Subnanometer to nanometer transition metal CO oxidation catalysts

Vajda, Stefan; Fortunelli, Alessandro; Yasumatsu, Hisato

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Title: Subnanometer to nanometer transition metal CO oxidation catalysts

Abstract

The present invention provides a catalyst defined in part by a conductive substrate; a film overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises between 8 and 11 atoms. Further provided is a catalyst defined in part by a conductive substrate; a layer overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises at least two metals.

Inventors:: Vajda, Stefan; Fortunelli, Alessandro; Yasumatsu, Hisato

Issue Date:: 2017-12-26

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1414917

Patent Number(s):: 9849445

Application Number:: 15/276,374

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/1021 - Platinum
B01D2255/1023 - Palladium
B01D2255/104 - Silver
B01D2255/106 - Gold
B01D2255/20746 - Cobalt
B01D2255/20753 - Nickel
B01D2255/2092 - Aluminium
B01D2255/30 - Silica
B01D2255/9202 - Linear dimensions
B01D53/864 - {Removing carbon monoxide or hydrocarbons}
B01D53/944 - {Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J21/04 - Alumina
B01J21/06 - Silicon, titanium, zirconium or hafnium
B01J23/42 - Platinum
B01J23/44 - Palladium
B01J23/462 - {Ruthenium}
B01J23/50 - Silver
B01J23/52 - Gold
B01J23/8913 - {Cobalt and noble metals}
B01J23/892 - {Nickel and noble metals}
B01J35/0013 - {Colloids}
B01J35/006 - {metal crystallite size}
B01J35/02 - Solids
B01J35/10 - characterised by their surface properties or porosity
B01J37/348 - {Electrochemical processes, e.g. electrochemical deposition or anodisation}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/50 - Carbon dioxide

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Sep 26

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Vajda, Stefan, Fortunelli, Alessandro, and Yasumatsu, Hisato. Subnanometer to nanometer transition metal CO oxidation catalysts.  United States: N. p., 2017. 
        Web.

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                    Vajda, Stefan, Fortunelli, Alessandro, & Yasumatsu, Hisato. Subnanometer to nanometer transition metal CO oxidation catalysts.  United States.

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                    Vajda, Stefan, Fortunelli, Alessandro, and Yasumatsu, Hisato. Tue .  
        "Subnanometer to nanometer transition metal CO oxidation catalysts".  United States.  https://www.osti.gov/servlets/purl/1414917.

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@article{osti_1414917,

  title        = {Subnanometer to nanometer transition metal CO oxidation catalysts},

  author       = {Vajda, Stefan and Fortunelli, Alessandro and Yasumatsu, Hisato},

  abstractNote = {The present invention provides a catalyst defined in part by a conductive substrate; a film overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises between 8 and 11 atoms. Further provided is a catalyst defined in part by a conductive substrate; a layer overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises at least two metals.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {12}

}

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Works referenced in this record:

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts
patent, March 2012

Vajda, Stefan; Pellin, Michael J.; Elam, Jeffrey W.
US Patent Document 8,143,189
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8143189

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts
patent, April 2012

Vajda, Stefan; Pellin, Michael J.; Elam, Jeffrey W.
US Patent Document 8,148,293
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8148293

Hydro-oxidation process using a catalyst prepared from a gold cluster complex
patent, October 2012

Dhingra, Sandeep; Schroden, Rick C.; Watson, Keith J.
US Patent Document 8,288,311
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8288311

Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument
journal, May 2014

Yin, C.; Tyo, E.; Kuchta, K.
The Journal of Chemical Physics, Vol. 140, Issue 17, Article No. 174201
https://doi.org/10.1063/1.4871799

Generation of intense and cold beam of Pt-Ag bi-element cluster ions having single-composition
journal, March 2011

Yasumatsu, H.
The European Physical Journal D, Vol. 63, Issue 2, p. 195-200
https://doi.org/10.1140/epjd/e2011-10530-9

Pd nanoparticle enhanced re-oxidation of non-stoichiometric TiO₂: STM imaging of spillover and a new form of SMSI
journal, January 1999

Bennett, R. A.; Stone, P.; Bowker, M.
Catalysis Letters, Vol. 59, Issue 2-4, p. 99-105
https://doi.org/10.1023/A:1019053512230

Effect of the TiO₂ Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters
journal, February 2012

Bonanni, Simon; Aït-Mansour, Kamel; Harbich, Wolfgang
Journal of the American Chemical Society, Vol. 134, Issue 7, p. 3445-3450
https://doi.org/10.1021/ja2098854

Size-Dependent Oxygen Activation Efficiency over Pd_n/TiO₂(110) for the CO Oxidation Reaction
journal, September 2010

Kaden, William E.; Kunkel, William A.; Kane, Matt D.
Journal of the American Chemical Society, Vol. 132, Issue 38, p. 13097-13099
https://doi.org/10.1021/ja103347v

Size-dependent catalytic activity and geometries of size-selected Pt clusters on TiO₂(110) surfaces
journal, January 2011

Watanabe, Yoshihide; Wu, Xingyang; Hirata, Hirohito
Catalysis Science & Technology, Vol. 1, Issue 8, p. 1490-1495
https://doi.org/10.1039/c1cy00204j

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Similar Records

Title: Subnanometer to nanometer transition metal CO oxidation catalysts

Abstract

Citation Formats

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts patent, March 2012

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts patent, April 2012

Hydro-oxidation process using a catalyst prepared from a gold cluster complex patent, October 2012

Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument journal, May 2014

Generation of intense and cold beam of Pt-Ag bi-element cluster ions having single-composition journal, March 2011

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Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters journal, February 2012

Size-Dependent Oxygen Activation Efficiency over Pdn/TiO2(110) for the CO Oxidation Reaction journal, September 2010

Size-dependent catalytic activity and geometries of size-selected Pt clusters on TiO2(110) surfaces journal, January 2011

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts
patent, March 2012

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts
patent, April 2012

Hydro-oxidation process using a catalyst prepared from a gold cluster complex
patent, October 2012

Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument
journal, May 2014

Generation of intense and cold beam of Pt-Ag bi-element cluster ions having single-composition
journal, March 2011

Pd nanoparticle enhanced re-oxidation of non-stoichiometric TiO₂: STM imaging of spillover and a new form of SMSI
journal, January 1999

Effect of the TiO₂ Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters
journal, February 2012

Size-Dependent Oxygen Activation Efficiency over Pd_n/TiO₂(110) for the CO Oxidation Reaction
journal, September 2010

Size-dependent catalytic activity and geometries of size-selected Pt clusters on TiO₂(110) surfaces
journal, January 2011