Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process
Abstract
The disclosure provides an oxygen carrier for a chemical looping cycle, such as the chemical looping combustion of solid carbonaceous fuels, such as coal, coke, coal and biomass char, and the like. The oxygen carrier is comprised of at least 24 weight % (wt %) CuO, at least 10 wt % Fe2O3, and an inert support, and is typically a calcine. The oxygen carrier exhibits a CuO crystalline structure and an absence of iron oxide crystalline structures under XRD crystallography, and provides an improved and sustained combustion reactivity in the temperature range of 600.degree. C.-1000.degree. C. particularly for solid fuels such as carbon and coal.
- Inventors:
- Issue Date:
- Research Org.:
- National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1336926
- Patent Number(s):
- 9523499
- Application Number:
- 13/159,553
- Assignee:
- U.S. Department of Energy (Washington, DC)
- Patent Classifications (CPCs):
-
F - MECHANICAL ENGINEERING F23 - COMBUSTION APPARATUS F23C - METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN {A CARRIER GAS OR} AIR
F - MECHANICAL ENGINEERING F23 - COMBUSTION APPARATUS F23D - BURNERS
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2011 Jun 14
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 01 COAL, LIGNITE, AND PEAT
Citation Formats
Siriwardane, Ranjani V., and Tian, Hanjing. Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process. United States: N. p., 2016.
Web.
Siriwardane, Ranjani V., & Tian, Hanjing. Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process. United States.
Siriwardane, Ranjani V., and Tian, Hanjing. Tue .
"Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process". United States. https://www.osti.gov/servlets/purl/1336926.
@article{osti_1336926,
title = {Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process},
author = {Siriwardane, Ranjani V. and Tian, Hanjing},
abstractNote = {The disclosure provides an oxygen carrier for a chemical looping cycle, such as the chemical looping combustion of solid carbonaceous fuels, such as coal, coke, coal and biomass char, and the like. The oxygen carrier is comprised of at least 24 weight % (wt %) CuO, at least 10 wt % Fe2O3, and an inert support, and is typically a calcine. The oxygen carrier exhibits a CuO crystalline structure and an absence of iron oxide crystalline structures under XRD crystallography, and provides an improved and sustained combustion reactivity in the temperature range of 600.degree. C.-1000.degree. C. particularly for solid fuels such as carbon and coal.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {12}
}
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Works referenced in this record:
Chemical looping combustion of coke oven gas by using Fe2O3/CuO with MgAl2O4 as oxygen carrier
journal, January 2010
- Wang, Shuzhong; Wang, Guoxian; Jiang, Feng
- Energy & Environmental Science, Vol. 3, Issue 9