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Title: Modular assembly of metal-organic super-containers incorporating calixarenes

A new strategy to design container molecules is presented. Sulfonylcalix[4]arenes, which are synthetic macrocyclic containers, are used as building blocks that are combined with various metal ions and tricarboxylate ligands to construct metal-organic `super-containers` (MOSCs). These MOSCs possess both endo and exo cavities and thus mimic the structure of viruses. The synthesis of MOSCs is highly modular, robust, and predictable.
Inventors:
;
Issue Date:
OSTI Identifier:
1417589
Assignee:
South Dakota Board of Regents (Pierre, SD) CHO
Patent Number(s):
9,868,752
Application Number:
13/862,651
Contract Number:
FG02-08ER64624; EE0000270
Resource Relation:
Patent File Date: 2013 Apr 15
Research Org:
South Dakota Board of Regents, Pierre, SD (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 59 BASIC BIOLOGICAL SCIENCES

Works referenced in this record:

Radon removal from gaseous xenon with activated charcoal
journal, January 2012
  • Abe, K.; Hieda, K.; Hiraide, K.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 661, Issue 1, p. 50-57
  • DOI: 10.1016/j.nima.2011.09.051

Excellent Correlation between Drug Release and Portal Size in Metalla-Cage Drug-Delivery Systems
journal, July 2011
  • Barry, Nicolas; Zava, Olivier; Dyson, Paul
  • Chemistry - A European Journal, Vol. 17, Issue 35, p. 9669-9677
  • DOI: 10.1002/chem.201003530

Pharmaceuticals and Endocrine Disrupting Compounds in U.S. Drinking Water
journal, December 2008
  • Benotti, Mark; Trenholm, Rebecca; Vanderford, Brett
  • Environmental Science & Technology, Vol. 43, Issue 3, p. 597-603
  • DOI: 10.1021/es801845a

A {Co32} Nanosphere Supported byp-tert-Butylthiacalix[4]arene
journal, August 2009
  • Bi, Yanfeng; Wang, Xiu-Teng; Liao, Wuping
  • Journal of the American Chemical Society, Vol. 131, Issue 33, p. 11650-11651
  • DOI: 10.1021/ja9034939

p-tert-Butylthiacalix[4]arene-supported high-nuclearity {Co24M8} (M = Mo or W) nanospheres and the hybrids with Keggin polyoxometalates
journal, January 2011
  • Bi, Yanfeng; Du, Shangchao; Liao, Wuping
  • Chemical Communications, Vol. 47, Issue 16, p. 4724-4726
  • DOI: 10.1039/C0CC05574C

The atomic pair distribution function: past and present
journal, January 2004
  • Billinge, Simon
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 219, Issue 3, p. 117-121
  • DOI: 10.1524/zkri.219.3.117.29094

Modular Assembly of Metal–Organic Supercontainers Incorporating Sulfonylcalixarenes
journal, April 2012
  • Dai, Feng-Rong; Wang, Zhenqiang
  • Journal of the American Chemical Society, Vol. 134, Issue 19, p. 8002-8005
  • DOI: 10.1021/ja300095j

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007
  • El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
  • Science, Vol. 316, Issue 5822, p. 268-272
  • DOI: 10.1126/science.1139915

Pairwise selection of guests in a cylindrical molecular capsule of nanometre dimensions
journal, August 1998
  • Rebek, Julius; Heinz, Thomas; Rudkevich, Dmitry
  • Nature, Vol. 394, Issue 6695, p. 764-766
  • DOI: 10.1038/29501

Synthesis of p-tert-Butylthiacalix[4]arene and its Inclusion Property
journal, March 2000

Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal ions
journal, October 1998

A Shape-Persistent Organic Molecular Cage with High Selectivity for the Adsorption of CO2 over N2
journal, July 2010
  • Jin, Yinghua; Voss, Bret ; Noble, Richard 
  • Angewandte Chemie International Edition, Vol. 49, Issue 36, p. 6348-6351
  • DOI: 10.1002/anie.201001517

Highly Symmetrical Tetranuclear Cluster Complexes Supported byp-tert-Butylsulfonylcalix[4]arene as a Cluster-Forming Ligand
journal, May 2006
  • Kajiwara, Takashi; Kobashi, Takanori; Shinagawa, Reiko
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 9, p. 1765-1770
  • DOI: 10.1002/ejic.200501086

Octalanthanide Wheels Supported byp-tert-Butylsulfonylcalix[4]arene
journal, March 2004
  • Kajiwara, Takashi; Wu, Hashen; Ito, Tasuku
  • Angewandte Chemie International Edition, Vol. 43, Issue 14, p. 1832-1835
  • DOI: 10.1002/anie.200353449

Transition metal and lanthanide cluster complexes constructed with thiacalix[n]arene and its derivatives
journal, July 2007
  • Kajiwara, Takashi; Iki, Nobuhiko; Yamashita, Masahiro
  • Coordination Chemistry Reviews, Vol. 251, Issue 13-14, p. 1734-1746
  • DOI: 10.1016/j.ccr.2007.01.001

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007
  • Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
  • DOI: 10.1021/ja076877g

Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base
journal, June 1997
  • Kumagai, Hitoshi; Hasegawa, Mitsuharu; Miyanari, Setsuko
  • Tetrahedron Letters, Vol. 38, Issue 22, p. 3971-3972
  • DOI: 10.1016/S0040-4039(97)00792-2

The Cucurbit[n]uril Family
journal, August 2005
  • Lagona, Jason; Mukhopadhyay, Pritam; Chakrabarti, Sriparna
  • Angewandte Chemie International Edition, Vol. 44, Issue 31, p. 4844-4870
  • DOI: 10.1002/anie.200460675

Metal–Organic Frameworks for Separations
journal, September 2011
  • Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
  • Chemical Reviews, Vol. 112, Issue 2, p. 869-932
  • DOI: 10.1021/cr200190s

Calixarene-Based Nanoscale Coordination Cages
journal, December 2011
  • Liu, Mei; Liao, Wuping; Hu, Chunhua
  • Angewandte Chemie International Edition, Vol. 51, Issue 7, p. 1585-1588
  • DOI: 10.1002/anie.201106732

A Salicylbisimine Cage Compound with High Surface Area and Selective CO2/CH4 Adsorption
journal, November 2010
  • Mastalerz, Michael; Schneider, Markus W.; Oppel, Iris M.
  • Angewandte Chemie International Edition, Vol. 50, Issue 5, p. 1046-1051
  • DOI: 10.1002/anie.201005301

Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2
journal, June 2010
  • Murray, Leslie J.; Dinca, Mircea; Yano, Junko
  • Journal of the American Chemical Society, Vol. 132, Issue 23, p. 7856-7857
  • DOI: 10.1021/ja1027925

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009
  • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
  • DOI: 10.1021/ja808853q

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006
  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103