Global to push GA events into
skip to main content

Title: Modular assembly of metal-organic super-containers incorporating calixarenes

A new strategy to design container molecules is presented. Sulfonylcalix[4]arenes, which are synthetic macrocyclic containers, are used as building blocks that are combined with various metal ions and tricarboxylate ligands to construct metal-organic `super-containers` (MOSCs). These MOSCs possess both endo and exo cavities and thus mimic the structure of viruses. The synthesis of MOSCs is highly modular, robust, and predictable.
Inventors:
;
Issue Date:
OSTI Identifier:
1417589
Assignee:
South Dakota Board of Regents (Pierre, SD) CHO
Patent Number(s):
9,868,752
Application Number:
13/862,651
Contract Number:
FG02-08ER64624; EE0000270
Resource Relation:
Patent File Date: 2013 Apr 15
Research Org:
South Dakota Board of Regents, Pierre, SD (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 59 BASIC BIOLOGICAL SCIENCES

Other works cited in this record:

Supramolecular structures and process for making the same
patent, September 2001

Supramolecular structures and process for making the same
patent, September 2004

Adsorbent with multiple layers
patent, February 2009

Radon removal from gaseous xenon with activated charcoal
journal, January 2012
  • Abe, K.; Hieda, K.; Hiraide, K.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 661, Issue 1, p. 50-57
  • DOI: 10.1016/j.nima.2011.09.051

Excellent Correlation between Drug Release and Portal Size in Metalla-Cage Drug-Delivery Systems
journal, July 2011
  • Barry, Nicolas; Zava, Olivier; Dyson, Paul
  • Chemistry - A European Journal, Vol. 17, Issue 35, p. 9669-9677
  • DOI: 10.1002/chem.201003530

Pharmaceuticals and Endocrine Disrupting Compounds in U.S. Drinking Water
journal, December 2008
  • Benotti, Mark; Trenholm, Rebecca; Vanderford, Brett
  • Environmental Science & Technology, Vol. 43, Issue 3, p. 597-603
  • DOI: 10.1021/es801845a

A {Co32} Nanosphere Supported byp-tert-Butylthiacalix[4]arene
journal, August 2009
  • Bi, Yanfeng; Wang, Xiu-Teng; Liao, Wuping
  • Journal of the American Chemical Society, Vol. 131, Issue 33, p. 11650-11651
  • DOI: 10.1021/ja9034939

p-tert-Butylthiacalix[4]arene-supported high-nuclearity {Co24M8} (M = Mo or W) nanospheres and the hybrids with Keggin polyoxometalates
journal, January 2011
  • Bi, Yanfeng; Du, Shangchao; Liao, Wuping
  • Chemical Communications, Vol. 47, Issue 16, p. 4724-4726
  • DOI: 10.1039/C0CC05574C

The atomic pair distribution function: past and present
journal, January 2004
  • Billinge, Simon
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 219, Issue 3, p. 117-121
  • DOI: 10.1524/zkri.219.3.117.29094

Modular Assembly of Metal–Organic Supercontainers Incorporating Sulfonylcalixarenes
journal, April 2012
  • Dai, Feng-Rong; Wang, Zhenqiang
  • Journal of the American Chemical Society, Vol. 134, Issue 19, p. 8002-8005
  • DOI: 10.1021/ja300095j

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007
  • El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
  • Science, Vol. 316, Issue 5822, p. 268-272
  • DOI: 10.1126/science.1139915

Pairwise selection of guests in a cylindrical molecular capsule of nanometre dimensions
journal, August 1998
  • Rebek, Julius; Heinz, Thomas; Rudkevich, Dmitry
  • Nature, Vol. 394, Issue 6695, p. 764-766
  • DOI: 10.1038/29501

Synthesis of p-tert-Butylthiacalix[4]arene and its Inclusion Property
journal, March 2000

Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal ions
journal, October 1998

A Shape-Persistent Organic Molecular Cage with High Selectivity for the Adsorption of CO2 over N2
journal, July 2010
  • Jin, Yinghua; Voss, Bret ; Noble, Richard 
  • Angewandte Chemie International Edition, Vol. 49, Issue 36, p. 6348-6351
  • DOI: 10.1002/anie.201001517

Highly Symmetrical Tetranuclear Cluster Complexes Supported byp-tert-Butylsulfonylcalix[4]arene as a Cluster-Forming Ligand
journal, May 2006
  • Kajiwara, Takashi; Kobashi, Takanori; Shinagawa, Reiko
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 9, p. 1765-1770
  • DOI: 10.1002/ejic.200501086

Octalanthanide Wheels Supported byp-tert-Butylsulfonylcalix[4]arene
journal, March 2004
  • Kajiwara, Takashi; Wu, Hashen; Ito, Tasuku
  • Angewandte Chemie International Edition, Vol. 43, Issue 14, p. 1832-1835
  • DOI: 10.1002/anie.200353449

Transition metal and lanthanide cluster complexes constructed with thiacalix[n]arene and its derivatives
journal, July 2007
  • Kajiwara, Takashi; Iki, Nobuhiko; Yamashita, Masahiro
  • Coordination Chemistry Reviews, Vol. 251, Issue 13-14, p. 1734-1746
  • DOI: 10.1016/j.ccr.2007.01.001

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007
  • Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
  • DOI: 10.1021/ja076877g

Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base
journal, June 1997
  • Kumagai, Hitoshi; Hasegawa, Mitsuharu; Miyanari, Setsuko
  • Tetrahedron Letters, Vol. 38, Issue 22, p. 3971-3972
  • DOI: 10.1016/S0040-4039(97)00792-2

The Cucurbit[n]uril Family
journal, August 2005
  • Lagona, Jason; Mukhopadhyay, Pritam; Chakrabarti, Sriparna
  • Angewandte Chemie International Edition, Vol. 44, Issue 31, p. 4844-4870
  • DOI: 10.1002/anie.200460675

Metal–Organic Frameworks for Separations
journal, September 2011
  • Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
  • Chemical Reviews, Vol. 112, Issue 2, p. 869-932
  • DOI: 10.1021/cr200190s

Calixarene-Based Nanoscale Coordination Cages
journal, December 2011
  • Liu, Mei; Liao, Wuping; Hu, Chunhua
  • Angewandte Chemie International Edition, Vol. 51, Issue 7, p. 1585-1588
  • DOI: 10.1002/anie.201106732

A Salicylbisimine Cage Compound with High Surface Area and Selective CO2/CH4 Adsorption
journal, November 2010
  • Mastalerz, Michael; Schneider, Markus W.; Oppel, Iris M.
  • Angewandte Chemie International Edition, Vol. 50, Issue 5, p. 1046-1051
  • DOI: 10.1002/anie.201005301

Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2
journal, June 2010
  • Murray, Leslie J.; Dinca, Mircea; Yano, Junko
  • Journal of the American Chemical Society, Vol. 132, Issue 23, p. 7856-7857
  • DOI: 10.1021/ja1027925

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009
  • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
  • DOI: 10.1021/ja808853q

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006
  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Similar records in DOepatents and OSTI.GOV collections: