Global to push GA events into
skip to main content

Title: Transition metal complexes supported on metal-organic frameworks for heterogeneous catalysts

A robust mesoporous metal-organic framework comprising a hafnium-based metal-organic framework and a single-site zirconium-benzyl species is provided. The hafnium, zirconium-benzyl metal-organic framework is useful as a catalyst for the polymerization of an alkene.
; ; ;
Issue Date:
OSTI Identifier:
Northwestern University EFRC
Patent Number(s):
Application Number:
Contract Number:
Resource Relation:
Patent File Date: 2015 Aug 12
Research Org:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org:
Country of Publication:
United States

Works referenced in this record:

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
  • DOI: 10.1021/ja4050828

Zr- and Hf-Based Metal–Organic Frameworks: Tracking Down the Polymorphism
journal, February 2013
  • Bon, Volodymyr; Senkovska, Irena; Baburin, Igor A.
  • Crystal Growth & Design, Vol. 13, Issue 3, p. 1231-1237
  • DOI: 10.1021/cg301691d

Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry
journal, January 2003
  • Copéret, Christophe; Chabanas, Mathieu; Petroff Saint-Arroman, Romain
  • Angewandte Chemie International Edition, Vol. 42, Issue 2, p. 156-181
  • DOI: 10.1002/anie.200390072

Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins
journal, November 2014
  • Stalzer, Madelyn M.; Delferro, Massimiliano; Marks, Tobin J.
  • Catalysis Letters, Vol. 145, Issue 1, p. 3-14
  • DOI: 10.1007/s10562-014-1427-x

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
  • Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
  • Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456
  • DOI: 10.1002/ange.201204475

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012
  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014
  • Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
  • DOI: 10.1021/ja500330a

Charge Model 5: An Extension of Hirshfeld Population Analysis for the Accurate Description of Molecular Interactions in Gaseous and Condensed Phases
journal, February 2012
  • Marenich, Aleksandr V.; Jerome, Steven V.; Cramer, Christopher J.
  • Journal of Chemical Theory and Computation, Vol. 8, Issue 2, p. 527-541
  • DOI: 10.1021/ct200866d

Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014
  • Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
  • DOI: 10.1021/jz501899j

Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
journal, June 2015
  • Yang, Dong; Odoh, Samuel O.; Wang, Timothy C.
  • Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396
  • DOI: 10.1021/jacs.5b02956

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013
  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
  • DOI: 10.1021/ja408959g

Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation
journal, January 2014
  • Deria, Pravas; Bury, Wojciech; Hupp, Joseph T.
  • Chemical Communications, Vol. 50, Issue 16, p. 1965-1968
  • DOI: 10.1039/C3CC48562E

Metallocenes@COF-102: organometallic host–guest chemistry of porous crystalline organic frameworks
journal, January 2011
  • Kalidindi, Suresh Babu; Yusenko, Kirill; Fischer, Roland A.
  • Chemical Communications, Vol. 47, Issue 30, p. 8506-8508
  • DOI: 10.1039/C1CC11450F

Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins
journal, December 2011
  • Zhang, Zhenjie; Zhang, Linping; Wojtas, Lukasz
  • Journal of the American Chemical Society, Vol. 134, Issue 2, p. 928-933
  • DOI: 10.1021/ja208256u

Metal-Cation-Directed de Novo Assembly of a Functionalized Guest Molecule in the Nanospace of a Metal–Organic Framework
journal, January 2014
  • Li, Baiyan; Zhang, Yiming; Ma, Dingxuan
  • Journal of the American Chemical Society, Vol. 136, Issue 4, p. 1202-1205
  • DOI: 10.1021/ja410868r

Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
journal, September 2011
  • Yoon, Minyoung; Srirambalaji, Renganathan; Kim, Kimoon
  • Chemical Reviews, Vol. 112, Issue 2, p. 1196-1231
  • DOI: 10.1021/cr2003147

Turning MIL-53(Al) Redox-Active by Functionalization of the Bridging OH-Group with 1,1′-Ferrocenediyl-Dimethylsilane
journal, July 2009
  • Meilikhov, Mikhail; Yusenko, Kirill; Fischer, Roland A.
  • Journal of the American Chemical Society, Vol. 131, Issue 28, p. 9644-9645
  • DOI: 10.1021/ja903918s

Titration of Zr3(μ-OH) Hydroxy Groups at the Cornerstones of Bulk MOF UiO-67, [Zr6O4(OH)4(biphenyldicarboxylate)6], and Their Reaction with [AuMe(PMe3)]
journal, May 2012
  • Larabi, Cherif; Quadrelli, Elsje Alessandra
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 18, p. 3014-3022
  • DOI: 10.1002/ejic.201200033

Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene
journal, June 2014
  • Nguyen, Huong Giang T.; Schweitzer, Neil M.; Chang, Chih-Yi
  • ACS Catalysis, Vol. 4, Issue 8, p. 2496-2500
  • DOI: 10.1021/cs5001448

Metathesis of Alkanes and Related Reactions
journal, February 2010
  • Basset, Jean-Marie; Coperet, Christophe; Soulivong, Daravong
  • Accounts of Chemical Research, Vol. 43, Issue 2, p. 323-334
  • DOI: 10.1021/ar900203a

One-Component Catalysts for Polymerization of Olefins
book, January 1975

Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry
journal, April 2015
  • Gu, Weixing; Stalzer, Madelyn Marie; Nicholas, Christopher P.
  • Journal of the American Chemical Society, Vol. 137, Issue 21, p. 6770-6780
  • DOI: 10.1021/jacs.5b03254

A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core
journal, March 2010
  • Stylianou, Kyriakos C.; Heck, Romain; Chong, Samantha Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4119-4130
  • DOI: 10.1021/ja906041f

Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry
journal, November 2012
  • Popoff, Nicolas; Espinas, Jeff; Pelletier, Jérémie
  • Chemistry - A European Journal, Vol. 19, Issue 3, p. 964-973
  • DOI: 10.1002/chem.201202737

Well-Defined Silica-Supported Zirconium-Benzyl Cationic Species: Improved Heterogenization of Single-Site Polymerization Catalysts
journal, January 2014
  • Popoff, Nicolas; Macqueron, Benoît; Sayhoun, Wissam
  • European Journal of Inorganic Chemistry, Vol. 2014, Issue 5, p. 888-895
  • DOI: 10.1002/ejic.201301317

Highly Variable Zr–CH2–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes
journal, November 2012
  • Rong, Yi; Al-Harbi, Ahmed; Parkin, Gerard
  • Organometallics, Vol. 31, Issue 23, p. 8208-8217
  • DOI: 10.1021/om300820b

Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
journal, April 2000
  • Chen, Eugene You-Xian; Marks, Tobin J.
  • Chemical Reviews, Vol. 100, Issue 4, p. 1391-1434
  • DOI: 10.1021/cr980462j

Synthesis and properties of some titanium and zirconium benzyl derivatives
journal, February 1971

WinXAS a Program for X-ray Absorption Spectroscopy Data Analysis under MS-Windows
journal, March 1998

Accurate and simple analytic representation of the electron-gas correlation energy
journal, June 1992

Generalized Gradient Approximation Made Simple
journal, October 1996
  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Rationale for mixing exact exchange with density functional approximations
journal, December 1996
  • Perdew, John P.; Ernzerhof, Matthias; Burke, Kieron
  • The Journal of Chemical Physics, Vol. 105, Issue 22, p. 9982-9985
  • DOI: 10.1063/1.472933

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
journal, November 2006
  • Zhao, Yan; Truhlar, Donald G.
  • The Journal of Chemical Physics, Vol. 125, Issue 19, Article No. 194101
  • DOI: 10.1063/1.2370993

A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
journal, October 2014
  • Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat
  • Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864
  • DOI: 10.1021/ja508626n