Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

Wallace, Andrew P.; Melack, John M.; Lefenfeld, Michael

Title: Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

Abstract

Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.

Inventors:: Wallace, Andrew P.; Melack, John M.; Lefenfeld, Michael

Issue Date:: 2017-06-06

Research Org.:: Intelligent Energy Limited, Loughborough, GB

Sponsoring Org.:: USDOE

OSTI Identifier:: 1361629

Patent Number(s):: 9669371

Application Number:: 14/733,596

Assignee:: Intelligent Energy Limited

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J7/02 - by wet methods

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/36 - Hydrogen production from non-carbon containing sources
Y02E60/32 - Hydrogen storage

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/06 - by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/50 - Fuel cells

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M8/0606 - with means for production of gaseous reactants

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/065 - {from a hydride}

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DOE Contract Number:: FG36-08G088108

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Jun 08

Country of Publication:: United States

Language:: English

Subject:: 08 HYDROGEN

Citation Formats


                    Wallace, Andrew P., Melack, John M., and Lefenfeld, Michael. Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials.  United States: N. p., 2017. 
        Web.

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                    Wallace, Andrew P., Melack, John M., & Lefenfeld, Michael. Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials.  United States.

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                    Wallace, Andrew P., Melack, John M., and Lefenfeld, Michael. Tue .  
        "Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials".  United States.  https://www.osti.gov/servlets/purl/1361629.

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@article{osti_1361629,

  title        = {Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials},

  author       = {Wallace, Andrew P. and Melack, John M. and Lefenfeld, Michael},

  abstractNote = {Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {6}

}

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Works referenced in this record:

NMR and X-ray Spectroscopy of Sodium−Silicon Clathrates
journal, May 2001

He, Jiliang; Klug, Dennis D.; Uehara, Kentaro
The Journal of Physical Chemistry B, Vol. 105, Issue 17, p. 3475-3485
https://doi.org/10.1021/jp010255e

A versatile low temperature synthetic route to Zintl phase precursors: Na₄Si₄, Na₄Ge₄ and K₄Ge₄ as examples
journal, January 2009

Ma, Xuchu; Xu, Fen; Atkins, Tonya M.
Dalton Transactions, Vol. 0, Issue 46, p. 10250-10255
https://doi.org/10.1039/B913320H

NMR Study of the Synthesis of Alkyl-Terminated Silicon Nanoparticles from the Reaction of SiCl₄ with the Zintl Salt, NaSi
journal, March 2001

Mayeri, Daniel; Phillips, Brian L.; Augustine, Matthew P.
Chemistry of Materials, Vol. 13, Issue 3, p. 765-770
https://doi.org/10.1021/cm000418w

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Similar Records

Title: Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

Abstract

Citation Formats

NMR and X-ray Spectroscopy of Sodium−Silicon Clathrates journal, May 2001

A versatile low temperature synthetic route to Zintl phase precursors: Na4Si4, Na4Ge4 and K4Ge4 as examples journal, January 2009

NMR Study of the Synthesis of Alkyl-Terminated Silicon Nanoparticles from the Reaction of SiCl4 with the Zintl Salt, NaSi journal, March 2001

NMR and X-ray Spectroscopy of Sodium−Silicon Clathrates
journal, May 2001

A versatile low temperature synthetic route to Zintl phase precursors: Na₄Si₄, Na₄Ge₄ and K₄Ge₄ as examples
journal, January 2009

NMR Study of the Synthesis of Alkyl-Terminated Silicon Nanoparticles from the Reaction of SiCl₄ with the Zintl Salt, NaSi
journal, March 2001