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Title: Reactive sintering of ceramic lithium ion electrolyte membranes

Abstract

Disclosed herein are methods for making a solid lithium ion electrolyte membrane, the methods comprising combining a first reactant chosen from amorphous, glassy, or low melting temperature solid reactants with a second reactant chosen from refractory oxides to form a mixture; heating the mixture to a first temperature to form a homogenized composite, wherein the first temperature is between a glass transition temperature of the first reactant and a crystallization onset temperature of the mixture; milling the homogenized composite to form homogenized particles; casting the homogenized particles to form a green body; and sintering the green body at a second temperature to form a solid membrane. Solid lithium ion electrolyte membranes manufactured according to these methods are also disclosed herein.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Corning Incorporated, Corning, NY (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1361420
Patent Number(s):
9673483
Application Number:
14/599,692
Assignee:
Corning Incorporated
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
EE-0005757
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Jan 19
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Badding, Michael Edward, Dutta, Indrajit, Iyer, Sriram Rangarajan, Kent, Brian Alan, and Lonnroth, Nadja Teresia. Reactive sintering of ceramic lithium ion electrolyte membranes. United States: N. p., 2017. Web.
Badding, Michael Edward, Dutta, Indrajit, Iyer, Sriram Rangarajan, Kent, Brian Alan, & Lonnroth, Nadja Teresia. Reactive sintering of ceramic lithium ion electrolyte membranes. United States.
Badding, Michael Edward, Dutta, Indrajit, Iyer, Sriram Rangarajan, Kent, Brian Alan, and Lonnroth, Nadja Teresia. Tue . "Reactive sintering of ceramic lithium ion electrolyte membranes". United States. https://www.osti.gov/servlets/purl/1361420.
@article{osti_1361420,
title = {Reactive sintering of ceramic lithium ion electrolyte membranes},
author = {Badding, Michael Edward and Dutta, Indrajit and Iyer, Sriram Rangarajan and Kent, Brian Alan and Lonnroth, Nadja Teresia},
abstractNote = {Disclosed herein are methods for making a solid lithium ion electrolyte membrane, the methods comprising combining a first reactant chosen from amorphous, glassy, or low melting temperature solid reactants with a second reactant chosen from refractory oxides to form a mixture; heating the mixture to a first temperature to form a homogenized composite, wherein the first temperature is between a glass transition temperature of the first reactant and a crystallization onset temperature of the mixture; milling the homogenized composite to form homogenized particles; casting the homogenized particles to form a green body; and sintering the green body at a second temperature to form a solid membrane. Solid lithium ion electrolyte membranes manufactured according to these methods are also disclosed herein.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {6}
}

Works referenced in this record:

Superionic Conductivity in a Lithium Aluminum Germanium Phosphate Glass–Ceramic
journal, January 2008