Conversion of 2,3-butanediol to 2-butanol, olefins and fuels

Title: Conversion of 2,3-butanediol to 2-butanol, olefins and fuels

Embodiments of an integrated method for step-wise conversion of 2,3-butanediol to 2-butanol, and optionally to hydrocarbons, are disclosed. The method includes providing an acidic catalyst, exposing a composition comprising aqueous 2,3-butanediol to the acidic catalyst to produce an intermediate composition comprising methyl ethyl ketone, providing a hydrogenation catalyst that is spatially separated from the acidic catalyst, and subsequently exposing the intermediate composition to the hydrogenation catalyst to produce a composition comprising 2-butanol. The method may further include subsequently exposing the composition comprising 2-butanol to a deoxygenation catalyst, and deoxygenating the 2-butanol to form hydrocarbons. In some embodiments, the hydrocarbons comprise olefins, such as butenes, and the method may further include subsequently exposing the hydrocarbons to a hydrogenation catalyst to form saturated hydrocarbons.

Inventors:: Lilga, Michael A.; Lee, Guo-Shuh; Lee, Suh-Jane

Issue Date:: 2016-12-13

OSTI Identifier:: 1335870

Assignee:: Battelle Memorial Institute (Richland, WA) PNNL

Patent Number(s):: 9,517,984

Application Number:: 14/678,729

Contract Number:: AC05-76RL01830

Resource Relation:: Patent File Date: 2015 Apr 03

Research Org:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org:: USDOE

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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Works referenced in this record:

Selective Catalytic Dehydration of 2-Alcohols; a New Synthesis of 1-Olefins
journal, July 1963

Lundeen, Allan J.; Van Hoozer, Robert.
Journal of the American Chemical Society, Vol. 85, Issue 14, p. 2180-2181
DOI: 10.1021/ja00897a041

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