High conducting oxide--sulfide composite lithium superionic conductor

Liang, Chengdu; Rangasamy, Ezhiylmurugan; Dudney, Nancy J.; Keum, Jong Kahk; Rondinone, Adam Justin

Title: High conducting oxide--sulfide composite lithium superionic conductor

Abstract

A solid electrolyte for a lithium-sulfur battery includes particles of a lithium ion conducting oxide composition embedded within a lithium ion conducting sulfide composition. The lithium ion conducting oxide composition can be Li.sub.7La.sub.3Zr.sub.2O.sub.12 (LLZO). The lithium ion conducting sulfide composition can be .beta.-Li.sub.3PS.sub.4 (LPS). A lithium ion battery and a method of making a solid electrolyte for a lithium ion battery are also disclosed.

Inventors:: Liang, Chengdu; Rangasamy, Ezhiylmurugan; Dudney, Nancy J.; Keum, Jong Kahk; Rondinone, Adam Justin

Issue Date:: 2017-01-17

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1339534

Patent Number(s):: 9548512

Application Number:: 14/104,803

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0562 - Solid materials
H01M2300/0068 - inorganic
H01M2300/0071 - Oxides

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Dec 12

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Liang, Chengdu, Rangasamy, Ezhiylmurugan, Dudney, Nancy J., Keum, Jong Kahk, and Rondinone, Adam Justin. High conducting oxide--sulfide composite lithium superionic conductor.  United States: N. p., 2017. 
        Web.

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                    Liang, Chengdu, Rangasamy, Ezhiylmurugan, Dudney, Nancy J., Keum, Jong Kahk, & Rondinone, Adam Justin. High conducting oxide--sulfide composite lithium superionic conductor.  United States.

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                    Liang, Chengdu, Rangasamy, Ezhiylmurugan, Dudney, Nancy J., Keum, Jong Kahk, and Rondinone, Adam Justin. Tue .  
        "High conducting oxide--sulfide composite lithium superionic conductor".  United States.  https://www.osti.gov/servlets/purl/1339534.

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@article{osti_1339534,

  title        = {High conducting oxide--sulfide composite lithium superionic conductor},

  author       = {Liang, Chengdu and Rangasamy, Ezhiylmurugan and Dudney, Nancy J. and Keum, Jong Kahk and Rondinone, Adam Justin},

  abstractNote = {A solid electrolyte for a lithium-sulfur battery includes particles of a lithium ion conducting oxide composition embedded within a lithium ion conducting sulfide composition. The lithium ion conducting oxide composition can be Li.sub.7La.sub.3Zr.sub.2O.sub.12 (LLZO). The lithium ion conducting sulfide composition can be .beta.-Li.sub.3PS.sub.4 (LPS). A lithium ion battery and a method of making a solid electrolyte for a lithium ion battery are also disclosed.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {1}

}

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Title: High conducting oxide--sulfide composite lithium superionic conductor

Abstract

Citation Formats

Ion Conductor Having a Garnet Structure patent-application, August 2010

GARNET-TYPE LITHIUM ION-CONDUCTING OXIDE AND ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY CONTAINING THE SAME patent-application, October 2011

Sulfide Solid Electrolyte Glass, Method for Producing Sulfide Solid Electrolyte Glass, and Lithium Solid State Battery patent-application, June 2013

Effect of substitution (Ta, Al, Ga) on the conductivity of Li7La3Zr2O12 journal, May 2012

Synthesis and structure analysis of tetragonal Li7La3Zr2O12 with the garnet-related type structure journal, August 2009

Li–O2 and Li–S batteries with high energy storage journal, January 2012

Effect of Interfacial Space-Charge Polarization on the Ionic Conductivity of Composite Electrolytes journal, October 1985

Enhanced ionic conductivity in composite electrolytes journal, September 1988

Crystal Chemistry and Stability of “Li7La3Zr2O12 ” Garnet: A Fast Lithium-Ion Conductor journal, February 2011

Al-doped Li7La3Zr2O12 synthesized by a polymerized complex method journal, October 2011

A lithium superionic conductor journal, July 2011

Lithium Ionic Conductor Thio-LISICON: The Li2S-GeS2-P2S5 System journal, January 2001

Inorganic solid Li ion conductors: An overview journal, June 2009

Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes journal, October 1973

Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery journal, October 2009

Lithium Superionic Sulfide Cathode for All-Solid Lithium–Sulfur Batteries journal, March 2013

Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4 journal, January 2013

Nanoionics: ion transport and electrochemical storage in confined systems journal, November 2005

Space Charge Regions in Solid Two Phase Systems and Their Conduction Contribution - II Contact Equilibrium at the Interface of Two Ionic Conductors and the Related Conductivity Effect journal, April 1985

Size-Controlled AgI/Ag Heteronanowires in Highly Ordered Alumina Membranes: Superionic Phase Stabilization and Conductivity journal, July 2015

First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material journal, December 2011

Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal, October 2007

Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet journal, July 2012

Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification journal, September 2006

High lithium ionic conductivity in the garnet-type oxide Li7−XLa3(Zr2−X, NbX)O12 (X=0–2) journal, March 2011

The effect of 24c-site (A) cation substitution on the tetragonal–cubic phase transition in Li7−xLa3−xAxZr2O12 garnet-based ceramic electrolyte journal, May 2013

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O12 journal, January 2012

Progress and prospective of solid-state lithium batteries journal, February 2013

Issues and challenges facing rechargeable lithium batteries journal, November 2001

High conductivity of dense tetragonal Li7La3Zr2O12 journal, June 2012

Ion Conductor Having a Garnet Structure
patent-application, August 2010

GARNET-TYPE LITHIUM ION-CONDUCTING OXIDE AND ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY CONTAINING THE SAME
patent-application, October 2011

Sulfide Solid Electrolyte Glass, Method for Producing Sulfide Solid Electrolyte Glass, and Lithium Solid State Battery
patent-application, June 2013

Effect of substitution (Ta, Al, Ga) on the conductivity of Li₇La₃Zr₂O₁₂
journal, May 2012

Synthesis and structure analysis of tetragonal Li₇La₃Zr₂O₁₂ with the garnet-related type structure
journal, August 2009

Li–O₂ and Li–S batteries with high energy storage
journal, January 2012

Effect of Interfacial Space-Charge Polarization on the Ionic Conductivity of Composite Electrolytes
journal, October 1985

Enhanced ionic conductivity in composite electrolytes
journal, September 1988

Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

Al-doped Li₇La₃Zr₂O₁₂ synthesized by a polymerized complex method
journal, October 2011

A lithium superionic conductor
journal, July 2011

Lithium Ionic Conductor Thio-LISICON: The Li₂S-GeS₂-P₂S₅ System
journal, January 2001

Inorganic solid Li ion conductors: An overview
journal, June 2009

Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes
journal, October 1973

Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery
journal, October 2009

Lithium Superionic Sulfide Cathode for All-Solid Lithium–Sulfur Batteries
journal, March 2013

Anomalous High Ionic Conductivity of Nanoporous β-Li₃PS₄
journal, January 2013

Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005

Space Charge Regions in Solid Two Phase Systems and Their Conduction Contribution - II Contact Equilibrium at the Interface of Two Ionic Conductors and the Related Conductivity Effect
journal, April 1985

Size-Controlled AgI/Ag Heteronanowires in Highly Ordered Alumina Membranes: Superionic Phase Stabilization and Conductivity
journal, July 2015

First Principles Study of the Li₁₀GeP₂S₁₂ Lithium Super Ionic Conductor Material
journal, December 2011

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007

Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet
journal, July 2012

Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification
journal, September 2006

High lithium ionic conductivity in the garnet-type oxide Li_7−XLa₃(Zr_2−X, Nb_X)O₁₂ (X=0–2)
journal, March 2011

The effect of 24c-site (A) cation substitution on the tetragonal–cubic phase transition in Li_7−xLa_3−xA_xZr₂O₁₂ garnet-based ceramic electrolyte
journal, May 2013

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂
journal, January 2012

Progress and prospective of solid-state lithium batteries
journal, February 2013

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

High conductivity of dense tetragonal Li₇La₃Zr₂O₁₂
journal, June 2012