High-density 3D graphene-based monolith and related materials, methods, and devices
Abstract
A composition comprising at least one high-density graphene-based monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds and having a density of at least 0.1 g/cm.sup.3. Also provided is a method comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension selected from a graphene oxide (GO) suspension and a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce a high-density graphene-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1347564
- Patent Number(s):
- 9601226
- Application Number:
- 13/844,340
- Assignee:
- Lawrence Livermore National Security, LLC
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Mar 15
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, and Tylski, Elijah. High-density 3D graphene-based monolith and related materials, methods, and devices. United States: N. p., 2017.
Web.
Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, & Tylski, Elijah. High-density 3D graphene-based monolith and related materials, methods, and devices. United States.
Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Charnvanichborikarn, Supakit, Kucheyev, Sergei, Montalvo, Elizabeth, Shin, Swanee, and Tylski, Elijah. Tue .
"High-density 3D graphene-based monolith and related materials, methods, and devices". United States. https://www.osti.gov/servlets/purl/1347564.
@article{osti_1347564,
title = {High-density 3D graphene-based monolith and related materials, methods, and devices},
author = {Worsley, Marcus A. and Baumann, Theodore F. and Biener, Juergen and Charnvanichborikarn, Supakit and Kucheyev, Sergei and Montalvo, Elizabeth and Shin, Swanee and Tylski, Elijah},
abstractNote = {A composition comprising at least one high-density graphene-based monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds and having a density of at least 0.1 g/cm.sup.3. Also provided is a method comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension selected from a graphene oxide (GO) suspension and a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce a high-density graphene-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {3}
}
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