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Title: Metal organic frameworks for the catalytic detoxification of chemical warfare nerve agents

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.
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Resource Relation:
Patent File Date: 2014 Dec 30
Research Org:
Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States)
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Country of Publication:
United States

Works referenced in this record:

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
  • DOI: 10.1021/ja4050828

Hybrid porous solids past, present, future
journal, January 2008
  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010
  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Structure–property relationships of porous materials for carbon dioxide separation and capture
journal, January 2012
  • Wilmer, Christopher E.; Farha, Omar K.; Bae, Youn-Sang
  • Energy & Environmental Science, Vol. 5, Issue 12, p. 9849-9856
  • DOI: 10.1039/C2EE23201D

Removal of Chlorine Gases from Streams of Air Using Reactive Zirconium Hydroxide Based Filtration Media
journal, January 2012
  • Peterson, Gregory W.; Rossin, Joseph A.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 6, p. 2675-2681
  • DOI: 10.1021/ie200809r

Effect of Adsorbed Water and Surface Hydroxyls on the Hydrolysis of VX, GD, and HD on Titania Materials The Development of Self-Decontaminating Paints
journal, February 2012
  • Wagner, George W.; Peterson, Gregory W.; Mahle, John J.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 9, p. 3598-3603
  • DOI: 10.1021/ie202063p

Reactions of VX, GD, and HD with Zr(OH)4 Near Instantaneous Decontamination of VX
journal, May 2012
  • Bandosz, Teresa J.; Laskoski, Matt; Mahle, John
  • The Journal of Physical Chemistry C, Vol. 116, Issue 21, p. 11606-11614
  • DOI: 10.1021/jp3028879

Organophophorous Ester Degradation by Chromium(III) Terephthalate Metal–Organic Framework (MIL-101) Chelated toN,N-Dimethylaminopyridine and Related Aminopyridines
journal, February 2013
  • Wang, Sa; Bromberg, Lev; Schreuder-Gibson, Heidi
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 4, p. 1269-1278
  • DOI: 10.1021/am302359b

Catalytic methods for the destruction of chemical warfare agents under ambient conditions
journal, January 2008
  • Smith, Bryan M.
  • Chem. Soc. Rev., Vol. 37, Issue 3, p. 470-478
  • DOI: 10.1039/B705025A

Catalytic mechanisms for phosphotriesterases
journal, January 2013
  • Bigley, Andrew N.; Raushel, Frank M.
  • Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics, Vol. 1834, Issue 1, p. 443-453
  • DOI: 10.1016/j.bbapap.2012.04.004

Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013
  • Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K.
  • Angewandte Chemie International Edition, Vol. 53, Issue 2, p. 497-501
  • DOI: 10.1002/anie.201307520

Detoxification of chemical warfare agents by CuBTC
journal, November 2013
  • Peterson, Gregory W.; Wagner, George W.
  • Journal of Porous Materials, Vol. 21, Issue 2, p. 121-126
  • DOI: 10.1007/s10934-013-9755-6

Effects of pelletization pressure on the physical and chemical properties of the metal–organic frameworks Cu3(BTC)2 and UiO-66
journal, September 2013

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011
  • Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
  • Nature Chemistry, Vol. 4, Issue 2, p. 83-89
  • DOI: 10.1038/nchem.1192

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
  • Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
  • Nature, Vol. 427, Issue 6974, p. 523-527
  • DOI: 10.1038/nature02311