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Title: First-row transition metal hydrogenation and hydrosilylation catalysts

Transition metal compounds, and specifically transition metal compounds having a tetradentate and/or pentadentate supporting ligand are described, together with methods for the preparation thereof and the use of such compounds as hydrogenation and/or hydrosilylation catalysts.
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Issue Date:
OSTI Identifier:
Arizona Board of Regents on Behalf of Arizona State University DOESC
Patent Number(s):
Application Number:
Contract Number:
Resource Relation:
Patent File Date: 2014 Jun 11
Research Org:
Arizona Board of Regents on Behalf of Arizona State University, Scottsdale, AZ (United States)
Sponsoring Org:
Country of Publication:
United States

Other works cited in this record:

Platinum-Olefin Complex Catalyzed Addition of Hydrogen- And Alkenyl-Sub-Stituted Siloxanes
patent, December 1964

Organosilicon Process Using a Chloroplatinic Acid Reaction Product As The Catalyst
patent, November 1965

Nickel Complex Olefin Dimerization
patent, July 1971

Epithio Dienamides
patent, November 1973

L-Dopa process and intermediates
patent, January 1977

Modification of DNA and oligonucleotides using metal complexes of polyaza ligands
patent, December 1993

Hydrosilylation catalysts
patent, August 2012

Hydrosilylation catalysts
patent, April 2013

Hydrosilylation Catalysts
patent-application, January 2011

Hydrosilylation Catalysts
patent-application, January 2011

Non-Precious Metal-Containing 2,8-Bis(Imino)Quinoline Complexes And Their Use As Hydrosilylation Catalysts
patent-application, May 2012

In-Situ Activation Of Metal Complexes Containing Terdentate Nitrogen Ligands Used As Hydrosilylation Catalysts
patent-application, May 2012

Enantiopure Base-Metal Catalysts For Asymmetric Catalysis And Bis(Imino)Pyridine Iron Alkyl Complexes For Catalys
patent-application, March 2013

A Highly Active Manganese Precatalyst for the Hydrosilylation of Ketones and Esters
journal, January 2014
  • Mukhopadhyay, Tufan K.; Flores, Marco; Groy, Thomas L.
  • Journal of the American Chemical Society, Vol. 136, Issue 3, p. 882-885
  • DOI: 10.1021/ja4116346

Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands
journal, March 2010
  • Inagaki, Tomohiko; Phong, Le Thanh; Furuta, Akihiro
  • Chemistry - A European Journal, Vol. 16, Issue 10, p. 3090-3096
  • DOI: 10.1002/chem.200903118

Cobalt(ii)-catalyzed asymmetric hydrosilylation of simple ketones using dipyridylphosphine ligands in air
journal, January 2011
  • Yu, Feng; Zhang, Xi-Chang; Wu, Fei-Fei
  • Organic & Biomolecular Chemistry, Vol. 9, Issue 16, p. 5652-5654
  • DOI: 10.1039/C1OB05494E

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