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Title: Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

Abstract

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.

Inventors:
; ; ;
Issue Date:
Research Org.:
Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1351885
Patent Number(s):
9623404
Application Number:
14/585,718
Assignee:
NORTHWESTERN UNIVERSITY
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
AC05-06OR23100
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Dec 30
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hupp, Joseph T., Farha, Omar K., Katz, Michael J., and Mondloch, Joseph E. Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents. United States: N. p., 2017. Web.
Hupp, Joseph T., Farha, Omar K., Katz, Michael J., & Mondloch, Joseph E. Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents. United States.
Hupp, Joseph T., Farha, Omar K., Katz, Michael J., and Mondloch, Joseph E. Tue . "Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents". United States. https://www.osti.gov/servlets/purl/1351885.
@article{osti_1351885,
title = {Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents},
author = {Hupp, Joseph T. and Farha, Omar K. and Katz, Michael J. and Mondloch, Joseph E.},
abstractNote = {A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {4}
}

Patent:

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Works referenced in this record:

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013

  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
  • https://doi.org/10.1021/ja4050828

Hybrid porous solids past, present, future
journal, January 2008


De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010


Structure–property relationships of porous materials for carbon dioxide separation and capture
journal, January 2012


Removal of Chlorine Gases from Streams of Air Using Reactive Zirconium Hydroxide Based Filtration Media
journal, January 2012


Effect of Adsorbed Water and Surface Hydroxyls on the Hydrolysis of VX, GD, and HD on Titania Materials The Development of Self-Decontaminating Paints
journal, February 2012

  • Wagner, George W.; Peterson, Gregory W.; Mahle, John J.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 9, p. 3598-3603
  • https://doi.org/10.1021/ie202063p

Reactions of VX, GD, and HD with Zr(OH)4 Near Instantaneous Decontamination of VX
journal, May 2012


Organophophorous Ester Degradation by Chromium(III) Terephthalate Metal–Organic Framework (MIL-101) Chelated toN,N-Dimethylaminopyridine and Related Aminopyridines
journal, February 2013


Catalytic methods for the destruction of chemical warfare agents under ambient conditions
journal, January 2008


Catalytic mechanisms for phosphotriesterases
journal, January 2013


Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013


Detoxification of chemical warfare agents by CuBTC
journal, November 2013


Effects of pelletization pressure on the physical and chemical properties of the metal–organic frameworks Cu3(BTC)2 and UiO-66
journal, September 2013


Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999


Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011


Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010


A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004