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Title: First-row transition metal hydrogenation and hydrosilylation catalysts

Transition metal compounds, and specifically transition metal compounds having a tetradentate and/or pentadentate supporting ligand are described, together with methods for the preparation thereof and the use of such compounds as hydrogenation and/or hydrosilylation catalysts.
Inventors:
; ; ; ; ;
Issue Date:
OSTI Identifier:
1371933
Assignee:
Arizona Board of Regents on Behalf of Arizona State University DOESC
Patent Number(s):
9,708,355
Application Number:
14/896,813
Contract Number:
SC0001016
Resource Relation:
Patent File Date: 2014 Jun 11
Research Org:
Arizona Board of Regents on Behalf of Arizona State University, Scottsdale, AZ (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Works referenced in this record:

Hydrosilylation Catalysts
patent-application, January 2011

A Highly Active Manganese Precatalyst for the Hydrosilylation of Ketones and Esters
journal, January 2014
  • Mukhopadhyay, Tufan K.; Flores, Marco; Groy, Thomas L.
  • Journal of the American Chemical Society, Vol. 136, Issue 3, p. 882-885
  • DOI: 10.1021/ja4116346

Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands
journal, March 2010
  • Inagaki, Tomohiko; Phong, Le Thanh; Furuta, Akihiro
  • Chemistry - A European Journal, Vol. 16, Issue 10, p. 3090-3096
  • DOI: 10.1002/chem.200903118

Cobalt(ii)-catalyzed asymmetric hydrosilylation of simple ketones using dipyridylphosphine ligands in air
journal, January 2011
  • Yu, Feng; Zhang, Xi-Chang; Wu, Fei-Fei
  • Organic & Biomolecular Chemistry, Vol. 9, Issue 16, p. 5652-5654
  • DOI: 10.1039/C1OB05494E