Slippery liquid-infused porous surfaces having improved stability

Aizenberg, Joanna; Vogel, Nicolas

Title: Slippery liquid-infused porous surfaces having improved stability

Abstract

Methods and articles disclosed herein relate to liquid repellant surfaces having selective wetting and transport properties. An article having a repellant surface includes a substrate comprising surface features with re-entrant curvature and an immobilized layer of lubricating liquid wetting over the surface features. The surface features with re-entrant curvature can be designed to provide high repellency even after failure or removal of the immobilized layer of lubricating liquid under certain operating conditions.

Inventors:: Aizenberg, Joanna; Vogel, Nicolas

Issue Date:: Tue Apr 25 00:00:00 EDT 2017

Research Org.:: Harvard Univ., Cambridge, MA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1353081

Patent Number(s):: 9630224

Application Number:: 14/414,684

Assignee:: President and Fellows of Harvard College

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL

B - PERFORMING OPERATIONS B08 - CLEANING B08B - CLEANING IN GENERAL

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B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D5/08 - to obtain an anti-friction or anti-adhesive surface

B - PERFORMING OPERATIONS B08 - CLEANING B08B - CLEANING IN GENERAL
B08B17/065 - {the surface having a microscopic surface pattern to achieve the same effect as a lotus flower}

C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
C09D5/1681 - {Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/24355 - Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]

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DOE Contract Number:: AR0000326

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Jul 12

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Aizenberg, Joanna, and Vogel, Nicolas. Slippery liquid-infused porous surfaces having improved stability.  United States: N. p., 2017. 
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                    Aizenberg, Joanna, & Vogel, Nicolas. Slippery liquid-infused porous surfaces having improved stability.  United States.

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                    Aizenberg, Joanna, and Vogel, Nicolas. Tue .  
        "Slippery liquid-infused porous surfaces having improved stability".  United States.  https://www.osti.gov/servlets/purl/1353081.

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@article{osti_1353081,

  title        = {Slippery liquid-infused porous surfaces having improved stability},

  author       = {Aizenberg, Joanna and Vogel, Nicolas},

  abstractNote = {Methods and articles disclosed herein relate to liquid repellant surfaces having selective wetting and transport properties. An article having a repellant surface includes a substrate comprising surface features with re-entrant curvature and an immobilized layer of lubricating liquid wetting over the surface features. The surface features with re-entrant curvature can be designed to provide high repellency even after failure or removal of the immobilized layer of lubricating liquid under certain operating conditions.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Apr 25 00:00:00 EDT 2017},

  month        = {Tue Apr 25 00:00:00 EDT 2017}

}

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Biomaterials, Vol. 24, Issue 11, p. 1959-1967
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Etch rates for micromachining processing-part II
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Williams, K.R.; Gupta, K.; Wasilik, M.
Journal of Microelectromechanical Systems, Vol. 12, Issue 6, p. 761-778
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Biosensors for real-time in vivo measurements
journal, June 2005

Wilson, George S.; Gifford, Raeann
Biosensors and Bioelectronics, Vol. 20, Issue 12, p. 2388-2403
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Deformation of DNA molecules by hydrodynamic focusing
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Wong, Pak Kin; Lee, Yi-Kuen; Ho, Chih-Ming
Journal of Fluid Mechanics, Vol. 497, p. 55-65
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Wong, P. K.; Yu, F.; Shahangian, A.
Proceedings of the National Academy of Sciences, Vol. 105, Issue 13, p. 5105-5110
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Wong, Tak-Sing; Kang, Sung Hoon; Tang, Sindy K. Y.
Nature, Vol. 477, Issue 7365, p. 443-447
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Zhao, Lingzhou; Chu, Paul K.; Zhang, Yumei
Journal of Biomedical Materials Research Part B: Applied Biomaterials, Vol. 91B, Issue 1, p. 470-480
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Keck, Stephen; Knoerzer, Timm A; Smith, Dennis W
Polymer International, Vol. 62, Issue 10, p. 1485-1491
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Miller-Chou, Beth A.; Koenig, Jack L.
Progress in Polymer Science, Vol. 28, Issue 8, p. 1223-1270
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Liu, Hongliang; Zhang, Pengchao; Liu, Mingjie
Advanced Materials, Vol. 25, Issue 32, p. 4477-4481
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Zhu, Lin; Xue, Jian; Wang, Yuanyi
ACS Applied Materials & Interfaces, Vol. 5, Issue 10, p. 4053-4062
https://doi.org/10.1021/am400704z

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Title: Slippery liquid-infused porous surfaces having improved stability

Abstract

Citation Formats

High-Temperature Resistant Self-Healing Coating and Method of Application patent, September 1966

Fluorosilanes and process for their preparation patent, December 1986

Porous microspheres coated with a perfluorinated oil, a fluorinated silicone oil or a silicone gum and cosmetic compositions containing them patent, October 1994

Clay type liquid-resistant protective layer patent, April 1997

Method of increasing lubricity of snow ski bases patent, April 1997

Agent for treating textile, method for treating textile and treated textile patent, May 1997

Reactive two-part polyurethane compositions and optionally self-healable and scratch-resistant coatings prepared therefrom patent, August 1998

Lubricious hydrogel surface modification patent, September 1998

Anti-immunoresponsive polymeric material and its use in biological applications patent, June 2000

Oil-bleeding silicone rubber compositions patent, May 2001

Process for producing article coated with water-repellent film article coated with water-repellent film and liquid composition for water-repellent film, article coated patent, January 2003

Self-healing liquid contact switch patent, March 2007

Self-healing coating and microcapsules to make same patent, March 2007

Polysulfone block copolymers as drug-eluting coating material patent, July 2009

Antifouling condensation curing organopolysiloxane composition and underwater structure patent, February 2010

Self-healing coating system patent, May 2010

Multiple function, self-repairing composites with special adhesives patent, October 2010

Lubricant compositions and methods patent-application, August 2001

Home care compositions comprising a dicarboxy functionalized polyorganosiloxane patent-application, November 2003

Organic fibers and textile products patent-application, February 2004

Thermally stable perfluoropolyethers and processes therefor and therewith patent-application, September 2004

Urethane polyol precursors for coating compositions patent-application, July 2005

Methods of controlling flow patent-application, February 2006

Liquid-repellent coating composition and coating having high alkali resistance patent-application, July 2006

Method of providing lubricious surfaces patent-application, July 2006

Electrofluidic Textiles and Cleaning Implements Using Such Electrofluidic Textiles patent-application, February 2007

Process for preparing a superhydrophobic coating patent-application, June 2007

Non-leaching surface-active film compositions for microbial adhesion prevention patent-application, July 2007

Water jet woven air bag fabric made from sized yarns patent-application, August 2007

Biocompatible self-lubricating polymer compositions and their use in medical and surgical devices patent-application, November 2007

Corrosion Inhibiting Pigment Comprising Nanoreservoirs of Corrosion Inhibitors patent-application, March 2009

Methods for Making Polymeric Substrates Comprising a Haze-Free, Self-Healing Coating and Coated Substrates Made Thereby patent-application, April 2009

Self-Lubricating Elastomeric Components for Use in Medical Devices patent-application,

Flame Retardant, Stain and Soil Resistant Textile Article patent-application, January 2010

Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes patent-application, August 2010

Preparation of Silicone Microemulsions patent-application, July 2011

Micro-Structured Surface Having Tailored Wetting Properties patent-application, November 2011

Tribo-System and Method for Reducing Particle Conglomeration Therein patent-application, November 2011

Self Lubricated Bearing Compositions and Methods of Making the Same patent-application, June 2012

Association Between a Silver-Coated Endotracheal Tube and Reduced Mortality in Patients With Ventilator-Associated Pneumonia journal, May 2010

Antifouling Coatings: Recent Developments in the Design of Surfaces That Prevent Fouling by Proteins, Bacteria, and Marine Organisms journal, September 2010

Manufacture, characterisation and application of cellular metals and metal foams journal, January 2001

Purity of the sacred lotus, or escape from contamination in biological surfaces journal, April 1997

The insect-trapping rim of Nepenthes pitchers: surface structure and function journal, November 2009

Insect aquaplaning: Nepenthes pitcher plants capture prey with the peristome, a fully wettable water-lubricated anisotropic surface journal, September 2004

Retention of bacteria on a substratum surface with micro-patterned hydrophobicity journal, August 2000

Large Contact Angles of Plant and Animal Surfaces journal, January 1945

Surface hydration: Principles and applications toward low-fouling/nonfouling biomaterials journal, October 2010

Survival of Mammals Breathing Organic Liquids Equilibrated with Oxygen at Atmospheric Pressure journal, June 1966

Bacterial Biofilms: A Common Cause of Persistent Infections journal, May 1999

Percutaneous Transcatheter Implantation of an Aortic Valve Prosthesis for Calcific Aortic Stenosis: First Human Case Description journal, November 2002

The Promise of Novel Technology for the Prevention of Intravascular Device–Related Bloodstream Infection. I. Pathogenesis and Short‐Term Devices journal, May 2002

Coronary artery stent infection journal, November 2000

Prosthetic Valve Endocarditis: Analysis of 38 Cases journal, August 1973

Surface Modification of Poly(ethylene terephthalate) To Prepare Surfaces with Silica-Like Reactivity journal, September 1998

Coding/Decoding and Reversibility of Droplet Trains in Microfluidic Networks journal, February 2007

Acute Coronary Syndrome Caused by Coronary Artery Mycotic Aneurysm Due to Late Stent Infection Localized With Radiolabeled Autologous Leukocyte Imaging journal, January 2009

Self-assembling polystyrene-block-poly(ethylene oxide) copolymer surface coatings Resistance to protein and cell adhesion journal, May 2009

Biomaterial-Centered Sepsis and the Total Artificial Heart: Microbial Adhesion vs Tissue Integration journal, February 1988

Bacterial biofilms: from the Natural environment to infectious diseases journal, February 2004

Assembly of large-area, highly ordered, crack-free inverse opal films journal, May 2010

Endovascular stent infection with delayed bacterial challenge journal, August 1997

Surface modification of polytetrafluoroethylene with ArF excimer laser irradiation journal, January 1994

In vitro and in vivo characterization of porous poly-L-lactic acid coatings for subcutaneously implanted glucose sensors journal, December 2008

Fast fabrication of long-range ordered porous alumina membranes by hard anodization journal, August 2006

Bioinspired Self-Healing Superhydrophobic Coatings journal, July 2010

Surface modification of polytetrafluoroethylene films by plasma pretreatment and graft copolymerization to improve their adhesion to bismaleimide journal, January 2009

Relationships between Water Wettability and Ice Adhesion journal, October 2010

Deterioration of pH electrode response due to biofilm formation on the glass membrane journal, December 1996

Biomimetic Superhydrophobic Surfaces Multiscale Approach journal, September 2007

Biofilm Formation as Microbial Development journal, October 2000

Bacterial adhesion on PEG modified polyurethane surfaces journal, April 1998

Metastable Underwater Superhydrophobicity journal, October 2010

Fabrication of Bioinspired Actuated Nanostructures with Arbitrary Geometry and Stiffness journal, January 2009

Complement deficiency states and associated infections journal, August 2011

Risk Factor Analysis of Permanent Pacemaker Infection journal, July 2007

Controlled growth of monodisperse silica spheres in the micron size range journal, January 1968

High-Temperature Resistant Self-Healing Coating and Method of Application
patent, September 1966

Fluorosilanes and process for their preparation
patent, December 1986

Porous microspheres coated with a perfluorinated oil, a fluorinated silicone oil or a silicone gum and cosmetic compositions containing them
patent, October 1994

Clay type liquid-resistant protective layer
patent, April 1997

Method of increasing lubricity of snow ski bases
patent, April 1997

Agent for treating textile, method for treating textile and treated textile
patent, May 1997

Reactive two-part polyurethane compositions and optionally self-healable and scratch-resistant coatings prepared therefrom
patent, August 1998

Lubricious hydrogel surface modification
patent, September 1998

Anti-immunoresponsive polymeric material and its use in biological applications
patent, June 2000

Oil-bleeding silicone rubber compositions
patent, May 2001

Process for producing article coated with water-repellent film article coated with water-repellent film and liquid composition for water-repellent film, article coated
patent, January 2003

Self-healing liquid contact switch
patent, March 2007

Self-healing coating and microcapsules to make same
patent, March 2007

Polysulfone block copolymers as drug-eluting coating material
patent, July 2009

Antifouling condensation curing organopolysiloxane composition and underwater structure
patent, February 2010

Self-healing coating system
patent, May 2010

Multiple function, self-repairing composites with special adhesives
patent, October 2010

Lubricant compositions and methods
patent-application, August 2001

Home care compositions comprising a dicarboxy functionalized polyorganosiloxane
patent-application, November 2003

Organic fibers and textile products
patent-application, February 2004

Thermally stable perfluoropolyethers and processes therefor and therewith
patent-application, September 2004

Urethane polyol precursors for coating compositions
patent-application, July 2005

Methods of controlling flow
patent-application, February 2006

Liquid-repellent coating composition and coating having high alkali resistance
patent-application, July 2006

Method of providing lubricious surfaces
patent-application, July 2006

Electrofluidic Textiles and Cleaning Implements Using Such Electrofluidic Textiles
patent-application, February 2007

Process for preparing a superhydrophobic coating
patent-application, June 2007

Non-leaching surface-active film compositions for microbial adhesion prevention
patent-application, July 2007

Water jet woven air bag fabric made from sized yarns
patent-application, August 2007

Biocompatible self-lubricating polymer compositions and their use in medical and surgical devices
patent-application, November 2007

Corrosion Inhibiting Pigment Comprising Nanoreservoirs of Corrosion Inhibitors
patent-application, March 2009

Methods for Making Polymeric Substrates Comprising a Haze-Free, Self-Healing Coating and Coated Substrates Made Thereby
patent-application, April 2009

Self-Lubricating Elastomeric Components for Use in Medical Devices
patent-application,

Flame Retardant, Stain and Soil Resistant Textile Article
patent-application, January 2010

Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
patent-application, August 2010

Preparation of Silicone Microemulsions
patent-application, July 2011

Micro-Structured Surface Having Tailored Wetting Properties
patent-application, November 2011

Tribo-System and Method for Reducing Particle Conglomeration Therein
patent-application, November 2011

Self Lubricated Bearing Compositions and Methods of Making the Same
patent-application, June 2012

Association Between a Silver-Coated Endotracheal Tube and Reduced Mortality in Patients With Ventilator-Associated Pneumonia
journal, May 2010

Antifouling Coatings: Recent Developments in the Design of Surfaces That Prevent Fouling by Proteins, Bacteria, and Marine Organisms
journal, September 2010

Manufacture, characterisation and application of cellular metals and metal foams
journal, January 2001

Purity of the sacred lotus, or escape from contamination in biological surfaces
journal, April 1997

The insect-trapping rim of Nepenthes pitchers: surface structure and function
journal, November 2009

Insect aquaplaning: Nepenthes pitcher plants capture prey with the peristome, a fully wettable water-lubricated anisotropic surface
journal, September 2004

Retention of bacteria on a substratum surface with micro-patterned hydrophobicity
journal, August 2000

Large Contact Angles of Plant and Animal Surfaces
journal, January 1945

Surface hydration: Principles and applications toward low-fouling/nonfouling biomaterials
journal, October 2010

Survival of Mammals Breathing Organic Liquids Equilibrated with Oxygen at Atmospheric Pressure
journal, June 1966

Bacterial Biofilms: A Common Cause of Persistent Infections
journal, May 1999

Percutaneous Transcatheter Implantation of an Aortic Valve Prosthesis for Calcific Aortic Stenosis: First Human Case Description
journal, November 2002

The Promise of Novel Technology for the Prevention of Intravascular Device–Related Bloodstream Infection. I. Pathogenesis and Short‐Term Devices
journal, May 2002

Coronary artery stent infection
journal, November 2000

Prosthetic Valve Endocarditis: Analysis of 38 Cases
journal, August 1973

Surface Modification of Poly(ethylene terephthalate) To Prepare Surfaces with Silica-Like Reactivity
journal, September 1998

Coding/Decoding and Reversibility of Droplet Trains in Microfluidic Networks
journal, February 2007

Acute Coronary Syndrome Caused by Coronary Artery Mycotic Aneurysm Due to Late Stent Infection Localized With Radiolabeled Autologous Leukocyte Imaging
journal, January 2009

Self-assembling polystyrene-block-poly(ethylene oxide) copolymer surface coatings Resistance to protein and cell adhesion
journal, May 2009

Biomaterial-Centered Sepsis and the Total Artificial Heart: Microbial Adhesion vs Tissue Integration
journal, February 1988

Bacterial biofilms: from the Natural environment to infectious diseases
journal, February 2004

Assembly of large-area, highly ordered, crack-free inverse opal films
journal, May 2010

Endovascular stent infection with delayed bacterial challenge
journal, August 1997

Surface modification of polytetrafluoroethylene with ArF excimer laser irradiation
journal, January 1994

In vitro and in vivo characterization of porous poly-L-lactic acid coatings for subcutaneously implanted glucose sensors
journal, December 2008

Fast fabrication of long-range ordered porous alumina membranes by hard anodization
journal, August 2006

Bioinspired Self-Healing Superhydrophobic Coatings
journal, July 2010

Surface modification of polytetrafluoroethylene films by plasma pretreatment and graft copolymerization to improve their adhesion to bismaleimide
journal, January 2009

Relationships between Water Wettability and Ice Adhesion
journal, October 2010

Deterioration of pH electrode response due to biofilm formation on the glass membrane
journal, December 1996

Biomimetic Superhydrophobic Surfaces Multiscale Approach
journal, September 2007

Biofilm Formation as Microbial Development
journal, October 2000

Bacterial adhesion on PEG modified polyurethane surfaces
journal, April 1998

Metastable Underwater Superhydrophobicity
journal, October 2010

Fabrication of Bioinspired Actuated Nanostructures with Arbitrary Geometry and Stiffness
journal, January 2009

Complement deficiency states and associated infections
journal, August 2011

Risk Factor Analysis of Permanent Pacemaker Infection
journal, July 2007

Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968

Silver resistance and accumulation in bacteria
journal, June 1987

Designing Superoleophobic Surfaces
journal, December 2007

Robust omniphobic surfaces
journal, November 2008