Nitrogen-doped carbon aerogels for electrical energy storage
Abstract
Disclosed here is a method for making a nitrogen-doped carbon aerogel, comprising: preparing a reaction mixture comprising formaldehyde, at least one nitrogen-containing resorcinol analog, at least one catalyst, and at least one solvent; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel; and thermally annealing the dry gel to produce the nitrogen-doped carbon aerogel. Also disclosed is a nitrogen-doped carbon aerogel obtained according to the method and a supercapacitor comprising the nitrogen-doped carbon aerogel.
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1397269
- Patent Number(s):
- 9776156
- Application Number:
- 14/820,397
- Assignee:
- Lawrence Livermore National Security, LLC
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Aug 06
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE
Citation Formats
Campbell, Patrick, Montalvo, Elizabeth, Baumann, Theodore F., Biener, Juergen, Merrill, Matthew, Reed, Eric W., and Worsley, Marcus A. Nitrogen-doped carbon aerogels for electrical energy storage. United States: N. p., 2017.
Web.
Campbell, Patrick, Montalvo, Elizabeth, Baumann, Theodore F., Biener, Juergen, Merrill, Matthew, Reed, Eric W., & Worsley, Marcus A. Nitrogen-doped carbon aerogels for electrical energy storage. United States.
Campbell, Patrick, Montalvo, Elizabeth, Baumann, Theodore F., Biener, Juergen, Merrill, Matthew, Reed, Eric W., and Worsley, Marcus A. Tue .
"Nitrogen-doped carbon aerogels for electrical energy storage". United States. https://www.osti.gov/servlets/purl/1397269.
@article{osti_1397269,
title = {Nitrogen-doped carbon aerogels for electrical energy storage},
author = {Campbell, Patrick and Montalvo, Elizabeth and Baumann, Theodore F. and Biener, Juergen and Merrill, Matthew and Reed, Eric W. and Worsley, Marcus A.},
abstractNote = {Disclosed here is a method for making a nitrogen-doped carbon aerogel, comprising: preparing a reaction mixture comprising formaldehyde, at least one nitrogen-containing resorcinol analog, at least one catalyst, and at least one solvent; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel; and thermally annealing the dry gel to produce the nitrogen-doped carbon aerogel. Also disclosed is a nitrogen-doped carbon aerogel obtained according to the method and a supercapacitor comprising the nitrogen-doped carbon aerogel.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {10}
}
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Works referenced in this record:
Polyimide aerogels, carbon aerogels, and metal carbide aerogels and methods of making same
patent, July 2006
- Rhine, Wendell E.; Wang, Jing; Begag, Redouane
- US Patent Document 7,074,880
Carbon Aerogels and Monoliths: Control of Porosity and Nanoarchitecture via Sol–Gel routes
journal, September 2013
- Antonietti, Markus; Fechler, Nina; Fellinger, Tim-Patrick
- Chemistry of Materials, Vol. 26, Issue 1, p. 196-210
Carbohydrate-Derived Nanoarchitectures: On a Synergistic Effect Toward an Improved Performance in Lithium–Sulfur Batteries
journal, October 2013
- Brun, Nicolas; Sakaushi, Ken; Eckert, Jürgen
- ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 2, p. 126-129
Enhanced electrochemical capacitance of nitrogen-doped carbon gels synthesized by microwave-assisted polymerization of resorcinol and formaldehyde
journal, July 2008
- Kang, Kyung Yeon; Hong, Suk Joon; Lee, Burtrand I.
- Electrochemistry Communications, Vol. 10, Issue 7, p. 1105-1108
Heteroatom-doped carbon gels from phenols and heterocyclic aldehydes: Sulfur-doped carbon xerogels
journal, August 2014
- Kiciński, Wojciech; Dziura, Aleksandra
- Carbon, Vol. 75
Nitric Acid Activated Carbon Aerogels for Supercapacitors
journal, February 2013
- Li, Ya Jie; Ni, Xing Yuan; Shen, Jun
- Applied Mechanics and Materials, Vol. 302, p. 158-164
Electrochemical performance of carbon gels with variable surface chemistry and physics
journal, August 2012
- Moreno-Castilla, Carlos; Dawidziuk, Marta B.; Carrasco-Marín, Francisco
- Carbon, Vol. 50, Issue 9
Activated nitrogen-enriched carbon/carbon aerogel nanocomposites for supercapacitor applications
journal, December 2009
- Qin, Chuan-li; Lu, Xing; Yin, Ge-ping
- Transactions of Nonferrous Metals Society of China, Vol. 19
Study of activated nitrogen-enriched carbon and nitrogen-enriched carbon/carbon aerogel composite as cathode materials for supercapacitors
journal, March 2011
- Qin, Chuanli; Lu, Xing; Yin, Geping
- Materials Chemistry and Physics, Vol. 126, Issue 1-2
Pyrolysis of N-doped organic aerogels with relation to sorption properties
journal, October 2011
- Veselá, Petra; Slovák, Václav
- Journal of Thermal Analysis and Calorimetry, Vol. 108, Issue 2, p. 475-480
Novel preparation of nitrogen-doped graphene in various forms with aqueous ammonia under mild conditions
journal, January 2012
- Wang, Gang; Jia, Li-Tao; Zhu, Yan
- RSC Advances, Vol. 2, Issue 30
Design and synthesis of carbonized polypyrrole-coated graphene aerogel acting as an efficient metal-free catalyst for oxygen reduction
journal, January 2014
- Wei, Hua; Xu, Mao-Wen; Bao, Shu-Juan
- RSC Adv., Vol. 4, Issue 33, p. 16979-16984
A Versatile, Ultralight, Nitrogen-Doped Graphene Framework
journal, October 2012
- Zhao, Yang; Hu, Chuangang; Hu, Yue
- Angewandte Chemie, Vol. 124, Issue 45, p. 11533-11537