Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor
Abstract
This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbonmore »
- Inventors:
- Issue Date:
- Research Org.:
- Gas Technology Institute, Des Plaines, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1334666
- Patent Number(s):
- 9512364
- Application Number:
- 14/492,840
- Assignee:
- Gas Technology Institute (Des Plaines, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- EE0002873
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Sep 22
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS
Citation Formats
Marker, Terry L., Felix, Larry G., Linck, Martin B., and Roberts, Michael J. Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor. United States: N. p., 2016.
Web.
Marker, Terry L., Felix, Larry G., Linck, Martin B., & Roberts, Michael J. Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor. United States.
Marker, Terry L., Felix, Larry G., Linck, Martin B., and Roberts, Michael J. Tue .
"Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor". United States. https://www.osti.gov/servlets/purl/1334666.
@article{osti_1334666,
title = {Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor},
author = {Marker, Terry L. and Felix, Larry G. and Linck, Martin B. and Roberts, Michael J.},
abstractNote = {This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {12}
}
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