Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

Hupp, Joseph T.; Farha, Omar K.; Katz, Michael J.; Mondloch, Joseph E.

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Title: Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

Abstract

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.

Inventors:: Hupp, Joseph T.; Farha, Omar K.; Katz, Michael J.; Mondloch, Joseph E.

Issue Date:: 2017-04-18

Research Org.:: Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1351885

Patent Number(s):: 9623404

Application Number:: 14/585,718

Assignee:: NORTHWESTERN UNIVERSITY

Patent Classifications (CPCs):: A - HUMAN NECESSITIES A62 - LIFE-SAVING A62B - DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING

A - HUMAN NECESSITIES A62 - LIFE-SAVING A62D - CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS

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A - HUMAN NECESSITIES A62 - LIFE-SAVING A62B - DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
A62B18/02 - Masks
A62B19/00 - Cartridges with absorbing substances for respiratory apparatus {
A62B7/10 - with filter elements

A - HUMAN NECESSITIES A62 - LIFE-SAVING A62D - CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS
A62D2101/02 - Chemical warfare substances, e.g. cholinesterase inhibitors
A62D3/35 - by hydrolysis
A62D9/00 - Composition of chemical substances for use in breathing apparatus

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2253/204 - Metal organic frameworks
B01D2253/306 - Surface area, e.g. BET-specific surface
B01D2253/308 - Pore size
B01D2257/408 - Cyanides, e.g. hydrogen cyanide
B01D2259/4583 - for removing chemical, biological and nuclear warfare agents
B01D53/04 - with stationary adsorbents {

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/226 - {Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
B01J2531/0211 - Metal clusters, i.e. complexes comprising 3 to about 1000 metal atoms with metal-metal bonds to provide one or more all-metal
B01J2531/46 - Titanium
B01J2531/48 - Zirconium
B01J2531/49 - Hafnium
B01J31/1691 - {Coordination polymers, e.g. metal-organic frameworks [MOF]
B01J31/223 - {At least two oxygen atoms present in one at least bidentate or bridging ligand}
B01J31/2239 - {Bridging ligands, e.g. OAc in Cr2
B01J35/023 - {Catalysts characterised by dimensions, e.g. grain size}
B01J35/1019 - {100-500 m2/g}
B01J35/1023 - {500-1000 m2/g}
B01J35/1028 - {more than 1000 m2/g}
B01J35/1057 - {less than 2 nm}
B01J35/1061 - {2-50 nm}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F7/003 - {without C-Metal linkages}

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DOE Contract Number:: AC05-06OR23100

Resource Type:: Patent

Resource Relation:: Patent File Date: 2014 Dec 30

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Hupp, Joseph T., Farha, Omar K., Katz, Michael J., and Mondloch, Joseph E. Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents.  United States: N. p., 2017. 
        Web.

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                    Hupp, Joseph T., Farha, Omar K., Katz, Michael J., & Mondloch, Joseph E. Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents.  United States.

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                    Hupp, Joseph T., Farha, Omar K., Katz, Michael J., and Mondloch, Joseph E. Tue .  
        "Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents".  United States.  https://www.osti.gov/servlets/purl/1351885.

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@article{osti_1351885,

  title        = {Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents},

  author       = {Hupp, Joseph T. and Farha, Omar K. and Katz, Michael J. and Mondloch, Joseph E.},

  abstractNote = {A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {4}

}

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Organophophorous Ester Degradation by Chromium(III) Terephthalate Metal–Organic Framework (MIL-101) Chelated toN,N-Dimethylaminopyridine and Related Aminopyridines
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Similar Records

Title: Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

Abstract

Citation Formats

Removal of toxic chemicals using metal-organic frameworks (MOFs) post-treated via plasma-enhanced chemical vapor deposition (PECVD) with fluorocarbons patent, November 2014

Removal of toxic chemicals using metal-organic frameworks (MOFs) post-treated via plasma-enhanced chemical vapor deposition (PECVD) with fluorocarbons patent, December 2015

Self-Decontaminating Metal Organic Frameworks patent-application, April 2010

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework journal, May 2013

Hybrid porous solids past, present, future journal, January 2008

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities journal, September 2010

Removal of Chlorine Gases from Streams of Air Using Reactive Zirconium Hydroxide Based Filtration Media journal, January 2012

Effect of Adsorbed Water and Surface Hydroxyls on the Hydrolysis of VX, GD, and HD on Titania Materials The Development of Self-Decontaminating Paints journal, February 2012

Reactions of VX, GD, and HD with Zr(OH)4 Near Instantaneous Decontamination of VX journal, May 2012

Organophophorous Ester Degradation by Chromium(III) Terephthalate Metal–Organic Framework (MIL-101) Chelated toN,N-Dimethylaminopyridine and Related Aminopyridines journal, February 2013

Catalytic mechanisms for phosphotriesterases journal, January 2013

Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants journal, November 2013

Detoxification of chemical warfare agents by CuBTC journal, November 2013

Effects of pelletization pressure on the physical and chemical properties of the metal–organic frameworks Cu3(BTC)2 and UiO-66 journal, September 2013

Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal, November 1999

Large-scale screening of hypothetical metal–organic frameworks journal, November 2011

Ultrahigh Porosity in Metal-Organic Frameworks journal, July 2010

A route to high surface area, porosity and inclusion of large molecules in crystals journal, February 2004

Removal of toxic chemicals using metal-organic frameworks (MOFs) post-treated via plasma-enhanced chemical vapor deposition (PECVD) with fluorocarbons
patent, November 2014

Removal of toxic chemicals using metal-organic frameworks (MOFs) post-treated via plasma-enhanced chemical vapor deposition (PECVD) with fluorocarbons
patent, December 2015

Self-Decontaminating Metal Organic Frameworks
patent-application, April 2010

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013

Hybrid porous solids past, present, future
journal, January 2008

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010

Removal of Chlorine Gases from Streams of Air Using Reactive Zirconium Hydroxide Based Filtration Media
journal, January 2012

Effect of Adsorbed Water and Surface Hydroxyls on the Hydrolysis of VX, GD, and HD on Titania Materials The Development of Self-Decontaminating Paints
journal, February 2012

Reactions of VX, GD, and HD with Zr(OH)₄ Near Instantaneous Decontamination of VX
journal, May 2012

Organophophorous Ester Degradation by Chromium(III) Terephthalate Metal–Organic Framework (MIL-101) Chelated toN,N-Dimethylaminopyridine and Related Aminopyridines
journal, February 2013

Catalytic mechanisms for phosphotriesterases
journal, January 2013

Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013

Detoxification of chemical warfare agents by CuBTC
journal, November 2013

Effects of pelletization pressure on the physical and chemical properties of the metal–organic frameworks Cu₃(BTC)₂ and UiO-66
journal, September 2013

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004