible graphene–polyaniline composite paper for high-performance supercapacitor journal, January 2013

Tailored recovery of carbons from waste tires for enhanced performance as anodes in lithium-ion batteries journal, January 2014

Process for producing granular activated carbon patent, January 1977

Pyrolyzed rubber products and processes patent, May 2011

Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents journal, March 2005

Towards High-Energy-Density Pseudocapacitive Flowable Electrodes by the Incorporation of Hydroquinone journal, January 2015

Biodiesel Production From Oils And Fats With High Free Fatty Acids journal, January 2001

Effect of Oxidation of Carbon Material on Suspension Electrodes for Flow Electrode Capacitive Deionization journal, February 2015

Method for recovering carbon black from a waste rubber such as tires and the like and apparatus therefor patent, October 1999

Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life journal, September 2015

Flexible and Conductive Waste Tire-Derived Carbon/Polymer Composite Paper As Pseudocapacitive Electrode patent-application, December 2016

Preparation of Graphitic Oxide journal, March 1958

Pyrolytic carbon black composite and method of making the same patent, September 2016

Charge storage mechanism in nanoporous carbons and its consequence for electrical double layer capacitors journal, June 2010

Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films journal, March 2010

Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage journal, August 2010

Pyrolytic Carbon Black Composite And Method Of Making The Same patent-application, January 2015

Biochar based solid acid catalyst for biodiesel production journal, July 2010

Composite carbon material of negative electrode in lithuim ion battery and its preparation method
patent-application, May 2009

Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
journal, January 2015

Surface Functional Characteristics (C, O, S) of Waste Tire-Derived Carbon Black before and after Steam Activation
journal, January 2008

Polyaniline nanotubules—anion effect on conformation and oxidation state of polyaniline studied by Raman spectroscopy
journal, April 2004

A metal-oxide nanofiber-decorated three-dimensional graphene hybrid nanostructured flexible electrode for high-capacity electrochemical capacitors
journal, January 2014

A review of electrode materials for electrochemical supercapacitors
journal, January 2012

Evolution of disposable bamboo chopsticks into uniform carbon fibers: a smart strategy to fabricate sustainable anodes for Li-ion batteries
journal, January 2014

Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Reduced Graphene Oxide Sheets for Supercapacitors
journal, December 2013

Effects of Pore Structure on Performance of An Activated-Carbon Supercapacitor Electrode Recycled from Scrap Waste Tires
journal, June 2014

Human hair-derived carbon flakes for electrochemical supercapacitors
journal, January 2014

Method For Obtaining A Carbon Black Powder By Pyrolyzing Scrap Rubber, The Carbon Black Thus Obtained And The Use Thereof
patent-application, December 2014

Crosslinked polyaniline nanorods with improved electrochemical performance as electrode material for supercapacitors
journal, January 2014

Composite Manganese Oxide Percolating Networks As a Suspension Electrode for an Asymmetric Flow Capacitor
journal, May 2014

Flexible all-solid-state high-power supercapacitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose
journal, January 2013

Process of producing gasoline, diesel and carbon black with waste rubbers and/or waste plastics
patent, April 1998

Pyrolysis of Tire Rubber: Porosity and Adsorption Characteristics of the Pyrolytic Chars
journal, June 1998

Liquefaction of waste tires by pyrolysis for oil and chemicals—A review
journal, May 2013

Mesoporous carbons and polymers
patent, October 2001

Apparatus for recovering marketable products from scrap rubber
patent, August 2008

Li₄Ti₅O₁₂/poly(methyl)thiophene asymmetric hybrid electrochemical device
journal, January 2004

Pyrolytic conversion of scrap tires to carbon products
patent, March 2009

Method For Upgrade-Processing Carbon Black Produced By Performing A Pyrolysis Process On Waste Tires
patent-application, October 2012

Conducting polymer/carbon nanocoil composite electrodes for efficient supercapacitors
journal, January 2012

Sulfonic acid group-containing carbonaceous material
patent, November 2013

Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction
journal, January 2014

Carbon nano-particle and method of preparing the same and transparent conductive polymer composite containing the same
patent, July 2005

Mesoporous carbons and polymers
patent-application, May 2002

From dead leaves to high energy density supercapacitors
journal, January 2013

Process for producing carbon anode compositions for lithium ion batteries
patent, August 2011

Activity of solid acid catalysts for biodiesel production: A critical review
journal, January 2014

Sulfonated Amorphous Carbon, Process for Producing the Same and Use Thereof
patent-application, July 2007

Polyaniline and Polypyrrole Pseudocapacitor Electrodes with Excellent Cycling Stability
journal, April 2014

Activated Carbon Spheres as a Flowable Electrode in Electrochemical Flow Capacitors
journal, January 2014

Biodiesel sulfur slurry
patent, October 2004

Biodiesel production: a review
journal, October 1999

Green chemistry: Biodiesel made with sugar catalyst
journal, November 2005

Growth of Polyaniline on Hollow Carbon Spheres for Enhancing Electrocapacitance
journal, November 2010

Production of a Char Reinforcing Agent from Pyrolyzed Scrap Rubber
patent, July 1974

Graphene-containing flowable electrodes for capacitive energy storage
journal, October 2015

Highly Stable Supercapacitors with Conducting Polymer Core-Shell Electrodes for Energy Storage Applications
journal, January 2015

Reduced-graphene oxide/molybdenum oxide/polyaniline ternary composite for high energy density supercapacitors: Synthesis and properties
journal, January 2012

Thermal plasma pyrolysis of used tires for carbon black recovery
journal, July 2005

Mesoporous and adsorptive properties of palm date seed activated carbon prepared via sequential hydrothermal carbonization and sodium hydroxide activation
journal, June 2015

Mesoporous carbons and polymers
patent, May 2004

Pyrolytic Carbon Black Composite And Method Of Making The Same
patent-application, September 2016

Interconnected Carbon Nanosheets Derived from Hemp for Ultrafast Supercapacitors with High Energy
journal, May 2013

Carbon-based solid acid, catalyst comprising the solid acid, and reaction using the solid acid as catalyst
patent, September 2011

Solid acid catalyzed biodiesel production from waste cooking oil
journal, December 2008

Carbons and Electrolytes for Advanced Supercapacitors
journal, February 2014

Method for recovering carbon black from composites
patent, March 1998

Activated carbon for use in electric double layer capacitors
patent-application, August 2002

Sulfonated rubber compositions and processes therefor and therewith
patent, April 2003

High-Density Sodium and Lithium Ion Battery Anodes from Banana Peels
journal, June 2014

Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst
journal, August 2010

Nanofiber Formation in the Chemical Polymerization of Aniline: A Mechanistic Study
journal, November 2004

Activated carbon and process for producing the same
patent, October 1999

Chloroform vapour sensor based on copper/polyaniline nanocomposite
journal, June 2002

Synthesis of biodiesel from cottonseed oil and methanol using a carbon-based solid acid catalyst
journal, July 2009

Polymer-Nanocarbon Composites, Methods Of Making Composites, And Energy Storage Devices Including The Composite
patent-application, January 2015

Flexible graphene–polyaniline composite paper for high-performance supercapacitor
journal, January 2013

Tailored recovery of carbons from waste tires for enhanced performance as anodes in lithium-ion batteries
journal, January 2014

Process for producing granular activated carbon
patent, January 1977

Pyrolyzed rubber products and processes
patent, May 2011

Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents
journal, March 2005

Towards High-Energy-Density Pseudocapacitive Flowable Electrodes by the Incorporation of Hydroquinone
journal, January 2015

Biodiesel Production From Oils And Fats With High Free Fatty Acids
journal, January 2001

Effect of Oxidation of Carbon Material on Suspension Electrodes for Flow Electrode Capacitive Deionization
journal, February 2015

Method for recovering carbon black from a waste rubber such as tires and the like and apparatus therefor
patent, October 1999

Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life
journal, September 2015

Flexible and Conductive Waste Tire-Derived Carbon/Polymer Composite Paper As Pseudocapacitive Electrode
patent-application, December 2016

Preparation of Graphitic Oxide
journal, March 1958

Pyrolytic carbon black composite and method of making the same
patent, September 2016

Charge storage mechanism in nanoporous carbons and its consequence for electrical double layer capacitors
journal, June 2010

Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films
journal, March 2010

Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage
journal, August 2010

Pyrolytic Carbon Black Composite And Method Of Making The Same
patent-application, January 2015

Biochar based solid acid catalyst for biodiesel production
journal, July 2010

Polyaniline/multi-walled carbon nanotube composites with core–shell structures as supercapacitor electrode materials
journal, April 2010

Highly porous carbon spheres for electrochemical capacitors and capacitive flowable suspension electrodes
journal, October 2014

A comparative study of solid carbon acid catalysts for the esterification of free fatty acids for biodiesel production. Evidence for the leaching of colloidal carbon
journal, November 2013