Process-based approach for the detection of CO2 injectate leakage
Abstract
The present invention includes a method for distinguishing between a natural source of deep gas and gas leaking from a CO.sub.2 storage reservoir at a near surface formation comprising: obtaining one or more surface or near surface geological samples; measuring a CO.sub.2, an O.sub.2, a CH.sub.4, and an N.sub.2 level from the surface or near surface geological sample; determining the water vapor content at or above the surface or near surface geological samples; normalizing the gas mixture of the CO.sub.2, the O.sub.2, the CH.sub.4, the N.sub.2 and the water vapor content to 100% by volume or 1 atmospheric total pressure; determining: a ratio of CO.sub.2 versus N.sub.2; and a ratio of CO.sub.2 to N.sub.2, wherein if the ratio is greater than that produced by a natural source of deep gas CO.sub.2 or deep gas methane oxidizing to CO.sub.2, the ratio is indicative of gas leaking from a CO.sub.2 storage reservoir.
- Inventors:
- Issue Date:
- Research Org.:
- Board of Regents, The University of Texas System, Austin, TX (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1408908
- Patent Number(s):
- 9816972
- Application Number:
- 14/317,836
- Assignee:
- Board of Regents, The University of Texas System (Austin, TX)
- Patent Classifications (CPCs):
-
G - PHYSICS G01 - MEASURING G01M - TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- DOE Contract Number:
- FG04-90AL65847; FG26-05NT42590
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Jun 27
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES
Citation Formats
Romanak, Katherine, and Bennett, Philip C. Process-based approach for the detection of CO2 injectate leakage. United States: N. p., 2017.
Web.
Romanak, Katherine, & Bennett, Philip C. Process-based approach for the detection of CO2 injectate leakage. United States.
Romanak, Katherine, and Bennett, Philip C. Tue .
"Process-based approach for the detection of CO2 injectate leakage". United States. https://www.osti.gov/servlets/purl/1408908.
@article{osti_1408908,
title = {Process-based approach for the detection of CO2 injectate leakage},
author = {Romanak, Katherine and Bennett, Philip C.},
abstractNote = {The present invention includes a method for distinguishing between a natural source of deep gas and gas leaking from a CO.sub.2 storage reservoir at a near surface formation comprising: obtaining one or more surface or near surface geological samples; measuring a CO.sub.2, an O.sub.2, a CH.sub.4, and an N.sub.2 level from the surface or near surface geological sample; determining the water vapor content at or above the surface or near surface geological samples; normalizing the gas mixture of the CO.sub.2, the O.sub.2, the CH.sub.4, the N.sub.2 and the water vapor content to 100% by volume or 1 atmospheric total pressure; determining: a ratio of CO.sub.2 versus N.sub.2; and a ratio of CO.sub.2 to N.sub.2, wherein if the ratio is greater than that produced by a natural source of deep gas CO.sub.2 or deep gas methane oxidizing to CO.sub.2, the ratio is indicative of gas leaking from a CO.sub.2 storage reservoir.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {11}
}
Works referenced in this record:
Method of detecting leakage from geologic formations used to sequester CO2
patent, April 2010
- White, Curt; Wells, Arthur; Diehl, J. Rodney
- US Patent Document 7,704,746
System and method for determining flux of isotopologues
patent, March 2014
- Nickerson, Nicholas R.; Egan, Jocelyn Elizabeth; Risk, David A.
- US Patent Document 8,681,336
Gas flux measurement using traps
patent, May 2014
- Zimbron, Julio; Sale, Thomas C.; Lyverse, Mark
- US Patent Document 8,714,034
System and method for monitoring unsaturated zone gas and near-surface atmosphere in real time by using isotope analyzer
patent, July 2014
- Chae, Gi-Tak; Sung, Ki-Sung; Kim, Jeong-Chan
- US Patent Document 8,772,720
Measurement of Carbon Capture Efficiency and Stored Carbon Leakage
patent-application, September 2010
- Keeling, Ralph F.; Dubey, Manvendra K.
- US Patent Document 12/730031; 20100241363
Apparatus for Detecting Carbon Dioxide Concentration in Unsaturated Zone, Carbon Dioxide Concentration Monitoring System, and Carbon Dioxide Concentration Monitoring Method
patent-application, March 2011
- Kim, Jeong-Chan; Sung, Ki-Sung
- US Patent Document 12/861978; 20110068940
Monitoring of fluidārock interaction and CO2 storage through produced fluid sampling at the Weyburn CO2-injection enhanced oil recovery site, Saskatchewan, Canada
journal, June 2005
- Emberley, S.; Hutcheon, I.; Shevalier, M.
- Applied Geochemistry, Vol. 20, Issue 6, p. 1131-1157
Nitrate reduction during ground-water recharge, Southern High Plains, Texas
journal, January 2000
- Fryar, Alan E.; Macko, Stephen A.; Mullican III, William F.
- Journal of Contaminant Hydrology, Vol. 40, Issue 4, p. 335-363
Soil and fumarole gases of Mount Etna: geochemistry and relations with volcanic activity
journal, May 1998
- Giammanco, S.; Inguaggiato, S.; Valenza, M.
- Journal of Volcanology and Geothermal Research, Vol. 81, Issue 3-4, p. 297-310
Depositional facies of the Miocene-Pliocene Ogallala Formation, northwestern Texas and eastern New Mexico
journal, January 1988
- Gustavson, Thomas C.; Winkler, Dale A.
- Geology, Vol. 16, Issue 3, p. 203-206
Separating root and soil microbial contributions to soil respiration: A review of methods and observations
journal, January 2000
- Hanson, P. J.; Edwards, N. T.; Garten, C. T.
- Biogeochemistry, Vol. 48, Issue 1, p. 115-146
Changes in the chemistry of shallow groundwater related to the 2008 injection of CO2 at the ZERT field site, Bozeman, Montana
journal, December 2009
- Kharaka, Yousif K.; Thordsen, James J.; Kakouros, Evangelos
- Environmental Earth Sciences, Vol. 60, Issue 2, p. 273-284
Comparison of surface and near-surface geochemical methods for detection of gas microseepage from carbon dioxide sequestration
journal, November 2011
- Klusman, Ronald W.
- International Journal of Greenhouse Gas Control, Vol. 5, Issue 6, p. 1369-1392
Computer modeling of methanotrophic oxidation of hydrocarbons in the unsaturated zone from an enhanced oil recovery/sequestration project, Rangely, Colorado, USA
journal, December 2003
- Klusman, Ronald W.
- Applied Geochemistry, Vol. 18, Issue 12, p. 1839-1852
Detailed compositional analysis of gas seepage at the National Carbon Storage Test Site, Teapot Dome, Wyoming, USA
journal, September 2006
- Klusman, Ronald W.
- Applied Geochemistry, Vol. 21, Issue 9, p. 1498-1521
Rate measurements and detection of gas microseepage to the atmosphere from an enhanced oil recovery/sequestration project, Rangely, Colorado, USA
journal, December 2003
- Klusman, Ronald W.
- Applied Geochemistry, Vol. 18, Issue 12, p. 1825-1838
Experimental determination of nitrogen kinetic isotope fractionation: Some principles; illustration for the denitrification and nitrification processes
journal, October 1981
- Mariotti, A.; Germon, J. C.; Hubert, P.
- Plant and Soil, Vol. 62, Issue 3, p. 413-430
Soil-Gas Sampling and Misinterpretation
journal, June 1988
- Marrin, Donn L.
- Groundwater Monitoring & Remediation, Vol. 8, Issue 2, p. 51-54
Simultaneous Determination of Argon and Nitrogen
journal, September 1995
- Martin, Glen E.; Snow, Daniel D.; Kim, Euisik
- Ground Water, Vol. 33, Issue 5, p. 781-785
Shallow Subsurface Characterization of Gas Transport in a Playa Wetland
journal, November 1998
- Nicot, Jean-Philippe; Bennett, Philip C.
- Journal of Environmental Engineering, Vol. 124, Issue 11, p. 1038-1046
Biodegradation of hydrocarbon vapors in the unsaturated zone
journal, April 1991
- Ostendorf, David W.; Kampbell, Don H.
- Water Resources Research, Vol. 27, Issue 4, p. 453-462
Playa-lake basins on the Southern High Plains of Texas and New Mexico: Part I. Hydrologic, geomorphic, and geologic evidence for their development
journal, January 1987
- Osterkamp, W. R.; Wood, Warren W.
- Geological Society of America Bulletin, Vol. 99, Issue 2, p. 215-223
The application and interpretation of Keeling plots in terrestrial carbon cycle research
journal, March 2003
- Pataki, D. E.; Ehleringer, J. R.; Flanagan, L. B.
- Global Biogeochemical Cycles, Vol. 17, Issue 1, Article No. 1022
Potential for a Process-based Monitoring Method above Geologic Carbon Storage Sites using Dissolved Gases in Freshwater Aquifers
journal, January 2013
- Romanak, Katherine; Dobeck, Laura; Dixon, Tim
- Procedia Earth and Planetary Science, Vol. 7, p. 746-749
Processābased approach to CO2 leakage detection by vadose zone gas monitoring at geologic CO2 storage sites
journal, August 2012
- Romanak, K. D.; Bennett, P. C.; Yang, Changbing
- Geophysical Research Letters, Vol. 39, Issue 15, Article No. L15405
Multiple origins of methane in the Earth
journal, December 1988
- Schoell, Martin
- Chemical Geology, Vol. 71, Issue 1-3, p. 1-10
The Occurrence of Ethylene in Anaerobic Soil
journal, December 1971
- Smith, K. A.; Restall, S. W. F.
- Journal of Soil Science, Vol. 22, Issue 4, p. 430-443
A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models
journal, December 2009
- Spangler, Lee H.; Dobeck, Laura M.; Repasky, Kevin S.
- Environmental Earth Sciences, Vol. 60, Issue 2, p. 227-239
Near-surface monitoring for the ZERT shallow CO2 injection project
journal, December 2009
- Strazisar, Brian R.; Wells, Arthur W.; Diehl, J. Rodney
- International Journal of Greenhouse Gas Control, Vol. 3, Issue 6, p. 736-744
Carbon dioxide retention and carbon exchange on unsaturated Quaternary sediments
journal, August 1990
- Striegl, Robert G.; Armstrong, David E.
- Geochimica et Cosmochimica Acta, Vol. 54, Issue 8, p. 2277-2283
Gas maturity and alteration systematics across the Western Canada Sedimentary Basin from four mud gas isotope depth profiles
journal, December 2006
- Tilley, Barbara; Muehlenbachs, Karlis
- Organic Geochemistry, Vol. 37, Issue 12, p. 1857-1868
Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane
journal, September 1999
- Whiticar, Michael J.
- Chemical Geology, Vol. 161, Issue 1-3, p. 291-314
Greensites and brownsites: Implications for CO2 sequestration characterization, risk assessment, and monitoring
journal, November 2013
- Wolaver, Brad D.; Hovorka, Susan D.; Smyth, Rebecca C.
- International Journal of Greenhouse Gas Control, Vol. 19, p. 49-62
Modeling CO2 Release Experiment in the Shallow Subsurface and Sensitivity Analysis
journal, July 2013
- Yang, C.; Romanak, K.; Hovorka, S.
- Environmental & Engineering Geoscience, Vol. 19, Issue 3, p. 207-220
Near-Surface Monitoring of Large-Volume CO2 Injection at Cranfield: Early Field Test of SECARB Phase III
journal, January 2013
- Yang, Changbing; Romanak, Katherine; Hovorka, Susan D.
- SPE Journal, Vol. 18, Issue 03, p. 486-494
Noble gas tracing of groundwater/coalbed methane interaction in the San Juan Basin, USA
journal, December 2005
- Zhou, Zheng; Ballentine, Chris J.; Kipfer, Rolf
- Geochimica et Cosmochimica Acta, Vol. 69, Issue 23, p. 5413-5428