Title: Metallated metal-organic frameworks

Abstract

Porous metal-organic frameworks (MOFs) and metallated porous MOFs are provided. Also provided are methods of metallating porous MOFs using atomic layer deposition and methods of using the metallated MOFs as catalysts and in remediation applications.

Inventors:

Bury, Wojciech; Farha, Omar K.; Hupp, Joseph T.; Mondloch, Joseph E.

Issue Date:

Tue Aug 22 00:00:00 EDT 2017

Research Org.:

INTERNATIONAL AIDS VACCINE INITIATIVE, New York, NY (United States)

Sponsoring Org.:

USDOE

OSTI Identifier:

1376216

Patent Number(s):

9738665

Application Number:

15/374,218

Assignee:

Northwestern University

Patent Classifications (CPCs):

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B - PERFORMING OPERATIONS B09 - DISPOSAL OF SOLID WASTE B09C - RECLAMATION OF CONTAMINATED SOIL

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J20/226 - {Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
B01J20/3236 - {containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts}
B01J2231/342 - Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
B01J2531/31 - Aluminium
B01J2531/48 - Zirconium
B01J31/1691 - {Coordination polymers, e.g. metal-organic frameworks [MOF]
B01J31/2239 - {Bridging ligands, e.g. OAc in Cr2

B - PERFORMING OPERATIONS B09 - DISPOSAL OF SOLID WASTE B09C - RECLAMATION OF CONTAMINATED SOIL

B09C1/08 - chemically

C - CHEMISTRY C02 - TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE C02F - TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F1/281 - {using inorganic sorbents}
C02F1/285 - {using synthetic organic sorbents}
C02F1/288 - {using composite sorbents, e.g. coated, impregnated, multi-layered}
C02F2101/20 - Heavy metals or heavy metal compounds

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C253/30 - by reactions not involving the formation of cyano groups
C07C255/41 - the carbon skeleton being further substituted by carboxyl groups, other than cyano groups

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C07F7/003 - {without C-Metal linkages}

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

C23C16/045 - {Coating cavities or hollow spaces, e.g. interior of tubes
C23C16/18 - from metallo-organic compounds
C23C16/45555 - {applied in non-semiconductor technology}

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DOE Contract Number:  

AC05-06OR23100

Resource Type:

Patent

Resource Relation:

Patent File Date: 2016 Dec 09

Country of Publication:

United States

Language:

English

Subject:

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY