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Title: Magnesium-based energy storage systems and methods having improved electrolytes

Abstract

Electrolytes for Mg-based energy storage devices can be formed from non-nucleophilic Mg.sup.2+ sources to provide outstanding electrochemical performance and improved electrophilic susceptibility compared to electrolytes employing nucleophilic sources. The instant electrolytes are characterized by high oxidation stability (up to 3.4 V vs Mg), improved electrophile compatibility and electrochemical reversibility (up to 100% coulombic efficiency). Synthesis of the Mg.sup.2+ electrolytes utilizes inexpensive and safe magnesium dihalides as non-nucleophilic Mg.sup.2+ sources in combination with Lewis acids, MR.sub.aX.sub.3-a (for 3.gtoreq.a.gtoreq.1). Furthermore, addition of free-halide-anion donors can improve the coulombic efficiency of Mg electrolytes from nucleophilic or non-nucleophilic Mg.sup.2+ sources.

Inventors:
; ; ;
Issue Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1336916
Patent Number(s):
9,525,191
Application Number:
14/084,075
Assignee:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Nov 19
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats

Liu, Tianbiao, Li, Guosheng, Liu, Jun, and Shao, Yuyan. Magnesium-based energy storage systems and methods having improved electrolytes. United States: N. p., 2016. Web.
Liu, Tianbiao, Li, Guosheng, Liu, Jun, & Shao, Yuyan. Magnesium-based energy storage systems and methods having improved electrolytes. United States.
Liu, Tianbiao, Li, Guosheng, Liu, Jun, and Shao, Yuyan. Tue . "Magnesium-based energy storage systems and methods having improved electrolytes". United States. https://www.osti.gov/servlets/purl/1336916.
@article{osti_1336916,
title = {Magnesium-based energy storage systems and methods having improved electrolytes},
author = {Liu, Tianbiao and Li, Guosheng and Liu, Jun and Shao, Yuyan},
abstractNote = {Electrolytes for Mg-based energy storage devices can be formed from non-nucleophilic Mg.sup.2+ sources to provide outstanding electrochemical performance and improved electrophilic susceptibility compared to electrolytes employing nucleophilic sources. The instant electrolytes are characterized by high oxidation stability (up to 3.4 V vs Mg), improved electrophile compatibility and electrochemical reversibility (up to 100% coulombic efficiency). Synthesis of the Mg.sup.2+ electrolytes utilizes inexpensive and safe magnesium dihalides as non-nucleophilic Mg.sup.2+ sources in combination with Lewis acids, MR.sub.aX.sub.3-a (for 3.gtoreq.a.gtoreq.1). Furthermore, addition of free-halide-anion donors can improve the coulombic efficiency of Mg electrolytes from nucleophilic or non-nucleophilic Mg.sup.2+ sources.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {12}
}

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Works referenced in this record:

Microelectrode studies of reversible Mg deposition in THF solutions containing complexes of alkylaluminum chlorides and dialkylmagnesium
journal, March 2005