System and process for polarity swing assisted regeneration of gas selective capture liquids

Heldebrant, David J.; Tegrotenhuis, Ward E.; Freeman, Charles J.; Elliott, Michael L.; Koech, Phillip K.; Humble, Paul H.; Zheng, Feng; Zhang, Jian

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Title: System and process for polarity swing assisted regeneration of gas selective capture liquids

Abstract

A polarity swing-assisted regeneration (PSAR) process is disclosed for improving the efficiency of releasing gases chemically bound to switchable ionic liquids. Regeneration of the SWIL involves addition of a quantity of non-polar organic compound as an anti-solvent to destabilize the SWIL, which aids in release of the chemically bound gas. The PSAR decreases gas loading of a SWIL at a given temperature and increases the rate of gas release compared to heating in the absence of anti-solvent.

Inventors:: Heldebrant, David J.; Tegrotenhuis, Ward E.; Freeman, Charles J.; Elliott, Michael L.; Koech, Phillip K.; Humble, Paul H.; Zheng, Feng; Zhang, Jian

Issue Date:: 2017-07-18

Research Org.:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1372056

Patent Number(s):: 9707508

Application Number:: 13/224,680

Assignee:: BATTELLE MEMORIAL INSTITUTE

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02B - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2252/30 - Ionic liquids and zwitter-ions
B01D2257/308 - Carbonoxysulfide COS
B01D2258/0233 - from cement factories
B01D2258/0283 - Flue gases
B01D53/1425 - {Regeneration of liquid absorbents}
B01D53/1475 - {Removing carbon dioxide}
B01D53/1481 - {Removing sulfur dioxide or sulfur trioxide}
B01D53/1493 - {Selection of liquid materials for use as absorbents}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02B - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
Y02B30/52 - Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/129 - Energy recovery

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DOE Contract Number:: AC05-76RL01830

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Sep 02

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Heldebrant, David J., Tegrotenhuis, Ward E., Freeman, Charles J., Elliott, Michael L., Koech, Phillip K., Humble, Paul H., Zheng, Feng, and Zhang, Jian. System and process for polarity swing assisted regeneration of gas selective capture liquids.  United States: N. p., 2017. 
        Web.

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                    Heldebrant, David J., Tegrotenhuis, Ward E., Freeman, Charles J., Elliott, Michael L., Koech, Phillip K., Humble, Paul H., Zheng, Feng, & Zhang, Jian. System and process for polarity swing assisted regeneration of gas selective capture liquids.  United States.

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                    Heldebrant, David J., Tegrotenhuis, Ward E., Freeman, Charles J., Elliott, Michael L., Koech, Phillip K., Humble, Paul H., Zheng, Feng, and Zhang, Jian. Tue .  
        "System and process for polarity swing assisted regeneration of gas selective capture liquids".  United States.  https://www.osti.gov/servlets/purl/1372056.

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@article{osti_1372056,

  title        = {System and process for polarity swing assisted regeneration of gas selective capture liquids},

  author       = {Heldebrant, David J. and Tegrotenhuis, Ward E. and Freeman, Charles J. and Elliott, Michael L. and Koech, Phillip K. and Humble, Paul H. and Zheng, Feng and Zhang, Jian},

  abstractNote = {A polarity swing-assisted regeneration (PSAR) process is disclosed for improving the efficiency of releasing gases chemically bound to switchable ionic liquids. Regeneration of the SWIL involves addition of a quantity of non-polar organic compound as an anti-solvent to destabilize the SWIL, which aids in release of the chemically bound gas. The PSAR decreases gas loading of a SWIL at a given temperature and increases the rate of gas release compared to heating in the absence of anti-solvent.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {7}

}

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Organic liquid CO₂ capture agents with high gravimetric CO₂ capacity
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Similar Records

Title: System and process for polarity swing assisted regeneration of gas selective capture liquids

Abstract

Citation Formats

Method of removing acidic gases from gaseous mixtures patent, December 1964

Separation Process patent, November 1966

Capture and release of mixed acid gasses with binding organic liquids patent, September 2010

System and process for capture of H2S from gaseous process streams and process for regeneration of the capture agent patent, February 2014

Switchable solvents and methods of use thereof patent-application, March 2008

Capture and Release of Acid-Gasses with Acid-Gas Binding Organic Compounds patent-application, September 2009

Removal Of Acid Gases By Means Of An Absorbent Comprising A Stripping Aid patent-application, December 2010

Chemically selective gas sweetening without thermal-swing regeneration journal, January 2011

Green chemistry: Reversible nonpolar-to-polar solvent journal, August 2005

Performance of single-component CO2-binding organic liquids (CO2BOLs) for post combustion CO2 capture journal, July 2011

Organic liquid CO2 capture agents with high gravimetric CO2 capacity journal, January 2008

Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures journal, February 2008

CO2 Capture by a Task-Specific Ionic Liquid journal, February 2002

Equimolar CO2 Absorption by Anion-Functionalized Ionic Liquids journal, February 2010

Reversible and robust CO2 capture by equimolar task-specific ionic liquid–superbase mixtures journal, January 2010

One-component, switchable ionic liquids derived from siloxylated amines journal, January 2009

Single component, reversible ionic liquids for energy applications journal, June 2010

A reversible zwitterionic SO2-binding organic liquid journal, January 2010

Reversible Uptake of COS, CS2, and SO2: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions journal, August 2009

IR spectra of H2S isolated in free-standing crystals of Kr and Xe journal, August 1998

The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study journal, June 1983

Method of removing acidic gases from gaseous mixtures
patent, December 1964

Separation Process
patent, November 1966

Capture and release of mixed acid gasses with binding organic liquids
patent, September 2010

System and process for capture of H2S from gaseous process streams and process for regeneration of the capture agent
patent, February 2014

Switchable solvents and methods of use thereof
patent-application, March 2008

Capture and Release of Acid-Gasses with Acid-Gas Binding Organic Compounds
patent-application, September 2009

Removal Of Acid Gases By Means Of An Absorbent Comprising A Stripping Aid
patent-application, December 2010

Chemically selective gas sweetening without thermal-swing regeneration
journal, January 2011

Green chemistry: Reversible nonpolar-to-polar solvent
journal, August 2005

Performance of single-component CO2-binding organic liquids (CO2BOLs) for post combustion CO2 capture
journal, July 2011

Organic liquid CO₂ capture agents with high gravimetric CO₂ capacity
journal, January 2008

Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures
journal, February 2008

CO₂ Capture by a Task-Specific Ionic Liquid
journal, February 2002

Equimolar CO₂ Absorption by Anion-Functionalized Ionic Liquids
journal, February 2010

Reversible and robust CO₂ capture by equimolar task-specific ionic liquid–superbase mixtures
journal, January 2010

One-component, switchable ionic liquids derived from siloxylated amines
journal, January 2009

Single component, reversible ionic liquids for energy applications
journal, June 2010

A reversible zwitterionic SO₂-binding organic liquid
journal, January 2010

Reversible Uptake of COS, CS₂, and SO₂: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions
journal, August 2009

IR spectra of H₂S isolated in free-standing crystals of Kr and Xe
journal, August 1998

The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study
journal, June 1983