skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Lipon coatings for high voltage and high temperature Li-ion battery cathodes

Abstract

A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1343743
Patent Number(s):
9,570,748
Application Number:
13/651,043
Assignee:
UT-BATTELLE, LLC
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Oct 12
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats

Dudney, Nancy J., Liang, Chengdu, Nanda, Jagjit, Veith, Gabriel M., Kim, Yoongu, and Martha, Surendra Kumar. Lipon coatings for high voltage and high temperature Li-ion battery cathodes. United States: N. p., 2017. Web.
Dudney, Nancy J., Liang, Chengdu, Nanda, Jagjit, Veith, Gabriel M., Kim, Yoongu, & Martha, Surendra Kumar. Lipon coatings for high voltage and high temperature Li-ion battery cathodes. United States.
Dudney, Nancy J., Liang, Chengdu, Nanda, Jagjit, Veith, Gabriel M., Kim, Yoongu, and Martha, Surendra Kumar. Tue . "Lipon coatings for high voltage and high temperature Li-ion battery cathodes". United States. https://www.osti.gov/servlets/purl/1343743.
@article{osti_1343743,
title = {Lipon coatings for high voltage and high temperature Li-ion battery cathodes},
author = {Dudney, Nancy J. and Liang, Chengdu and Nanda, Jagjit and Veith, Gabriel M. and Kim, Yoongu and Martha, Surendra Kumar},
abstractNote = {A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {2}
}

Patent:

Save / Share:

Works referenced in this record:

Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009


Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

  • Arora, Pankaj; White, Ralph E.; Doyle, Marc
  • Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667
  • DOI: 10.1149/1.1838857

Electrical properties of amorphous lithium electrolyte thin films
journal, July 1992


Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries
journal, March 1993


Soft Chemistry Synthesis and Characterization of Layered Li1-xNi1-yCoyO2-δ (0 ≤ x ≤ 1 and 0 ≤ y ≤ 1)
journal, September 2001

  • Chebiam, R. V.; Prado, F.; Manthiram, A.
  • Chemistry of Materials, Vol. 13, Issue 9, p. 2951-2957
  • DOI: 10.1021/cm0102537

The Effect of a Metal-Oxide Coating on the Cycling Behavior at 55°C in Orthorhombic LiMnO2 Cathode Materials
journal, January 2002

  • Cho, Jaephil; Kim, Tae-Joon; Park, Byungwoo
  • Journal of The Electrochemical Society, Vol. 149, Issue 3, p. A288-A292
  • DOI: 10.1149/1.1446870

Zero-Strain Intercalation Cathode for Rechargeable Li-Ion Cell
journal, September 2001


Solid-state thin-film rechargeable batteries
journal, February 2005


Dissolution of Spinel Oxides and Capacity Losses in 4V Li / LixMn2O4 Cells
journal, January 1996

  • Jang, Dong H.; Shin, Young J.; Oh, Seung M.
  • Journal of The Electrochemical Society, Vol. 143, Issue 7, p. 2204-2211
  • DOI: 10.1149/1.1836981

Ion-implantation modification of lithium–phosphorus oxynitride thin-films
journal, June 2002


The Electrochemical Stability of Spinel Electrodes Coated with ZrO2, Al2O3, and SiO2 from Colloidal Suspensions
journal, January 2004

  • Kim, J.-S.; Johnson, C. S.; Vaughey, J. T.
  • Journal of The Electrochemical Society, Vol. 151, Issue 10, p. A1755-A1761
  • DOI: 10.1149/1.1793713

The effect of zirconium oxide coating on the lithium nickel cobalt oxide for lithium secondary batteries
journal, December 2006


Solid‐State Electrochemical Kinetics of Li‐Ion Intercalation into Li1 − xCoO2: Simultaneous Application of Electroanalytical Techniques SSCV, PITT, and EIS
journal, January 1999

  • Levi, M. D.; Salitra, G.; Markovsky, B.
  • Journal of The Electrochemical Society, Vol. 146, Issue 4, p. 1279-1289
  • DOI: 10.1149/1.1391759

Role of Alumina Coating on Li−Ni−Co−Mn−O Particles as Positive Electrode Material for Lithium-Ion Batteries
journal, July 2005

  • Myung, Seung-Taek; Izumi, Kentarou; Komaba, Shinichi
  • Chemistry of Materials, Vol. 17, Issue 14, p. 3695-3704
  • DOI: 10.1021/cm050566s

Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification
journal, September 2006

  • Ohta, N.; Takada, K.; Zhang, L.
  • Advanced Materials, Vol. 18, Issue 17, p. 2226-2229
  • DOI: 10.1002/adma.200502604

Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites
journal, January 1997

  • Courtney, Ian A.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 2045-2052
  • DOI: 10.1149/1.1837740

Fabrication of High-Voltage, High-Capacity All-Solid-State Lithium Polymer Secondary Batteries by Application of the Polymer Electrolyte/Inorganic Electrolyte Composite Concept
journal, April 2005

  • Seki, Shiro; Kobayashi, Yo; Miyashiro, Hajime
  • Chemistry of Materials, Vol. 17, Issue 8, p. 2041-2045
  • DOI: 10.1021/cm047846c

Lithium insertion into manganese spinels
journal, April 1983

  • Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
  • Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
  • DOI: 10.1016/0025-5408(83)90138-1

Low-Temperature Oxidation of Nitrided Iron Surfaces
journal, June 2003

  • Torres, Jessica; Perry, C. C.; Bransfield, Stephen J.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 23, p. 5558-5567
  • DOI: 10.1021/jp027802w

Structural and electrical properties of magnetron sputtered Ti(ON) thin films: The case of TiN doped in situ with oxygen
journal, October 2009


Structural and electrochemical characterizations of surface-modified LiCoO2 cathode materials for Li-ion batteries
journal, June 2002


A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
journal, January 1997

  • Yu, Xiaohua; Bates, J. B.; Jellison, G. E.
  • Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532
  • DOI: 10.1149/1.1837443