Organic photovoltaic devices comprising solution-processed substituted metal-phthalocyanines and exhibiting near-IR photo-sensitivity
Abstract
Organic photovoltaic (OPV) devices are disclosed. An exemplary device has first and second electrodes and an organic, photovoltaically active zone located between the first and second electrodes. The photovoltaically active zone includes an organic electron-donor material and an organic electron-acceptor material. The electron-donor material includes one or more trivalent- or tetravalent-metal phthalocyanines with alkylchalcogenide ring substituents, and is soluble in at least one organic solvent. This solubility facilitates liquid-processability of the donor material, including formation of thin-films, on an unlimited scale to form planar and bulk heterojunctions in organic OPVs. These donor materials are photovoltaically active in both visible and near-IR wavelengths of light, enabling more of the solar spectrum, for example, to be applied to producing electricity. Also disclosed are methods for producing the metalated phthalocyanines and actual devices.
- Inventors:
- Issue Date:
- Research Org.:
- The Arizona Board of Regents of behalf of the University of Arizona, Tuscon, AZ (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1333818
- Patent Number(s):
- 9,505,770
- Application Number:
- 13/635,324
- Assignee:
- The Arizona Board of Regents of behalf of the University of Arizona (Tuscon, AZ)
- DOE Contract Number:
- SC0001084
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2011 Apr 11
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
McGrath, Dominic V., Mayukh, Mayank, Placencia, Diogenes, and Armstrong, Neal R. Organic photovoltaic devices comprising solution-processed substituted metal-phthalocyanines and exhibiting near-IR photo-sensitivity. United States: N. p., 2016.
Web.
McGrath, Dominic V., Mayukh, Mayank, Placencia, Diogenes, & Armstrong, Neal R. Organic photovoltaic devices comprising solution-processed substituted metal-phthalocyanines and exhibiting near-IR photo-sensitivity. United States.
McGrath, Dominic V., Mayukh, Mayank, Placencia, Diogenes, and Armstrong, Neal R. Tue .
"Organic photovoltaic devices comprising solution-processed substituted metal-phthalocyanines and exhibiting near-IR photo-sensitivity". United States. https://www.osti.gov/servlets/purl/1333818.
@article{osti_1333818,
title = {Organic photovoltaic devices comprising solution-processed substituted metal-phthalocyanines and exhibiting near-IR photo-sensitivity},
author = {McGrath, Dominic V. and Mayukh, Mayank and Placencia, Diogenes and Armstrong, Neal R.},
abstractNote = {Organic photovoltaic (OPV) devices are disclosed. An exemplary device has first and second electrodes and an organic, photovoltaically active zone located between the first and second electrodes. The photovoltaically active zone includes an organic electron-donor material and an organic electron-acceptor material. The electron-donor material includes one or more trivalent- or tetravalent-metal phthalocyanines with alkylchalcogenide ring substituents, and is soluble in at least one organic solvent. This solubility facilitates liquid-processability of the donor material, including formation of thin-films, on an unlimited scale to form planar and bulk heterojunctions in organic OPVs. These donor materials are photovoltaically active in both visible and near-IR wavelengths of light, enabling more of the solar spectrum, for example, to be applied to producing electricity. Also disclosed are methods for producing the metalated phthalocyanines and actual devices.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {11}
}