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Title: Method for selectively preparing evoglucosenone (LGO) and other anhydrosugars from biomass in polar aprotic solvents

Abstract

A method to produce 5-hydroxymethylfurfural (HMF) is described in which a reactant including cellulose, lignocellulose, or a combination thereof, in a reaction mixture of a polar, aprotic solvent and an acid is reacted for a time, at a temperature, and at a hydrogen ion concentration wherein at least a portion of the cellulose or lignocellulose present in the reactant is converted to HMF. The reaction mixture is initially substantially devoid of water. As the reaction proceeds, dehydration of intermediates causes the water concentration in the reaction mixture to rise to no more than about 2.0 wt % water.

Inventors:
; ; ;
Issue Date:
Research Org.:
Wisconsin Alumni Research Foundation, Madison, WI (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1344773
Patent Number(s):
9376451
Application Number:
14/588,178
Assignee:
Wisconsin Alumni Research Foundation (Madison, WI)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
DOE Contract Number:  
FC02-07EF64494
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Dec 31
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 59 BASIC BIOLOGICAL SCIENCES

Citation Formats

Huber, George W., Cao, Fei, Dumesic, James A., and Schwartz, Thomas J. Method for selectively preparing evoglucosenone (LGO) and other anhydrosugars from biomass in polar aprotic solvents. United States: N. p., 2016. Web.
Huber, George W., Cao, Fei, Dumesic, James A., & Schwartz, Thomas J. Method for selectively preparing evoglucosenone (LGO) and other anhydrosugars from biomass in polar aprotic solvents. United States.
Huber, George W., Cao, Fei, Dumesic, James A., and Schwartz, Thomas J. Tue . "Method for selectively preparing evoglucosenone (LGO) and other anhydrosugars from biomass in polar aprotic solvents". United States. https://www.osti.gov/servlets/purl/1344773.
@article{osti_1344773,
title = {Method for selectively preparing evoglucosenone (LGO) and other anhydrosugars from biomass in polar aprotic solvents},
author = {Huber, George W. and Cao, Fei and Dumesic, James A. and Schwartz, Thomas J.},
abstractNote = {A method to produce 5-hydroxymethylfurfural (HMF) is described in which a reactant including cellulose, lignocellulose, or a combination thereof, in a reaction mixture of a polar, aprotic solvent and an acid is reacted for a time, at a temperature, and at a hydrogen ion concentration wherein at least a portion of the cellulose or lignocellulose present in the reactant is converted to HMF. The reaction mixture is initially substantially devoid of water. As the reaction proceeds, dehydration of intermediates causes the water concentration in the reaction mixture to rise to no more than about 2.0 wt % water.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {6}
}

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Works referenced in this record:

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