High surface area carbon and process for its production

Title: High surface area carbon and process for its production

Abstract

Activated carbon materials and methods of producing and using activated carbon materials are provided. In particular, biomass-derived activated carbon materials and processes of producing the activated carbon materials with prespecified surface areas and pore size distributions are provided. Activated carbon materials with preselected high specific surface areas, porosities, sub-nm (<1 nm) pore volumes, and supra-nm (1-5 nm) pore volumes may be achieved by controlling the degree of carbon consumption and metallic potassium intercalation into the carbon lattice during the activation process.

Inventors:: Romanos, Jimmy; Burress, Jacob; Pfeifer, Peter; Rash, Tyler; Shah, Parag; Suppes, Galen

Issue Date:: 2016-12-13

Research Org.:: The Curators of the University of Missouri, Columbia, MO (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1335878

Patent Number(s):: 9517445

Application Number:: 13/790,831

Assignee:: The Curators of the University of Missouri

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

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Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/13 - Ultracapacitors, supercapacitors, double-layer capacitors

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B38/0022 - {obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M8/04216 - {characterised by the choice for a specific material, e.g. carbon, hydride, absorbent}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/28057 - {Surface area, e.g. B.E.T specific surface area}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/30 - Active carbon

F - MECHANICAL ENGINEERING F17 - STORING OR DISTRIBUTING GASES OR LIQUIDS F17C - VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES
F17C11/005 - {for hydrogen}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J21/18 - Carbon
B01J20/28083 - {being in the range 2-50 nm, i.e. mesopores}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/318 - characterised by the starting materials

B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
B82Y30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2111/00948 - {for the fabrication of containers}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T10/70 - Energy storage for electromobility

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/926 - {on carbon or graphite}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/0021 - {Carbon, e.g. active carbon, carbon nanotubes, fullerenes

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/00 - Solid sorbent compositions or filter aid compositions

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/52 - based on carbon, e.g. graphite

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G11/34 - characterised by carbonisation or activation of carbon

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/20 - comprising free carbon

F - MECHANICAL ENGINEERING F17 - STORING OR DISTRIBUTING GASES OR LIQUIDS F17C - VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES
F17C11/007 - {for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/28085 - {being more than 50 nm, i.e. macropores}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G11/24 - characterised by structural features, e.g. forms, shapes, surface areas, porosities or dimensions, of the materials making up or comprised in the electrodes

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/3064 - {Addition of pore forming agents, e.g. pore inducing or porogenic agents}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2111/00853 - {in electrochemical cells or batteries, e.g. fuel cells}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/145 - the feedstock being materials of biological origin

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
C10L3/10 - Working-up natural gas or synthetic natural gas

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/342 - characterised by non-gaseous activating agents

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B38/0054 - {the pores being microsized or nanosized}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/32 - Hydrogen storage
Y02E60/50 - Fuel cells

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DOE Contract Number:: FG36-08GO18142

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Mar 08

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Romanos, Jimmy, Burress, Jacob, Pfeifer, Peter, Rash, Tyler, Shah, Parag, and Suppes, Galen. High surface area carbon and process for its production.  United States: N. p., 2016. 
        Web.

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                    Romanos, Jimmy, Burress, Jacob, Pfeifer, Peter, Rash, Tyler, Shah, Parag, & Suppes, Galen. High surface area carbon and process for its production.  United States.

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                    Romanos, Jimmy, Burress, Jacob, Pfeifer, Peter, Rash, Tyler, Shah, Parag, and Suppes, Galen. Tue .  
        "High surface area carbon and process for its production".  United States.  https://www.osti.gov/servlets/purl/1335878.

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@article{osti_1335878,

  title        = {High surface area carbon and process for its production},

  author       = {Romanos, Jimmy and Burress, Jacob and Pfeifer, Peter and Rash, Tyler and Shah, Parag and Suppes, Galen},

  abstractNote = {Activated carbon materials and methods of producing and using activated carbon materials are provided. In particular, biomass-derived activated carbon materials and processes of producing the activated carbon materials with prespecified surface areas and pore size distributions are provided. Activated carbon materials with preselected high specific surface areas, porosities, sub-nm (<1 nm) pore volumes, and supra-nm (1-5 nm) pore volumes may be achieved by controlling the degree of carbon consumption and metallic potassium intercalation into the carbon lattice during the activation process.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {12}

}

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Works referenced in this record:

Porous, metal-containing carbonaceous material
patent, November 1990

Tachibana, Masao
US Patent Document 4,970,189
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4970189

Production of highly microporous activated carbon products
patent, May 1995

Baker, Frederick S.
US Patent Document 5,416,056
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5416056

Highly microporous carbons and process of manufacture
patent, October 1999

Baker, Frederick; Beckler, Robert; Miller, James
US Patent Document 5,965,483
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5965483

Pore structure and adsorption performance of the KOH-activated carbons prepared from corncob
journal, July 2005

Tseng, Ru-Ling; Tseng, Szu-Kung
Journal of Colloid and Interface Science, Vol. 287, Issue 2, p. 428-437
https://doi.org/10.1016/j.jcis.2005.02.033

Preparation of high surface area carbons from Corncob with KOH etching plus CO₂ gasification for the adsorption of dyes and phenols from water
journal, May 2006

Tseng, Ru-Ling; Tseng, Szu-Kung; Wu, Feng-Chin
Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 279, Issue 1-3, p. 69-78
https://doi.org/10.1016/j.colsurfa.2005.12.042

Process effects on activated carbon with large specific surface area from corn cob
journal, January 2006

Cao, Q.; Xie, K.; Lv, Y.
Bioresource Technology, Vol. 97, Issue 1
https://doi.org/10.1016/j.biortech.2005.02.026

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Similar Records

Title: High surface area carbon and process for its production

Abstract

Citation Formats

Porous, metal-containing carbonaceous material patent, November 1990

Production of highly microporous activated carbon products patent, May 1995

Highly microporous carbons and process of manufacture patent, October 1999

Pore structure and adsorption performance of the KOH-activated carbons prepared from corncob journal, July 2005

Preparation of high surface area carbons from Corncob with KOH etching plus CO2 gasification for the adsorption of dyes and phenols from water journal, May 2006

Process effects on activated carbon with large specific surface area from corn cob journal, January 2006

Porous, metal-containing carbonaceous material
patent, November 1990

Production of highly microporous activated carbon products
patent, May 1995

Highly microporous carbons and process of manufacture
patent, October 1999

Pore structure and adsorption performance of the KOH-activated carbons prepared from corncob
journal, July 2005

Preparation of high surface area carbons from Corncob with KOH etching plus CO₂ gasification for the adsorption of dyes and phenols from water
journal, May 2006

Process effects on activated carbon with large specific surface area from corn cob
journal, January 2006