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Title: Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process

Abstract

The disclosure provides an oxygen carrier for a chemical looping cycle, such as the chemical looping combustion of solid carbonaceous fuels, such as coal, coke, coal and biomass char, and the like. The oxygen carrier is comprised of at least 24 weight % (wt %) CuO, at least 10 wt % Fe2O3, and an inert support, and is typically a calcine. The oxygen carrier exhibits a CuO crystalline structure and an absence of iron oxide crystalline structures under XRD crystallography, and provides an improved and sustained combustion reactivity in the temperature range of 600.degree. C.-1000.degree. C. particularly for solid fuels such as carbon and coal.

Inventors:
;
Issue Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1336926
Patent Number(s):
9,523,499
Application Number:
13/159,553
Assignee:
U.S. Department of Energy (Washington, DC)
Resource Type:
Patent
Resource Relation:
Patent File Date: 2011 Jun 14
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 01 COAL, LIGNITE, AND PEAT

Citation Formats

Siriwardane, Ranjani V., and Tian, Hanjing. Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process. United States: N. p., 2016. Web.
Siriwardane, Ranjani V., & Tian, Hanjing. Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process. United States.
Siriwardane, Ranjani V., and Tian, Hanjing. Tue . "Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process". United States. https://www.osti.gov/servlets/purl/1336926.
@article{osti_1336926,
title = {Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process},
author = {Siriwardane, Ranjani V. and Tian, Hanjing},
abstractNote = {The disclosure provides an oxygen carrier for a chemical looping cycle, such as the chemical looping combustion of solid carbonaceous fuels, such as coal, coke, coal and biomass char, and the like. The oxygen carrier is comprised of at least 24 weight % (wt %) CuO, at least 10 wt % Fe2O3, and an inert support, and is typically a calcine. The oxygen carrier exhibits a CuO crystalline structure and an absence of iron oxide crystalline structures under XRD crystallography, and provides an improved and sustained combustion reactivity in the temperature range of 600.degree. C.-1000.degree. C. particularly for solid fuels such as carbon and coal.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {12}
}

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Works referenced in this record:

Chemical looping combustion of coke oven gas by using Fe2O3/CuO with MgAl2O4 as oxygen carrier
journal, January 2010

  • Wang, Shuzhong; Wang, Guoxian; Jiang, Feng
  • Energy & Environmental Science, Vol. 3, Issue 9
  • DOI: 10.1039/B926193A