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Title: Metal-organic framework catalysts for selective cleavage of aryl-ether bonds

Abstract

The present invention relates to methods of employing a metal-organic framework (MOF) as a catalyst for cleaving chemical bonds. In particular instances, the MOF results in selective bond cleavage that results in hydrogenolyzis. Furthermore, the MOF catalyst can be reused in multiple cycles. Such MOF-based catalysts can be useful, e.g., to convert biomass components.

Inventors:
;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1373909
Patent Number(s):
9718748
Application Number:
14/991,734
Assignee:
Sandia Corporation
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 2017 Jan 08
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Allendorf, Mark D., and Stavila, Vitalie. Metal-organic framework catalysts for selective cleavage of aryl-ether bonds. United States: N. p., 2017. Web.
Allendorf, Mark D., & Stavila, Vitalie. Metal-organic framework catalysts for selective cleavage of aryl-ether bonds. United States.
Allendorf, Mark D., and Stavila, Vitalie. Tue . "Metal-organic framework catalysts for selective cleavage of aryl-ether bonds". United States. https://www.osti.gov/servlets/purl/1373909.
@article{osti_1373909,
title = {Metal-organic framework catalysts for selective cleavage of aryl-ether bonds},
author = {Allendorf, Mark D. and Stavila, Vitalie},
abstractNote = {The present invention relates to methods of employing a metal-organic framework (MOF) as a catalyst for cleaving chemical bonds. In particular instances, the MOF results in selective bond cleavage that results in hydrogenolyzis. Furthermore, the MOF catalyst can be reused in multiple cycles. Such MOF-based catalysts can be useful, e.g., to convert biomass components.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {8}
}

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