Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Chen, Zonghai; Amine, Khalil

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Title: Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Abstract

Lithium-air cells employing poly(ethyleneoxide) phosphate-based electrolytes may be prepared and exhibit improved charge carrying capacity. Such PEO phosphates generally have the formulas IIa, IIb, IIc, where: ##STR00001##

Inventors:: Chen, Zonghai; Amine, Khalil

Issue Date:: 2015-09-08

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1346172

Patent Number(s):: 9130241

Application Number:: 13/912,390

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Show more

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M12/06 - with one metallic and one gaseous electrode
H01M12/08 - composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
H01M2300/0025 - Organic electrolyte
H01M2300/0085 - Immobilising or gelification of electrolyte
H01M4/382 - {Lithium
H01M4/90 - Selection of catalytic material

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage
Y02E60/50 - Fuel cells

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T10/70 - Energy storage for electromobility

Show less

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Jun 07

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; 36 MATERIALS SCIENCE

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                    Chen, Zonghai, and Amine, Khalil. Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes.  United States: N. p., 2015. 
        Web.

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                    Chen, Zonghai, & Amine, Khalil. Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes.  United States.

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                    Chen, Zonghai, and Amine, Khalil. Tue .  
        "Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes".  United States.  https://www.osti.gov/servlets/purl/1346172.

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@article{osti_1346172,

  title        = {Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes},

  author       = {Chen, Zonghai and Amine, Khalil},

  abstractNote = {Lithium-air cells employing poly(ethyleneoxide) phosphate-based electrolytes may be prepared and exhibit improved charge carrying capacity. Such PEO phosphates generally have the formulas IIa, IIb, IIc, where: ##STR00001##},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2015},

  month        = {9}

}

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Similar Records

Title: Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Abstract

Citation Formats

Layer for stabilization of lithium anode patent, January 1996

Methods of fabricating rechargeable positive electrodes patent, December 1996

Electrolytic solution for lithium secondary battery and lithium secondary battery using the same patent, March 1998

Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents patent, December 1998

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes patent, April 2000

Nonaqueous secondary battery patent, May 2001

Non-aqueous electrolyte battery patent, September 2001

Electrolyte for a rechargeable cell patent, May 2002

Lithium bisoxalatoborate, the production thereof and its use as a conducting salt patent, January 2003

Electrochemical cell comprising a liquid organic electrolyte with a conductive additive patent, July 2003

Additive for enhancing the performance of electrochemical cells patent, February 2007

Electrolyte for use in electrochemical devices patent, September 2009

Long life lithium batteries with stabilized electrodes patent, June 2011

Functional electrolyte for lithium-ion batteries patent, April 2015

Alkylspiroborate salts for use in electrochemical cells patent-application, October 2001

Lithium-based active materials and preparation thereof patent-application, April 2002

Solid polymer electrolyte and method of preparation patent-application, September 2003

Nonaqueous liquid electrolyte patent-application, September 2003

Rechargeable lithium electrochemical cell patent-application, February 2004

Mesoporous network electrode for electrochemical cell patent-application, July 2004

Polymer electrolyte for electrochemical cell patent-application, October 2004

Solid polymer electrolyte and method of preparation patent-application, January 2005

Electrochemical device having electrolyte including disiloxane patent-application, August 2005

Methods for fabricating lithium rechargeable batteries patent-application, December 2005

Electrochemical device having an electrolyte that includes a tetrasiloxane patent-application, February 2006

LI/AIR NON-AQUEOUS BATTERIES patent-application, May 2007

Rechargeable lithium/water, lithium/air batteries patent-application, September 2007

Poly(Ethyleneoxide) Siloxane Gel Electrolytes patent-application, June 2008

Non-Aqueous Electrolytes patent-application, December 2008

Novel silane compounds as electrolyte solvents for Li-ion batteries journal, March 2006

Li–O2 and Li–S batteries with high energy storage journal, January 2012

Reactions in the Rechargeable Lithium–O 2 Battery with Alkyl Carbonate Electrolytes journal, May 2011

2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn 2 O 4 Rechargable Battery journal, December 2002

Oxygen Reactions in a Non-Aqueous Li+ Electrolyte journal, May 2011

Reaction mechanisms for the limited reversibility of Li–O2 chemistry in organic carbonate electrolytes journal, November 2011

Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes journal, December 2011

Layer for stabilization of lithium anode
patent, January 1996

Methods of fabricating rechargeable positive electrodes
patent, December 1996

Electrolytic solution for lithium secondary battery and lithium secondary battery using the same
patent, March 1998

Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents
patent, December 1998

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes
patent, April 2000

Nonaqueous secondary battery
patent, May 2001

Non-aqueous electrolyte battery
patent, September 2001

Electrolyte for a rechargeable cell
patent, May 2002

Lithium bisoxalatoborate, the production thereof and its use as a conducting salt
patent, January 2003

Electrochemical cell comprising a liquid organic electrolyte with a conductive additive
patent, July 2003

Additive for enhancing the performance of electrochemical cells
patent, February 2007

Electrolyte for use in electrochemical devices
patent, September 2009

Long life lithium batteries with stabilized electrodes
patent, June 2011

Functional electrolyte for lithium-ion batteries
patent, April 2015

Alkylspiroborate salts for use in electrochemical cells
patent-application, October 2001

Lithium-based active materials and preparation thereof
patent-application, April 2002

Solid polymer electrolyte and method of preparation
patent-application, September 2003

Nonaqueous liquid electrolyte
patent-application, September 2003

Rechargeable lithium electrochemical cell
patent-application, February 2004

Mesoporous network electrode for electrochemical cell
patent-application, July 2004

Polymer electrolyte for electrochemical cell
patent-application, October 2004

Solid polymer electrolyte and method of preparation
patent-application, January 2005

Electrochemical device having electrolyte including disiloxane
patent-application, August 2005

Methods for fabricating lithium rechargeable batteries
patent-application, December 2005

Electrochemical device having an electrolyte that includes a tetrasiloxane
patent-application, February 2006

LI/AIR NON-AQUEOUS BATTERIES
patent-application, May 2007

Rechargeable lithium/water, lithium/air batteries
patent-application, September 2007

Poly(Ethyleneoxide) Siloxane Gel Electrolytes
patent-application, June 2008

Non-Aqueous Electrolytes
patent-application, December 2008

Novel silane compounds as electrolyte solvents for Li-ion batteries
journal, March 2006

Li–O₂ and Li–S batteries with high energy storage
journal, January 2012

Reactions in the Rechargeable Lithium–O ₂ Battery with Alkyl Carbonate Electrolytes
journal, May 2011

2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn ₂ O ₄ Rechargable Battery
journal, December 2002

Oxygen Reactions in a Non-Aqueous Li⁺ Electrolyte
journal, May 2011

Reaction mechanisms for the limited reversibility of Li–O₂ chemistry in organic carbonate electrolytes
journal, November 2011

Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes
journal, December 2011