Lithium-oxygen batteries incorporating lithium superoxide
Abstract
A composition includes LiO.sub.2, reduced graphene oxide, and a metal catalyst or residue thereof.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1340533
- Patent Number(s):
- 9553316
- Application Number:
- 14/667,524
- Assignee:
- UCHICAGO ARGONNE, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Mar 24
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE
Citation Formats
Lu, Jun, Amine, Khalil, Curtiss, Larry A., Lau, Chun Kah, Sun, Yang-Kook, Lee, Yun Jung, and Luo, Xiangyi. Lithium-oxygen batteries incorporating lithium superoxide. United States: N. p., 2017.
Web.
Lu, Jun, Amine, Khalil, Curtiss, Larry A., Lau, Chun Kah, Sun, Yang-Kook, Lee, Yun Jung, & Luo, Xiangyi. Lithium-oxygen batteries incorporating lithium superoxide. United States.
Lu, Jun, Amine, Khalil, Curtiss, Larry A., Lau, Chun Kah, Sun, Yang-Kook, Lee, Yun Jung, and Luo, Xiangyi. Tue .
"Lithium-oxygen batteries incorporating lithium superoxide". United States. https://www.osti.gov/servlets/purl/1340533.
@article{osti_1340533,
title = {Lithium-oxygen batteries incorporating lithium superoxide},
author = {Lu, Jun and Amine, Khalil and Curtiss, Larry A. and Lau, Chun Kah and Sun, Yang-Kook and Lee, Yun Jung and Luo, Xiangyi},
abstractNote = {A composition includes LiO.sub.2, reduced graphene oxide, and a metal catalyst or residue thereof.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {1}
}
Works referenced in this record:
Direct growth of metal nanoplates on semiconductor substrates
patent, August 2012
- Sun, Yugang
- US Patent Document 8,247,325
First-Principles Design of Graphene-Based Active Catalysts for Oxygen Reduction and Evolution Reactions in the Aprotic Li–O2 Battery
journal, June 2016
- Kang, Joonhee; Yu, Jong-Sung; Han, Byungchan
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 14, p. 2803-2808
Ir nanoparticles-anchored reduced graphene oxide as a catalyst for oxygen electrode in Li–O2 cells
journal, January 2015
- Kumar, Surender; Chinnathambi, Selvaraj; Munichandraiah, Nookala
- New Journal of Chemistry, Vol. 39, Issue 9, p. 7066-7075
Adsorption mechanisms of lithium oxides (LixO2) on a graphene-based electrode: A density functional theory approach
journal, October 2015
- Lee, Ji Hye; Kang, Sung Gu; Moon, Hye Sook
- Applied Surface Science, Vol. 351, p. 193-202
Non-precious Ir–V bimetallic nanoclusters assembled on reduced graphene nanosheets as catalysts for the oxygen reduction reaction
journal, January 2013
- Zhang, Ruizhong; Chen, Wei
- Journal of Materials Chemistry A, Vol. 1, Issue 37, p. 11457-11464
A lithium–oxygen battery based on lithium superoxide
journal, January 2016
- Lu, Jun; Jung Lee, Yun; Luo, Xiangyi
- Nature, Vol. 529, Issue 7586, p. 377-382
A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery
journal, January 1996
- Abraham, K. M.; Jiang, Z.
- Journal of The Electrochemical Society, Vol. 143, Issue 1, p. 1-5
Matrix infrared spectrum and bonding in the lithium superoxide molecule, LiO2
journal, December 1968
- Andrews, Lester
- Journal of the American Chemical Society, Vol. 90, Issue 26, p. 7368-7370
Iridium As Catalyst and Cocatalyst for Oxygen Evolution/Reduction in Acidic Polymer Electrolyte Membrane Electrolyzers and Fuel Cells
journal, April 2014
- Antolini, Ermete
- ACS Catalysis, Vol. 4, Issue 5, p. 1426-1440
Oxygen reduction reaction by electrochemically reduced graphene oxide
journal, June 2014
- Bikkarolla, Santosh Kumar; Cumpson, Peter; Joseph, Paul
- Faraday Discuss., Vol. 173, p. 415-428
The Role of Catalysts and Peroxide Oxidation in Lithium-Oxygen Batteries
journal, November 2012
- Black, Robert; Lee, Jin-Hyon; Adams, Brian
- Angewandte Chemie International Edition, Vol. 52, Issue 1, p. 392-396
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Stability of Lithium Superoxide LiO2 in the Gas Phase: Computational Study of Dimerization and Disproportionation Reactions
journal, August 2010
- Bryantsev, Vyacheslav S.; Blanco, Mario; Faglioni, Francesco
- The Journal of Physical Chemistry A, Vol. 114, Issue 31, p. 8165-8169
Structure and Stability of Lithium Superoxide Clusters and Relevance to Li–O2 Batteries
journal, February 2014
- Das, Ujjal; Lau, Kah Chun; Redfern, Paul C.
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 5, p. 813-819
The crystal structure of IrLi, Ir3Li and LiRh3
journal, December 1976
- Donkersloot, H. C.; Van Vucht, J. H. N.
- Journal of the Less Common Metals, Vol. 50, Issue 2, p. 279-282
Influence of Li2O2 morphology on oxygen reduction and evolution kinetics in Li–O2 batteries
journal, January 2013
- Gallant, Betar M.; Kwabi, David G.; Mitchell, Robert R.
- Energy & Environmental Science, Vol. 6, Issue 8, p. 2518-2528
Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006
- Grimme, Stefan
- Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
A rechargeable room-temperature sodium superoxide (NaO2) battery
journal, December 2012
- Hartmann, Pascal; Bender, Conrad L.; Vračar, Miloš
- Nature Materials, Vol. 12, Issue 3, p. 228-232
Investigation of the O2 Electrochemistry in a Polymer Electrolyte Solid-State Cell
journal, March 2011
- Hassoun, Jusef; Croce, Fausto; Armand, Michel
- Angewandte Chemie International Edition, Vol. 50, Issue 13, p. 2999-3002
Preparation of Graphitic Oxide
journal, March 1958
- Hummers, William S.; Offeman, Richard E.
- Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339
A Facile Mechanism for Recharging Li2O2 in Li–O2 Batteries
journal, August 2013
- Kang, ShinYoung; Mo, Yifei; Ong, Shyue Ping
- Chemistry of Materials, Vol. 25, Issue 16, p. 3328-3336
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Gold nanoparticles anchored reduced graphene oxide as catalyst for oxygen electrode of rechargeable Li–O2 cells
journal, January 2013
- Kumar, Surender; Selvaraj, C.; Munichandraiah, N.
- RSC Advances, Vol. 3, Issue 44, p. 21706-21714
Elucidating the Mechanism of Oxygen Reduction for Lithium-Air Battery Applications
journal, November 2009
- Laoire, Cormac O.; Mukerjee, Sanjeev; Abraham, K. M.
- The Journal of Physical Chemistry C, Vol. 113, Issue 46, p. 20127-20134
Density Functional Investigation of the Thermodynamic Stability of Lithium Oxide Bulk Crystalline Structures as a Function of Oxygen Pressure
journal, November 2011
- Lau, Kah Chun; Curtiss, Larry A.; Greeley, Jeffrey
- The Journal of Physical Chemistry C, Vol. 115, Issue 47, p. 23625-23633
Synthesis of Porous Carbon Supported Palladium Nanoparticle Catalysts by Atomic Layer Deposition: Application for Rechargeable Lithium–O2 Battery
journal, August 2013
- Lei, Yu; Lu, Jun; Luo, Xiangyi
- Nano Letters, Vol. 13, Issue 9, p. 4182-4189
Preparation of bcc Mg-Li-Al-Zn Alloy by Electrolysis in Molten Salt LiCl-KCl and the Alloy's Electrochemical Performance as Anode Material for Magnesium Batteries
journal, January 2009
- Lin, Meng-Chang; Uan, Jun-Yen
- Electrochemistry, Vol. 77, Issue 8, p. 604-607
Aprotic and Aqueous Li–O2 Batteries
journal, April 2014
- Lu, Jun; Li, Li; Park, Jin-Bum
- Chemical Reviews, Vol. 114, Issue 11, p. 5611-5640
Effect of the size-selective silver clusters on lithium peroxide morphology in lithium–oxygen batteries
journal, September 2014
- Lu, Jun; Cheng, Lei; Lau, Kah Chun
- Nature Communications, Vol. 5, Article No. 4895
Magnetism in Lithium-Oxygen Discharge Product
journal, May 2013
- Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun
- ChemSusChem, Vol. 6, Issue 7, p. 1196-1202
Evidence for lithium superoxide-like species in the discharge product of a Li–O2 battery
journal, January 2013
- Yang, Junbing; Zhai, Dengyun; Wang, Hsien-Hau
- Physical Chemistry Chemical Physics, Vol. 15, Issue 11, p. 3764-3771
Silicon Growth at the Two-Dimensional Limit on Ag(111)
journal, June 2014
- Mannix, Andrew J.; Kiraly, Brian; Fisher, Brandon L.
- ACS Nano, Vol. 8, Issue 7, p. 7538-7547
Graphene growth on AlN templates on silicon using propane-hydrogen chemical vapor deposition
journal, February 2014
- Michon, A.; Tiberj, A.; Vézian, S.
- Applied Physics Letters, Vol. 104, Issue 7, Article No. 071912
Mechanisms of Morphological Evolution of Li2O2 Particles during Electrochemical Growth
journal, March 2013
- Mitchell, Robert R.; Gallant, Betar M.; Shao-Horn, Yang
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 7, p. 1060-1064
Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes
journal, January 2010
- Mizuno, Fuminori; Nakanishi, Shinji; Kotani, Yukinari
- Electrochemistry, Vol. 78, Issue 5, p. 403-405
Synthesis of a metallic mesoporous pyrochlore as a catalyst for lithium–O2 batteries
journal, November 2012
- Oh, Si Hyoung; Black, Robert; Pomerantseva, Ekaterina
- Nature Chemistry, Vol. 4, Issue 12, p. 1004-1010
The Carbon Electrode in Nonaqueous Li–O2 Cells
journal, December 2012
- Ottakam Thotiyl, Muhammed M.; Freunberger, Stefan A.; Peng, Zhangquan
- Journal of the American Chemical Society, Vol. 135, Issue 1, p. 494-500
Oxygen Reactions in a Non-Aqueous Li+ Electrolyte
journal, May 2011
- Peng, Zhangquan; Freunberger, Stefan A.; Hardwick, Laurence J.
- Angewandte Chemie International Edition, Vol. 50, Issue 28, p. 6351-6355
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
The Initial Stages of Template-Controlled CaCO3 Formation Revealed by Cryo-TEM
journal, March 2009
- Pouget, E. M.; Bomans, P. H. H.; Goos, J. A. C. M.
- Science, Vol. 323, Issue 5920, p. 1455-1458
In situ fabrication of porous-carbon-supported α-MnO2 nanorods at room temperature: application for rechargeable Li–O2 batteries
journal, January 2013
- Qin, Yan; Lu, Jun; Du, Peng
- Energy & Environmental Science, Vol. 6, Issue 2, p. 519-531
A Low-Overpotential Potassium–Oxygen Battery Based on Potassium Superoxide
journal, February 2013
- Ren, Xiaodi; Wu, Yiying
- Journal of the American Chemical Society, Vol. 135, Issue 8, p. 2923-2926
Oxygen reduction reaction catalyst on lithium/air battery discharge performance
journal, January 2011
- Ren, Xiaoming; Zhang, Sheng S.; Tran, Dat T.
- Journal of Materials Chemistry, Vol. 21, Issue 27, p. 10118-10125
The Li-O (lithium-oxygen) system
journal, June 1992
- Sangster, J.; Pelton, A. D.
- Journal of Phase Equilibria, Vol. 13, Issue 3, p. 296-299
Reduced Graphene Oxide-Polypyrrole Composite as a Catalyst for Oxygen Electrode of High Rate Rechargeable Li-O2 Cells
journal, January 2014
- Selvaraj, C.; Kumar, S.; Munichandraiah, N.
- Journal of the Electrochemical Society, Vol. 161, Issue 4, p. A554-A560
Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges, and Perspective
journal, April 2012
- Shao, Yuyan; Park, Sehkyu; Xiao, Jie
- ACS Catalysis, Vol. 2, Issue 5, p. 844-857
Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010
- Xu, Yuxi; Sheng, Kaixuan; Li, Chun
- ACS Nano, Vol. 4, Issue 7, p. 4324-4330
Disproportionation in Li–O2 Batteries Based on a Large Surface Area Carbon Cathode
journal, October 2013
- Zhai, Dengyun; Wang, Hsien-Hau; Yang, Junbing
- Journal of the American Chemical Society, Vol. 135, Issue 41, p. 15364-15372
Raman Evidence for Late Stage Disproportionation in a Li–O2 Battery
journal, July 2014
- Zhai, Dengyun; Wang, Hsien-Hau; Lau, Kah Chun
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 15, p. 2705-2710
Structure, mechanical stability, and chemical bond in alkali metal oxides
journal, December 2010
- Zhuravlev, Yu. N.; Obolonskaya, O. S.
- Journal of Structural Chemistry, Vol. 51, Issue 6, p. 1005-1013