Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions
Abstract
The invention generally relates to systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions. In certain aspects, the invention provides methods that involve providing a metal and a solvent. The methods additionally involve applying voltage to the solvated metal to thereby produce solvent droplets including ions of the metal containing compound, and directing the solvent droplets including the metal ions to a target. In certain embodiments, once at the target, the metal ions can react directly or catalyze reactions.
- Inventors:
- Issue Date:
- Research Org.:
- Purdue Univ., West Lafayette, IN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1340578
- Patent Number(s):
- 9551079
- Application Number:
- 14/468,549
- Assignee:
- Purdue Research Foundation (West Lafayette, IN)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25C - PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- DOE Contract Number:
- FG02-06ER15807
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Aug 26
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Cooks, Robert Graham, Li, Anyin, and Luo, Qingjie. Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions. United States: N. p., 2017.
Web.
Cooks, Robert Graham, Li, Anyin, & Luo, Qingjie. Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions. United States.
Cooks, Robert Graham, Li, Anyin, and Luo, Qingjie. Tue .
"Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions". United States. https://www.osti.gov/servlets/purl/1340578.
@article{osti_1340578,
title = {Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions},
author = {Cooks, Robert Graham and Li, Anyin and Luo, Qingjie},
abstractNote = {The invention generally relates to systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions. In certain aspects, the invention provides methods that involve providing a metal and a solvent. The methods additionally involve applying voltage to the solvated metal to thereby produce solvent droplets including ions of the metal containing compound, and directing the solvent droplets including the metal ions to a target. In certain embodiments, once at the target, the metal ions can react directly or catalyze reactions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {1}
}
Works referenced in this record:
Measurement of the Distribution of Site Enhancements in Surface-Enhanced Raman Scattering
journal, July 2008
- Fang, Y.; Seong, N.-H.; Dlott, D. D.
- Science, Vol. 321, Issue 5887, p. 388-392
Structural diversity in binary nanoparticle superlattices
journal, January 2006
- Shevchenko, Elena V.; Talapin, Dmitri V.; Kotov, Nicholas A.
- Nature, Vol. 439, Issue 7072, p. 55-59
Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode
journal, November 1977
- Jeanmaire, David L.; Van Duyne, Richard P.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 84, Issue 1, p. 1-20
Direct and dry micro-patterning of nano-particles by electrospray deposition through a micro-stencil mask
journal, January 2009
- Kim, J.-W.; Yamagata, Y.; Kim, B. J.
- Journal of Micromechanics and Microengineering, Vol. 19, Issue 2, Article No. 025021
Dispersible Surface-Enhanced Raman Scattering Nanosheets
journal, September 2012
- Osberg, Kyle D.; Rycenga, Matthew; Bourret, Gilles R.
- Advanced Materials, Vol. 24, Issue 45, p. 6065-6070
Method for measuring contamination in liquids at PPQ levels
patent, June 2010
- Hanson, Jeffrey Allen; Loewenstein, Lee M.; Douglas, Monte A.
- US Patent Document 7,732,225
Characterization of hotspots in a highly enhancing SERS substrate
journal, January 2011
- Asiala, Steven M.; Schultz, Zachary D.
- Analyst, Vol. 136, Issue 21, p. 4472-4479
Synthesis and Catalytic Reactions of Nanoparticles formed by Electrospray Ionization of Coinage Metals
journal, February 2014
- Li, Anyin; Luo, Qingjie; Park, So-Jung
- Angewandte Chemie International Edition, Vol. 53, Issue 12, p. 3147-3150
Nanosphere lithography: A materials general fabrication process for periodic particle array surfaces
journal, May 1995
- Hulteen, John C.; Van Duyne, Richard P.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3, p. 1553-1558
System and method for the preparation of arrays of biological or other molecules
patent, April 2008
- Cooks, Robert Graham; Ouyang, Zheng
- US Patent Document 7,361,311
Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions
patent-application, March 2015
- Cooks, Robert; Li, Anyin; Luo, Qingjie
- US Patent Application 14/468549; 20150075998
Ion transport and focal properties of an ellipsoidal electrode operated at atmospheric pressure
journal, December 2012
- Baird, Zane; Peng, Wen-Ping; Cooks, R. Graham
- International Journal of Mass Spectrometry, Vol. 330-332, p. 277-284
Coverage-Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-Selected Ions
journal, November 2012
- Johnson, Grant E.; Priest, Thomas; Laskin, Julia
- The Journal of Physical Chemistry C, Vol. 116, Issue 47, p. 24977-24986
The chemical origin of enhanced signals from tip-enhanced Raman detection of functionalized nanoparticles
journal, February 2013
- Wang, Hao; Schultz, Zachary D.
- The Analyst, Vol. 138, Issue 11, p. 3150-3157
Ambient Ion Soft Landing
journal, April 2011
- Badu-Tawiah, Abraham K.; Wu, Chunping; Cooks, R. Graham
- Analytical Chemistry, Vol. 83, Issue 7, p. 2648-2654
Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties
journal, May 2008
- Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J.
- Journal of the American Chemical Society, Vol. 130, Issue 18, p. 5883-5885
Surface-Enhanced Raman Excitation Spectroscopy of a Single Rhodamine 6G Molecule
journal, January 2009
- Dieringer, Jon A.; Wustholz, Kristin L.; Masiello, David J.
- Journal of the American Chemical Society, Vol. 131, Issue 2, p. 849-854
Single-Molecule Surface-Enhanced Raman Spectroscopy of Crystal Violet Isotopologues: Theory and Experiment
journal, March 2011
- Kleinman, Samuel L.; Ringe, Emilie; Valley, Nicholas
- Journal of the American Chemical Society, Vol. 133, Issue 11, p. 4115-4122
Mechanistic Studies on the Galvanic Replacement Reaction between Multiply Twinned Particles of Ag and HAuCl4 in an Organic Medium
journal, February 2007
- Lu, Xianmao; Tuan, Hsing-Yu; Chen, Jingyi
- Journal of the American Chemical Society, Vol. 129, Issue 6, p. 1733-1742
Two-dimensional stimulated resonance Raman spectroscopy of molecules with broadband x-ray pulses
journal, May 2012
- Biggs, Jason D.; Zhang, Yu; Healion, Daniel
- The Journal of Chemical Physics, Vol. 136, Issue 17, Article No. 174117
Self-assembled Monolayers of 1,4-Benzenedimethanethiol on Polycrystalline Silver and Gold Films: An Investigation of Structure, Stability, Dynamics, and Reactivity
journal, September 1998
- Murty, K. V. G. K.; Venkataramanan, M.; Pradeep, T.
- Langmuir, Vol. 14, Issue 19, p. 5446-5456
Chemical Synthesis of Novel Plasmonic Nanoparticles
journal, May 2009
- Lu, Xianmao; Rycenga, Matthew; Skrabalak, Sara E.
- Annual Review of Physical Chemistry, Vol. 60, Issue 1, p. 167-192
Low-Energy Ionic Collisions at Molecular Solids
journal, June 2012
- Cyriac, Jobin; Pradeep, T.; Kang, H.
- Chemical Reviews, Vol. 112, Issue 10, p. 5356-5411
Shell-isolated nanoparticle-enhanced Raman spectroscopy
journal, March 2010
- Li, Jian Feng; Huang, Yi Fan; Ding, Yong
- Nature, Vol. 464, Issue 7287, p. 392-395
Atomically Precise Silver Clusters as New SERS Substrates
journal, July 2013
- Chakraborty, Indranath; Bag, Soumabha; Landman, Uzi
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 16, p. 2769-2773
Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag3{(PPh2)2CH2}3(μ3-H)(μ3-Cl)]BF4
journal, June 2013
- Zavras, Athanasios; Khairallah, George N.; Connell, Timothy U.
- Angewandte Chemie International Edition, Vol. 52, Issue 32, p. 8391-8394
Resonant Field Enhancements from Metal Nanoparticle Arrays
journal, January 2004
- Genov, Dentcho A.; Sarychev, Andrey K.; Shalaev, Vladimir M.
- Nano Letters, Vol. 4, Issue 1, p. 153-158
Nanoscale chemical analysis by tip-enhanced Raman spectroscopy
journal, February 2000
- Stöckle, Raoul M.; Suh, Yung Doug; Deckert, Volker
- Chemical Physics Letters, Vol. 318, Issue 1-3, p. 131-136
IonCCD™ for Direct Position-Sensitive Charged-Particle Detection: from Electrons and keV Ions to Hyperthermal Biomolecular Ions
journal, February 2011
- Hadjar, Omar; Johnson, Grant; Laskin, Julia
- Journal of The American Society for Mass Spectrometry, Vol. 22, Issue 4, p. 612-623
Method for low temperature preparation of a noble metal alloy
patent, February 2002
- Even, Jr., William R.
- US Patent Document 6,348,431
Electromagnetic fields around silver nanoparticles and dimers
journal, January 2004
- Hao, Encai; Schatz, George C.
- The Journal of Chemical Physics, Vol. 120, Issue 1, p. 357-366
Electrical functionality of inkjet-printed silver nanoparticle conductive tracks on nanostructured paper compared with those on plastic substrates
journal, January 2013
- Nge, Thi Thi; Nogi, Masaya; Suganuma, Katsuaki
- Journal of Materials Chemistry C, Vol. 1, Issue 34, p. 5235-5243
Thin-Film Fabrication Method for Organic Light-Emitting Diodes Using Electrospray Deposition
journal, November 2009
- Ju, Jungmyoung; Yamagata, Yutaka; Higuchi, Toshiro
- Advanced Materials, Vol. 21, Issue 43, p. 4343-4347
Transformation of Pd Nanocubes into Octahedra with Controlled Sizes by Maneuvering the Rates of Etching and Regrowth
journal, July 2013
- Liu, Maochang; Zheng, Yiqun; Zhang, Lei
- Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11752-11755
Inkjet-Printed Silver Nanoparticle Paper Detects Airborne Species from Crystalline Explosives and Their Ultratrace Residues in Open Environment
journal, March 2014
- Wang, Jianping; Yang, Liang; Liu, Bianhua
- Analytical Chemistry, Vol. 86, Issue 7, p. 3338-3345
Ultrasensitive Chemical Analysis by Raman Spectroscopy
journal, October 1999
- Kneipp, Katrin; Kneipp, Harald; Itzkan, Irving
- Chemical Reviews, Vol. 99, Issue 10, p. 2957-2976
Nanomaterial immobilization method and immobilization apparatus
patent, November 2011
- Kawakami, Tomonori
- US Patent Document 8,051,800
Gold Nanoparticles for Biology and Medicine
journal, April 2010
- Giljohann, David A.; Seferos, Dwight S.; Daniel, Weston L.
- Angewandte Chemie International Edition, Vol. 49, Issue 19, p. 3280-3294
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
Low-temperature continuous process to derive size-controlled lithium ion anodes and cathodes
patent-application, October 2015
- Kisailus, David; Zhu, Jianxin
- US Patent Application 14/648337; 20150295226
Noble Metals on the Nanoscale: Optical and Photothermal Properties and Some Applications in Imaging, Sensing, Biology, and Medicine
journal, December 2008
- Jain, Prashant K.; Huang, Xiaohua; El-Sayed, Ivan H.
- Accounts of Chemical Research, Vol. 41, Issue 12, p. 1578-1586
Cathodic Corrosion: A Quick, Clean, and Versatile Method for the Synthesis of Metallic Nanoparticles
journal, May 2011
- Yanson, Alexei I.; Rodriguez, Paramaconi; Garcia-Araez, Nuria
- Angewandte Chemie International Edition, Vol. 50, Issue 28, p. 6346-6350
Surface-Enhanced Raman Spectroscopy
journal, July 2008
- Stiles, Paul L.; Dieringer, Jon A.; Shah, Nilam C.
- Annual Review of Analytical Chemistry, Vol. 1, Issue 1, p. 601-626
Surface characterization of nanomaterials and nanoparticles: Important needs and challenging opportunities
journal, September 2013
- Baer, Donald R.; Engelhard, Mark H.; Johnson, Grant E.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 31, Issue 5, Article No. 050820
Methods of separating ionized particles
patent, March 2010
- Blanchard, William C.
- US Patent Document 7,679,052
Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes
journal, January 2006
- Eustis, Susie; El-Sayed, Mostafa A.
- Chemical Society Reviews, Vol. 35, Issue 3, p. 209-217
Real time plasmonic spectroscopy of the interaction of Hg2+ with single noble metal nanoparticles
journal, January 2012
- Bootharaju, M. S.; Chaudhari, Kamalesh; Pradeep, T.
- RSC Advances, Vol. 2, Issue 26, p. 10048-10056
Femtosecond laser ablation of gold in water: influence of the laser-produced plasma on the nanoparticle size distribution
journal, February 2005
- Sylvestre, J.-P.; Kabashin, A. V.; Sacher, E.
- Applied Physics A, Vol. 80, Issue 4, p. 753-758
Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles
journal, June 1996
- Ahmadi, T. S.; Wang, Z. L.; Green, T. C.
- Science, Vol. 272, Issue 5270, p. 1924-1925
Nanosphere Lithography: Tunable Localized Surface Plasmon Resonance Spectra of Silver Nanoparticles
journal, November 2000
- Jensen, Traci R.; Malinsky, Michelle Duval; Haynes, Christy L.
- The Journal of Physical Chemistry B, Vol. 104, Issue 45, p. 10549-10556
Methods of electrospray chemical synthesis and device for use therein
patent-application, January 2012
- Rehman, Atiq
- US Patent Application 13/144832; 20120012453
Methods and compositions for producing microlenses and optical filters
patent, September 2001
- Risen, Jr., William M.; Wang, Yong
- US Patent Document 6,294,217
Nanostructures in Biodiagnostics
journal, April 2005
- Rosi, Nathaniel L.; Mirkin, Chad A.
- Chemical Reviews, Vol. 105, Issue 4, p. 1547-1562
Trimeric Clusters of Silver in Aqueous AgNO3 Solutions and Their Role as Nuclei in Forming Triangular Nanoplates of Silver
journal, June 2007
- Xiong, Yujie; Washio, Isao; Chen, Jingyi
- Angewandte Chemie International Edition, Vol. 46, Issue 26, p. 4917-4921
The Bakerian Lecture: Experimental Relations of Gold (and Other Metals) to Light
journal, January 1857
- Faraday, M.
- Philosophical Transactions of the Royal Society of London, Vol. 147, p. 145-181
Gas-Phase Synthesis of [Ag4H]+ and Its Mediation of the C-C Coupling of Allyl Bromide
journal, January 2005
- Khairallah, George N.; O'Hair, Richard A. J.
- Angewandte Chemie International Edition, Vol. 44, Issue 5, p. 728-731
Ultrasensitive online SERS detection of structural isomers separated by capillary zone electrophoresis
journal, January 2014
- Negri, Pierre; Flaherty, Ryan J.; Dada, Oluwatosin O.
- Chemical Communications, Vol. 50, Issue 21, p. 2707-2710
Peptide Cross-Linking at Ambient Surfaces by Reactions of Nanosprayed Molecular Cations
journal, August 2012
- Badu-Tawiah, Abraham K.; Li, Anyin; Jjunju, Fred P. M.
- Angewandte Chemie, Vol. 124, Issue 37, p. 9551-9555
Unconventional Methods for Fabricating and Patterning Nanostructures
journal, May 1999
- Xia, Younan; Rogers, John A.; Paul, Kateri E.
- Chemical Reviews, Vol. 99, Issue 7, p. 1823-1848
Electrospray Ion Beam Deposition of Clusters and Biomolecules
journal, April 2006
- Rauschenbach, Stephan; Stadler, Frank L.; Lunedei, Eugenio
- Small, Vol. 2, Issue 4, p. 540-547
Immobilized Nanorod Assemblies: Fabrication and Understanding of Large Area Surface-Enhanced Raman Spectroscopy Substrates
journal, January 2013
- Greeneltch, Nathan G.; Blaber, Martin G.; Henry, Anne-Isabelle
- Analytical Chemistry, Vol. 85, Issue 4, p. 2297-2303