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Title: Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same

Abstract

Methods are described that include reacting a starting nanocrystal that includes a starting nanocrystal core and a covalently bound surface species to create an ion-exchangeable (IE) nanocrystal that includes a surface charge and a first ion-exchangeable (IE) surface ligand ionically bound to the surface charge, where the starting nanocrystal core includes a group IV element.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1416730
Patent Number(s):
9862841
Application Number:
15/388,415
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO)
Patent Classifications (CPCs):
C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Dec 22
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wheeler, Lance M., Nichols, Asa W., Chernomordik, Boris D., Anderson, Nicholas C., Beard, Matthew C., and Neale, Nathan R. Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same. United States: N. p., 2018. Web.
Wheeler, Lance M., Nichols, Asa W., Chernomordik, Boris D., Anderson, Nicholas C., Beard, Matthew C., & Neale, Nathan R. Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same. United States.
Wheeler, Lance M., Nichols, Asa W., Chernomordik, Boris D., Anderson, Nicholas C., Beard, Matthew C., and Neale, Nathan R. Tue . "Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same". United States. https://www.osti.gov/servlets/purl/1416730.
@article{osti_1416730,
title = {Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same},
author = {Wheeler, Lance M. and Nichols, Asa W. and Chernomordik, Boris D. and Anderson, Nicholas C. and Beard, Matthew C. and Neale, Nathan R.},
abstractNote = {Methods are described that include reacting a starting nanocrystal that includes a starting nanocrystal core and a covalently bound surface species to create an ion-exchangeable (IE) nanocrystal that includes a surface charge and a first ion-exchangeable (IE) surface ligand ionically bound to the surface charge, where the starting nanocrystal core includes a group IV element.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 09 00:00:00 EST 2018},
month = {Tue Jan 09 00:00:00 EST 2018}
}

Works referenced in this record:

Solution synthesis of germanium nanocrystals
patent, September 2009


Halogenated Supports and Supported Activators
patent-application, August 2001


Materials and methods for the preparation of nanocomposites
patent-application, November 2014


Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding
journal, November 2013

  • Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.
  • Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548
  • https://doi.org/10.1021/ja4086758

Illuminating Silicon Surface Hydrosilylation: An Unexpected Plurality of Mechanisms
journal, September 2013


Silicon Nanocrystals and Silicon-Polymer Hybrids: Synthesis, Surface Engineering, and Applications
journal, November 2015


Two-photon absorption of matrix-free Ge nanocrystals
journal, September 2006


Near-Infrared Photoluminescence Enhancement in Ge/CdS and Ge/ZnS Core/Shell Nanocrystals: Utilizing IV/II–VI Semiconductor Epitaxy
journal, July 2014


Toward a Mechanistic Understanding of Exciton-Mediated Hydrosilylation on Nanocrystalline Silicon
journal, December 2011


Colloidal Synthesis of Infrared-Emitting Germanium Nanocrystals
journal, March 2009


Plasma-Assisted Synthesis of Silicon Nanocrystal Inks
journal, September 2007


Thiol-Capped Germanium Nanocrystals: Preparation and Evidence for Quantum Size Effects
journal, March 2014


Size Controlled Synthesis of Germanium Nanocrystals by Hydride Reducing Agents and Their Biological Applications
journal, January 2010


Size and Bandgap Control in the Solution-Phase Synthesis of Near-Infrared-Emitting Germanium Nanocrystals
journal, November 2010


Surface Chemistry Exchange of Alloyed Germanium Nanocrystals: A Pathway Toward Conductive Group IV Nanocrystal Films
journal, January 2013


The synthesis of silicon and germanium quantum dots for biomedical applications
conference, March 2006


Hypervalent surface interactions for colloidal stability and doping of silicon nanocrystals
journal, July 2013


Silyl Radical Abstraction in the Functionalization of Plasma-Synthesized Silicon Nanocrystals
journal, September 2015


Synthesis and Characterization of Germanium/Si−Alkyl and Germanium/Silica Core−Shell Quantum Dots
journal, December 1999