Cross-linked polymeric membranes for carbon dioxide separation

Hong, Tao; Chatterjee, Sabornie; Mahurin, Shannon Mark; Long, Brian Keith; Jiang, De-en; Mays, Jimmy Wayne; Sokolov, Alexei P.; Saito, Tomonori

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Title: Cross-linked polymeric membranes for carbon dioxide separation

Abstract

A membrane useful in gas separation, the membrane comprising a cross-linked polysiloxane structure having a cross-link density of about 0.1.times.10.sup.-5 mol/cm.sup.3 to about 6.times.10.sup.-5 mol/cm.sup.3, where, in particular embodiments, the cross-linked polysiloxane structure has the following general structure: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are independently selected from hydrocarbon groups having at least 1 and up to 6 carbon atoms; A.sup.1 and A.sup.2 are independently selected from cyclic hydrocarbon groups; L.sup.1 and L.sup.2 are linking groups or covalent bonds; n is an integer of at least 1; r and s are independently selected from integers of at least 1; and p is an integer of at least 10. The invention also includes methods for making and using the above-described membranes for gas separation.

Inventors:: Hong, Tao; Chatterjee, Sabornie; Mahurin, Shannon Mark; Long, Brian Keith; Jiang, De-en; Mays, Jimmy Wayne; Sokolov, Alexei P.; Saito, Tomonori

Issue Date:: 2018-01-23

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1417966

Patent Number(s):: 9873094

Application Number:: 14/826,338

Assignee:: UT-Battelle, LLC (Oak Ridge, TN); University of Tennessee Research Foundation (Knoxville, TN)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2256/10 - Nitrogen
B01D2257/504 - Carbon dioxide
B01D2323/30 - Cross-linking
B01D53/22 - by diffusion
B01D53/228 - {characterised by specific membranes}
B01D67/0006 - {by chemical reactions
B01D71/70 - Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F136/14 - containing elements other than carbon and hydrogen
C08F2500/25 - Cycloolefine

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G77/28 - sulfur-containing groups

C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
C09D183/08 - containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/151 - Reduction of greenhouse gas [GHG] emissions

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Aug 14

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Hong, Tao, Chatterjee, Sabornie, Mahurin, Shannon Mark, Long, Brian Keith, Jiang, De-en, Mays, Jimmy Wayne, Sokolov, Alexei P., and Saito, Tomonori. Cross-linked polymeric membranes for carbon dioxide separation.  United States: N. p., 2018. 
        Web.

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                    Hong, Tao, Chatterjee, Sabornie, Mahurin, Shannon Mark, Long, Brian Keith, Jiang, De-en, Mays, Jimmy Wayne, Sokolov, Alexei P., & Saito, Tomonori. Cross-linked polymeric membranes for carbon dioxide separation.  United States.

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                    Hong, Tao, Chatterjee, Sabornie, Mahurin, Shannon Mark, Long, Brian Keith, Jiang, De-en, Mays, Jimmy Wayne, Sokolov, Alexei P., and Saito, Tomonori. Tue .  
        "Cross-linked polymeric membranes for carbon dioxide separation".  United States.  https://www.osti.gov/servlets/purl/1417966.

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@article{osti_1417966,

  title        = {Cross-linked polymeric membranes for carbon dioxide separation},

  author       = {Hong, Tao and Chatterjee, Sabornie and Mahurin, Shannon Mark and Long, Brian Keith and Jiang, De-en and Mays, Jimmy Wayne and Sokolov, Alexei P. and Saito, Tomonori},

  abstractNote = {A membrane useful in gas separation, the membrane comprising a cross-linked polysiloxane structure having a cross-link density of about 0.1.times.10.sup.-5 mol/cm.sup.3 to about 6.times.10.sup.-5 mol/cm.sup.3, where, in particular embodiments, the cross-linked polysiloxane structure has the following general structure: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are independently selected from hydrocarbon groups having at least 1 and up to 6 carbon atoms; A.sup.1 and A.sup.2 are independently selected from cyclic hydrocarbon groups; L.sup.1 and L.sup.2 are linking groups or covalent bonds; n is an integer of at least 1; r and s are independently selected from integers of at least 1; and p is an integer of at least 10. The invention also includes methods for making and using the above-described membranes for gas separation.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {1}

}

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Similar Records

Title: Cross-linked polymeric membranes for carbon dioxide separation

Abstract

Citation Formats

Polymers of cyano-substituted norbornene derivatives and method for preparing the same patent, December 1974

Method of making membranes for gas separation and the composite membranes patent, July 1986

Ion exchange method for separation of scandium and thorium patent, August 1988

Composite membrane and process for its production patent, March 1998

Process for the manufacture of an ophthalmic molding patent, March 2000

Dental impression material utilizing ruthenium catalyst patent, September 2002

Semipermeable membranes patent, November 2004

Interfacial composite structure and method of making them patent-application, September 2006

Method of preparing gas selective membrane using epoxy-functional siloxanes patent-application, March 2014

Method of making a membrane and a membrane for water filtration patent-application, May 2015

Porous membranes made of cross-linked thermoplastic silicone elastomer patent-application, December 2015

Fluoropolyether-polysiloxane elastomer compositions and shaped articles patent-application, May 2016

Synthesis of High Molecular Weight Poly[3-{tris(trimethylsiloxy)silyl}tricyclononenes-7] and Their Gas Permeation Properties journal, September 2011

An Efficient Polymer Molecular Sieve for Membrane Gas Separations journal, January 2013

The group separation of the rare-earth elements and yttrium from geologic materials by cation-exchange chromatography journal, August 1984

Advances in high permeability polymeric membrane materials for CO2 separations journal, January 2012

Polymer nanosieve membranes for CO2-capture applications journal, April 2011

Addition-Type Polynorbornenes with Si(CH3)3 Side Groups: Synthesis, Gas Permeability, and Free Volume journal, October 2006

Ring Opening Metathesis Polymerization of Norbornene and Derivatives by the Triply Bonded Ditungsten Complex Na[W2(µ-Cl)3Cl4(THF)2]·(THF)3 journal, November 2012

Unprecedented high-temperature CO2 selectivity in N2-phobic nanoporous covalent organic polymers journal, January 2013

Ab Initio Screening of CO2-philic Groups journal, April 2015

Polymers of cyano-substituted norbornene derivatives and method for preparing the same
patent, December 1974

Method of making membranes for gas separation and the composite membranes
patent, July 1986

Ion exchange method for separation of scandium and thorium
patent, August 1988

Composite membrane and process for its production
patent, March 1998

Process for the manufacture of an ophthalmic molding
patent, March 2000

Dental impression material utilizing ruthenium catalyst
patent, September 2002

Semipermeable membranes
patent, November 2004

Interfacial composite structure and method of making them
patent-application, September 2006

Method of preparing gas selective membrane using epoxy-functional siloxanes
patent-application, March 2014

Method of making a membrane and a membrane for water filtration
patent-application, May 2015

Porous membranes made of cross-linked thermoplastic silicone elastomer
patent-application, December 2015

Fluoropolyether-polysiloxane elastomer compositions and shaped articles
patent-application, May 2016

Synthesis of High Molecular Weight Poly[3-{tris(trimethylsiloxy)silyl}tricyclononenes-7] and Their Gas Permeation Properties
journal, September 2011

An Efficient Polymer Molecular Sieve for Membrane Gas Separations
journal, January 2013

The group separation of the rare-earth elements and yttrium from geologic materials by cation-exchange chromatography
journal, August 1984

Advances in high permeability polymeric membrane materials for CO₂ separations
journal, January 2012

Polymer nanosieve membranes for CO₂-capture applications
journal, April 2011

Addition-Type Polynorbornenes with Si(CH₃)₃ Side Groups: Synthesis, Gas Permeability, and Free Volume
journal, October 2006

Ring Opening Metathesis Polymerization of Norbornene and Derivatives by the Triply Bonded Ditungsten Complex Na[W₂(µ-Cl)₃Cl₄(THF)₂]·(THF)₃
journal, November 2012

Unprecedented high-temperature CO₂ selectivity in N₂-phobic nanoporous covalent organic polymers
journal, January 2013

Ab Initio Screening of CO₂-philic Groups
journal, April 2015