Metal-organic framework for the separation of alkane isomers
Abstract
A metal organic framework Fe.sub.2(bdp).sub.3 (BDP.sup.2-=1,4-benzenedipyrazolate) with triangular channels is particularly suited for C5-C7 separations of alkanes according to the number of branches in the molecule rather than by carbon number. The metal-organic framework can offer pore geometries that is unavailable in zeolites or other porous media, facilitating distinct types of shape-based molecular separations.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of California, Oakland, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1338932
- Patent Number(s):
- 9540294
- Application Number:
- 14/703,631
- Assignee:
- THE REGENTS OF THE UNIVERSITY OF CALIFORNIA (Oakland, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
- DOE Contract Number:
- SC0001015
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 May 04
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Long, Jeffrey R., Herm, Zoey R., Wiers, Brian M., and Krishna, Rajamani. Metal-organic framework for the separation of alkane isomers. United States: N. p., 2017.
Web.
Long, Jeffrey R., Herm, Zoey R., Wiers, Brian M., & Krishna, Rajamani. Metal-organic framework for the separation of alkane isomers. United States.
Long, Jeffrey R., Herm, Zoey R., Wiers, Brian M., and Krishna, Rajamani. Tue .
"Metal-organic framework for the separation of alkane isomers". United States. https://www.osti.gov/servlets/purl/1338932.
@article{osti_1338932,
title = {Metal-organic framework for the separation of alkane isomers},
author = {Long, Jeffrey R. and Herm, Zoey R. and Wiers, Brian M. and Krishna, Rajamani},
abstractNote = {A metal organic framework Fe.sub.2(bdp).sub.3 (BDP.sup.2-=1,4-benzenedipyrazolate) with triangular channels is particularly suited for C5-C7 separations of alkanes according to the number of branches in the molecule rather than by carbon number. The metal-organic framework can offer pore geometries that is unavailable in zeolites or other porous media, facilitating distinct types of shape-based molecular separations.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {1}
}
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Works referenced in this record:
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012
- Bloch, E. D.; Queen, W. L.; Krishna, R.
- Science, Vol. 335, Issue 6076, p. 1606-1610
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013
- Herm, Z. R.; Wiers, B. M.; Mason, J. A.
- Science, Vol. 340, Issue 6135, p. 960-964