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Title: Metal-organic frameworks with exceptionally large pore aperatures

The disclosure relates to metal organic frameworks or isoreticular metal organic frameworks, methods of production thereof, and methods of use thereof.
Inventors:
; ;
Issue Date:
OSTI Identifier:
1361632
Assignee:
The Regents of the University of California CHO
Patent Number(s):
9,669,098
Application Number:
14/797,312
Contract Number:
FG02-08ER15935,
Resource Relation:
Patent File Date: 2015 Jul 13
Research Org:
The Regents of the University of California, Oakland, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING

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Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008
  • Han, Sang Soo; Furukawa, Hiroyasu; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11580-11581
  • DOI: 10.1021/ja803247y

Zeolite A imidazolate frameworks
journal, May 2007
  • Hayashi, Hideki; Côté, Adrien P.; Furukawa, Hiroyasu
  • Nature Materials, Vol. 6, Issue 7, p. 501-506
  • DOI: 10.1038/nmat1927

The First Dinitrile Frameworks of the Rare Earth Elements: 3[LnCl3(1,4-Ph(CN)2)] and 3[Ln2Cl6(1,4-Ph(CN)2)], Ln = Sm, Gd, Tb, Y; Access to Novel Metal-Organic Frameworks by Solvent Free Synthesis in Molten 1,4-Benzodinitrile
journal, November 2008
  • Höller, Christoph J.; Müller-Buschbaum, Klaus
  • Inorganic Chemistry, Vol. 47, Issue 21, p. 10141-10149
  • DOI: 10.1021/ic800635u

Reticular Synthesis of Covalent Organic Borosilicate Frameworks
journal, September 2008
  • Hunt, Joseph R.; Doonan, Christian J.; LeVangie, James D.
  • Journal of the American Chemical Society, Vol. 130, Issue 36, p. 11872-11873
  • DOI: 10.1021/ja805064f

Metal-organic frameworks—New materials for hydrogen storage
journal, April 2007
  • Isaeva, V. I.; Kustov, L. M.
  • Russian Journal of General Chemistry, Vol. 77, Issue 4, p. 721-739
  • DOI: 10.1134/S1070363207040342

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007
  • El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
  • Science, Vol. 316, Issue 5822, p. 268-272
  • DOI: 10.1126/science.1139915

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007
  • Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
  • DOI: 10.1021/ja076877g

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures
journal, August 2001
  • Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.
  • Journal of the American Chemical Society, Vol. 123, Issue 34, p. 8239-8247
  • DOI: 10.1021/ja010825o

Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air
journal, March 2009
  • Kirai, Naohiro; Yamamoto, Yoshihiko
  • European Journal of Organic Chemistry, Vol. 2009, Issue 12, p. 1864-1867
  • DOI: 10.1002/ejoc.200900173

An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002
  • Koza, Darrell J.; Carita, Eric
  • Synthesis, Vol. 2002, Issue 15, p. 2183-2186
  • DOI: 10.1055/s-2002-34855

Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999

Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000
  • Li, Hailian; Eddaoudi, Mohamed; Plévert, Jacques
  • Journal of the American Chemical Society, Vol. 122, Issue 49, p. 12409-12410
  • DOI: 10.1021/ja003228v

20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001
  • Li, Hailian; Kim, Jaheon; Groy, T. L.
  • Journal of the American Chemical Society, Vol. 123, Issue 20, p. 4867-4868
  • DOI: 10.1021/ja010413f

[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity
journal, April 2003
  • Li, Hailian; Kim, Jaheon; O'Keeffe, Michael
  • Angewandte Chemie International Edition, Vol. 42, Issue 16, p. 1819-1821
  • DOI: 10.1002/anie.200250748

A metal–organic framework replete with ordered donor–acceptor catenanes
journal, January 2010
  • Li, Qiaowei; Zhang, Wenyu; Miljanić, Ognjen Š.
  • Chemical Communications, Vol. 46, Issue 3, p. 380-382
  • DOI: 10.1039/B919923C

A Catenated Strut in a Catenated Metal-Organic Framework
journal, August 2010
  • Li, Qiaowei; Sue, Chi-Hau; Basu, Subhadeep
  • Angewandte Chemie International Edition, Vol. 49, Issue 38, p. 6751-6755
  • DOI: 10.1002/anie.201003221

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