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Title: Greener process to synthesize water-soluble Mn.sup.2+-doped CdSSe(ZnS) core(shell) nanocrystals for ratiometric temperature sensing, nanocrystals, and methods implementing nanocrystals

Novel Mn.sup.2+-doped quantum dots are provided. These Mn.sup.2+-doped quantum dots exhibit excellent temperature sensitivity in both organic solvents and water-based solutions. Methods of preparing the Mn.sup.2+-doped quantum dots are provided. The Mn.sup.2+-doped quantum dots may be prepared via a stepwise procedure using air-stable and inexpensive chemicals. The use of air-stable chemicals can significantly reduce the cost of synthesis, chemical storage, and the risk associated with handling flammable chemicals. Methods of temperature sensing using Mn.sup.2+-doped quantum dots are provided. The stepwise procedure provides the ability to tune the temperature-sensing properties to satisfy specific needs for temperature sensing applications. Water solubility may be achieved by passivating the Mn.sup.2+-doped quantum dots, allowing the Mn.sup.2+-doped quantum dots to probe the fluctuations of local temperature in biological environments.
Inventors:
;
Issue Date:
OSTI Identifier:
1368199
Assignee:
The Trustees of Princeton University LBNL
Patent Number(s):
9,696,317
Application Number:
14/352,610
Contract Number:
AC02-05CH11231
Resource Relation:
Patent File Date: 2012 Oct 18
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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