Hydroxide catalysts for lignin depolymerization
Abstract
Solid base catalysts and their use for the base-catalyzed depolymerization (BCD) of lignin to compounds such as aromatics are presented herein. Exemplary catalysts include layered double hydroxides (LDHs) as recyclable, heterogeneous catalysts for BCD of lignin.
- Inventors:
- Issue Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1353079
- Patent Number(s):
- 9631146
- Application Number:
- 14/047,905
- Assignee:
- Alliance for Sustainable Energy, LLC
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
- DOE Contract Number:
- AC36-08GO28308
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Oct 07
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Beckham, Gregg T., Biddy, Mary J., Chmely, Stephen C., and Sturgeon, Matthew. Hydroxide catalysts for lignin depolymerization. United States: N. p., 2017.
Web.
Beckham, Gregg T., Biddy, Mary J., Chmely, Stephen C., & Sturgeon, Matthew. Hydroxide catalysts for lignin depolymerization. United States.
Beckham, Gregg T., Biddy, Mary J., Chmely, Stephen C., and Sturgeon, Matthew. Tue .
"Hydroxide catalysts for lignin depolymerization". United States. https://www.osti.gov/servlets/purl/1353079.
@article{osti_1353079,
title = {Hydroxide catalysts for lignin depolymerization},
author = {Beckham, Gregg T. and Biddy, Mary J. and Chmely, Stephen C. and Sturgeon, Matthew},
abstractNote = {Solid base catalysts and their use for the base-catalyzed depolymerization (BCD) of lignin to compounds such as aromatics are presented herein. Exemplary catalysts include layered double hydroxides (LDHs) as recyclable, heterogeneous catalysts for BCD of lignin.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {4}
}
Works referenced in this record:
Two powder synthesis of hydrotalcite and hydrotalcite-like compounds with monovalen inorganic anions
patent, July 1998
- Martin, Edward S.; Stinson, John M.; Cedro, III, Vito
- US Patent Document 5,776,424
Multi-Functional Catalyst Composition for the Conversion of Biomass
patent-application, February 2012
- O'Connor, Paul; Yanlk, Steve; Daamen, Sjoerd
- US Patent Application 13/130092; 20120037486
Method For Selective Production Of Biobased Chemicals And Biofuels From Plant Lignin
patent-application, September 2013
- Peterson, John; Patel, Jignesh; Romakh, Vladimir
- US Patent Application 13/470398; 20130232853
Hydroxide Catalysts for Lignin Depolymerization
patent-application, February 2016
- Beckham, Gregg T.; Biddy, Mary J.; Kruger, Jacob S.
- US Patent Application 14/817920; 20160052949
Solvent fractionation of renewable woody feedstocks: Organosolv generation of biorefinery process streams for the production of biobased chemicals
journal, October 2011
- Bozell, Joseph J.; Black, Stuart K.; Myers, Michele
- Biomass and Bioenergy, Vol. 35, Issue 10, p. 4197-4208
Exploring, Tuning, and Exploiting the Basicity of Hydrotalcites for Applications in Heterogeneous Catalysis
journal, April 2009
- Debecker, Damien P.; Gaigneaux, Eric M.; Busca, Guido
- Chemistry - A European Journal, Vol. 15, Issue 16, p. 3920-3935
Hydrogen Transfer from Supercritical Methanol over a Solid Base Catalyst A Model for Lignin Depolymerization
journal, March 2009
- Macala, Gerald S.; Matson, Theodore D.; Johnson, Charles L.
- ChemSusChem, Vol. 2, Issue 3, p. 215-217
Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors Solid Bases for Biodiesel Production
journal, April 2008
- Macala, Gerald S.; Robertson, Andrew W.; Johnson, Charles L.
- Catalysis Letters, Vol. 122, Issue 3-4, p. 205-209
One-Pot Catalytic Conversion of Cellulose and of Woody Biomass Solids to Liquid Fuels
journal, September 2011
- Matson, Theodore D.; Barta, Katalin; Iretskii, Alexei V.
- Journal of the American Chemical Society, Vol. 133, Issue 35, p. 14090-14097
Catalytic transfer hydrogenation of citral on calcined layered double hydroxides
journal, January 2001
- Aramendı́a, Marı́a A; Borau, Victoriano; Jiménez, César
- Applied Catalysis A: General, Vol. 206, Issue 1, p. 95-101
Liquid fuels, hydrogen and chemicals from lignin A critical review
journal, May 2013
- Azadi, Pooya; Inderwildi, Oliver R.; Farnood, Ramin
- Renewable and Sustainable Energy Reviews, Vol. 21, p. 506-523
Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels
journal, February 2010
- Bond, J. Q.; Alonso, D. M.; Wang, D.
- Science, Vol. 327, Issue 5969, p. 1110-1114
Synthesis, Characterization, and Ion Exchange Properties of Hydrotalcite Mg6Al2(OH)16(A)x(A‘)2-x·4H2O (A, A‘ = Cl-, Br-, I-, and NO3-, 2 ≥x≥ 0) Derivatives
journal, September 2003
- Bontchev, Ranko P.; Liu, Shirley; Krumhansl, James L.
- Chemistry of Materials, Vol. 15, Issue 19, p. 3669-3675
Solvent-Free Selective Oxidation of Benzyl Alcohol and Benzaldehyde by tert-Butyl Hydroperoxide Using MnO-4-Exchanged Mg–Al–Hydrotalcite Catalysts
journal, March 2003
- Choudhary, V.R.; Dumbre, D.K.; Narkhede, V.S.
- Catalysis Letters, Vol. 86, Issue 4, p. 229-233
Sorption enhanced steam reforming of ethanol on hydrotalcite-like compounds impregnated with active copper
journal, March 2013
- Cunha, A.F.; Wu, Y.-J.; Santos, J.C.
- Chemical Engineering Research and Design, Vol. 91, Issue 3, p. 581-592
Catalyzed decomposition of N2O on metal oxide supports
journal, September 1997
- Drago, Russell S.; Jurczyk, Krzysztof; Kob, Nicholas
- Applied Catalysis B: Environmental, Vol. 13, Issue 1, p. 69-79
Microbial degradation of aromatic compounds — from one strategy to four
journal, October 2011
- Fuchs, Georg; Boll, Matthias; Heider, Johann
- Nature Reviews Microbiology, Vol. 9, Issue 11, p. 803-816
Catalytic hydrodeoxygenation
journal, June 2000
- Furimsky, Edward
- Applied Catalysis A: General, Vol. 199, Issue 2, p. 147-190
Mild Heterogeneous Palladium-Catalyzed Cleavage of β-O-4′-Ether Linkages of Lignin Model Compounds and Native Lignin in Air
journal, November 2013
- Galkin, Maxim V.; Sawadjoon, Supaporn; Rohde, Volker
- ChemCatChem, Vol. 6, Issue 1, p. 179-184
Epoxidation of Cyclohexene With H2O2 and Acetonitrile Catalyzed by Mg–Al Hydrotalcite and Cobalt Modified Hydrotalcites
journal, December 2009
- Ionescu, Rodica; Pavel, Octavian Dumitru; Bîrjega, Ruxandra
- Catalysis Letters, Vol. 134, Issue 3-4, p. 309-317
Deintercalation of Carbonate Ions from a Hydrotalcite-Like Compound: Enhanced Decarbonation Using Acid−Salt Mixed Solution
journal, July 2004
- Iyi, Nobuo; Matsumoto, Taki; Kaneko, Yoshiro
- Chemistry of Materials, Vol. 16, Issue 15, p. 2926-2932
Catalytic transfer reduction (CTR) of alkyl alkyl, alkyl aryl, cyclic and unsaturated ketones over calcined Mg–Al hydrotalcites
journal, March 2001
- Jyothi, T. M.; Raja, T.; Rao, B. S.
- Journal of Molecular Catalysis A: Chemical, Vol. 168, Issue 1-2, p. 187-191
Chemoselective Transfer Hydrogenation Reactions over Calcined-Layered Double Hydroxides
journal, June 2000
- Jyothi, Thundi Madathil; Raja, Thirumalaiswamy; Talawar, Mahadev B.
- Bulletin of the Chemical Society of Japan, Vol. 73, Issue 6, p. 1425-1427
Improved Fe/Mg-Al hydrotalcite catalyst for Baeyer–Villiger oxidation of ketones with molecular oxygen and benzaldehyde
journal, July 2006
- Kawabata, Tomonori; Fujisaki, Naoko; Shishido, Tetsuya
- Journal of Molecular Catalysis A: Chemical, Vol. 253, Issue 1-2, p. 279-289
FT-IR Spectroscopy Study of Surface Acidity and 2-Propanol Decomposition on Mixed Oxides Obtained upon Calcination of Layered Double Hydroxides
journal, April 1997
- Kooli, Fathi; Martín, Cristina; Rives, Vicente
- Langmuir, Vol. 13, Issue 8, p. 2303-2306
Solid base-catalyzed reaction of nitriles with methanol to form α,β-unsaturated nitriles I. Conversion and selectivity
journal, November 1990
- Kurokawa, H.; Kato, T.; Ueda, W.
- Journal of Catalysis, Vol. 126, Issue 1, p. 199-207
Novel Ru−Mg−Al−O Catalyst Derived from Hydrotalcite-like Compound for NO Storage/Decomposition/Reduction
journal, July 2007
- Li, Lan Dong; Yu, Jun Jie; Hao, Zheng Ping
- The Journal of Physical Chemistry C, Vol. 111, Issue 28, p. 10552-10559
Regenerability of Hydrotalcite-Derived Nickel-Iron Alloy Nanoparticles for Syngas Production from Biomass Tar
journal, December 2013
- Li, Dalin; Koike, Mitsuru; Wang, Lei
- ChemSusChem, Vol. 7, Issue 2, p. 510-522
Reductive cleavage of azo dyes and reduction of nitroarenes over trivalent iron incorporated hexagonal mesoporous aluminophosphate molecular sieves
journal, October 2003
- Mohapatra, S.K.; Sonavane, S.U.; Jayaram, R.V.
- Applied Catalysis B: Environmental, Vol. 46, Issue 1, p. 155-163
Recent Studies on Solid Acid Catalysis and Solid Base Catalysis for Fine Chemicals Synthesis [固体酸・塩基触媒研究の新しい展開]
journal, January 2005
- Onaka, Makoto; Seki, Tsunetake; Masui, Yoich
- Journal of Synthetic Organic Chemistry, Japan, Vol. 63, Issue 5, p. 492-502
Lignin Depolymerization and Conversion A Review of Thermochemical Methods
journal, November 2010
- Pandey, M. P.; Kim, C. S.
- Chemical Engineering & Technology, Vol. 34, Issue 1, p. 29-41
Mg/Al hydrotalcites: preparation, characterisation and ketonisation of acetic acid
journal, February 2000
- Parida, Kulamani; Das, Jasobanta
- Journal of Molecular Catalysis A: Chemical, Vol. 151, Issue 1-2, p. 185-192
Mesoporous Nickel-Aluminum Mixed Oxide A Promising Catalyst in Hydride-Transfer Reactions Mesoporous Nickel-Aluminum Mixed Oxide
journal, September 2010
- Paul, Manidipa; Pal, Nabanita; Bhaumik, Asim
- European Journal of Inorganic Chemistry, Vol. 2010, Issue 32, p. 5129-5134
Organic chemical conversions catalyzed by intercalated layered double hydroxides (LDHs)
journal, August 1995
- Pinnavaia, Thomas J.; Chibwe, Malama; Constantino, Vera R.L.
- Applied Clay Science, Vol. 10, Issue 1-2, p. 117-129
Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin
journal, April 2013
- Rahimi, Alireza; Azarpira, Ali; Kim, Hoon
- Journal of the American Chemical Society, Vol. 135, Issue 17, p. 6415-6418
Layered double hydroxides (LDH) intercalated with metal coordination compounds and oxometalates
journal, January 1999
- Rives, Vicente; Angeles Ulibarri, Marı́a
- Coordination Chemistry Reviews, Vol. 181, Issue 1, p. 61-120
Towards Quantitative Catalytic Lignin Depolymerization
journal, April 2011
- Roberts, Virginia. M.; Stein, Valentin; Reiner, Thomas
- Chemistry - A European Journal, Vol. 17, Issue 21, p. 5939-5948
Microbial Biosynthesis of Alkanes
journal, July 2010
- Schirmer, A.; Rude, M. A.; Li, X.
- Science, Vol. 329, Issue 5991, p. 559-562
Catalytic decomposition of alcohols, including ethanol, for in situ H2 generation in a fuel stream using a layered double hydroxide-derived catalyst
journal, August 2003
- Segal, Scott R.; Carrado, Kathleen A.; Marshall, Christopher L.
- Applied Catalysis A: General, Vol. 248, Issue 1-2, p. 33-45
Low temperature steam reforming of methanol over layered double hydroxide-derived catalysts
journal, May 2002
- Segal, Scott R.; Anderson, Ken B.; Carrado, Kathleen A.
- Applied Catalysis A: General, Vol. 231, Issue 1-2, p. 215-226
Production of hydrogen from oxidative steam reforming of methanol: II. Catalytic activity and reaction mechanism on Cu/ZnO/Al2O3 hydrotalcite-derived catalysts
journal, November 2004
- Turco, M.; Bagnasco, G.; Costantino, U.
- Journal of Catalysis, Vol. 228, Issue 1, p. 56-65
Recent Development in Chemical Depolymerization of Lignin: A Review
journal, January 2013
- Wang, Hai; Tucker, Melvin; Ji, Yun
- Journal of Applied Chemistry, Vol. 2013, p. 1-9
Solvent Effects on the Hydrogenolysis of Diphenyl Ether with Raney Nickel and their Implications for the Conversion of Lignin
journal, April 2012
- Wang, Xingyu; Rinaldi, Roberto
- ChemSusChem, Vol. 5, Issue 8, p. 1455-1466
Influence of water on the activity and stability of activated MgAl hydrotalcites for the transesterification of tributyrin with methanol
journal, March 2008
- Xi, Y.; Davis, R.
- Journal of Catalysis, Vol. 254, Issue 2, p. 190-197
Robust Heterogeneous Nickel Catalysts with Tailored Porosity for the Selective Hydrogenolysis of Aryl Ethers
journal, October 2013
- Zaheer, Muhammad; Hermannsdörfer, Justus; Kretschmer, Winfried P.
- ChemCatChem, Vol. 6, Issue 1, p. 91-95
Layered double hydroxides — multifunctional nanomaterials
journal, November 2011
- Zümreoglu-Karan, Birgül; Ay, Ahmet
- Chemical Papers, Vol. 66, Issue 1, p. 1-10