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Title: Barium iodide and strontium iodide crystals and scintillators implementing the same

Abstract

In one embodiment, a material comprises a crystal comprising strontium iodide providing at least 50,000 photons per MeV, where the strontium iodide material is characterized by a volume not less than 1 cm.sup.3. In another embodiment, a scintillator optic includes europium-doped strontium iodide providing at least 50,000 photons per MeV, where the europium in the crystal is primarily Eu.sup.2+, and the europium is present in an amount greater than about 1.6%. A scintillator radiation detector in yet another embodiment includes a scintillator optic comprising SrI.sub.2 and BaI.sub.2, where a ratio of SrI.sub.2 to BaI.sub.2 is in a range of between 0:1 and 1.0, the scintillator optic is a crystal that provides at least 50,000 scintillation photons per MeV and energy resolution of less than about 5% at 662 keV, and the crystal has a volume of 1 cm.sup.3 or more; the scintillator optic contains more than about 2% europium.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1333729
Patent Number(s):
9507032
Application Number:
14/047,893
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Classifications (CPCs):
C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
G - PHYSICS G21 - NUCLEAR PHYSICS G21K - TECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR
DOE Contract Number:  
AC52-07NA27344
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Oct 07
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Payne, Stephen A., Cherepy, Nerine J., Hull, Giulia E., Drobshoff, Alexander D., and Burger, Arnold. Barium iodide and strontium iodide crystals and scintillators implementing the same. United States: N. p., 2016. Web.
Payne, Stephen A., Cherepy, Nerine J., Hull, Giulia E., Drobshoff, Alexander D., & Burger, Arnold. Barium iodide and strontium iodide crystals and scintillators implementing the same. United States.
Payne, Stephen A., Cherepy, Nerine J., Hull, Giulia E., Drobshoff, Alexander D., and Burger, Arnold. Tue . "Barium iodide and strontium iodide crystals and scintillators implementing the same". United States. https://www.osti.gov/servlets/purl/1333729.
@article{osti_1333729,
title = {Barium iodide and strontium iodide crystals and scintillators implementing the same},
author = {Payne, Stephen A. and Cherepy, Nerine J. and Hull, Giulia E. and Drobshoff, Alexander D. and Burger, Arnold},
abstractNote = {In one embodiment, a material comprises a crystal comprising strontium iodide providing at least 50,000 photons per MeV, where the strontium iodide material is characterized by a volume not less than 1 cm.sup.3. In another embodiment, a scintillator optic includes europium-doped strontium iodide providing at least 50,000 photons per MeV, where the europium in the crystal is primarily Eu.sup.2+, and the europium is present in an amount greater than about 1.6%. A scintillator radiation detector in yet another embodiment includes a scintillator optic comprising SrI.sub.2 and BaI.sub.2, where a ratio of SrI.sub.2 to BaI.sub.2 is in a range of between 0:1 and 1.0, the scintillator optic is a crystal that provides at least 50,000 scintillation photons per MeV and energy resolution of less than about 5% at 662 keV, and the crystal has a volume of 1 cm.sup.3 or more; the scintillator optic contains more than about 2% europium.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {11}
}

Works referenced in this record:

SrI 2 : a novel scintillator crystal for nuclear isotope identifiers
conference, August 2008


Scintillation properties and self absorption in SrI2:Eu2+
conference, October 2010

  • Alekhin, M. S.; de Haas, J. T. M.; Kramer, K. W.
  • 2010 IEEE Nuclear Science Symposium and Medical Imaging Conference (2010 NSS/MIC), IEEE Nuclear Science Symposuim & Medical Imaging Conference
  • https://doi.org/10.1109/NSSMIC.2010.5874044

SrI 2 scintillator for gamma ray spectroscopy
conference, September 2009


Die Kristallstruktur der monoklinen Form von Europium(II)jodid EuJ 2
journal, June 1969


The Crystal Structures of Barium Chloride, Barium Bromide, and Barium Iodide
journal, October 1963


Potential for RbGd2Br7:Ce, LaBr3:Ce, LaBr3:Ce, and LuI3:Ce in nuclear medical imaging
journal, January 2005

  • Moses, William W.; Shah, Kanai S.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 537, Issue 1-2, p. 317-320
  • https://doi.org/10.1016/j.nima.2004.08.034

Luminescence and scintillation properties of the small band gap compound LaI3:Ce3+
journal, January 2005

  • Bessiere, A.; Dorenbos, P.; van Eijk, C. W. E.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 537, Issue 1-2, p. 22-26
  • https://doi.org/10.1016/j.nima.2004.07.224

Scintillation characteristics of thin-film calcium iodide crystal x-ray detectors
journal, August 1998


Heterogeneous Halide-Silica Phosphors
journal, January 1975


CaI2 and CaI2(Eu) Scintillation Crystals
journal, June 1964


Cerium-doped barium halide scintillators for x-ray and γ-ray detections
journal, October 2007


Properties of Yb:YAG scintillators
journal, June 2002

  • Antonini, P.; Belogurov, S.; Bressi, G.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 486, Issue 1-2
  • https://doi.org/10.1016/S0168-9002(02)00706-4

Ce3+ activated LaBr3−xIx: High-light-yield and fast-response mixed halide scintillators
journal, May 2008


Bridgman growth of large SrI2:Eu2+ single crystals: A high-performance scintillator for radiation detection applications
journal, September 2013


Eu2+-doped Ba2CsI5, a new high-performance scintillator
journal, December 2009

  • Bourret-Courchesne, E. D.; Bizarri, G.; Borade, R.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 612, Issue 1, p. 138-142
  • https://doi.org/10.1016/j.nima.2009.10.146

Cerium Activated Scintillation in Yttrium Halides: First Principles Theory and Prediction
journal, June 2009


Scintillators With Potential to Supersede Lanthanum Bromide
journal, June 2009


Strontium and barium iodide high light yield scintillators
journal, February 2008


Ytterbium-based compounds as fast and dense inorganic scintillators
conference, January 2002


Design and Implementation of a Facility for Discovering New Scintillator Materials
journal, June 2008


The quest for the ideal inorganic scintillator
journal, June 2003

  • Derenzo, S. E.; Weber, M. J.; Bourret-Courchesne, E.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 505, Issue 1-2, p. 111-117
  • https://doi.org/10.1016/S0168-9002(03)01031-3

Europium-doped barium bromide iodide
journal, October 2009


Scintillation properties of Eu2+-activated barium fluoroiodide
conference, October 2009

  • Gundiah, G.; Bourret-Courchesne, E.; Bizarri, G.
  • 2009 IEEE Nuclear Science Symposium and Medical Imaging Conference (NSS/MIC 2009), 2009 IEEE Nuclear Science Symposium Conference Record (NSS/MIC)
  • https://doi.org/10.1109/NSSMIC.2009.5402265

Scintillation properties of Eu2+-activated barium fluoroiodide
conference, October 2009

  • Gundiah, G.; Bourret-Courchesne, E.; Bizarri, G.
  • 2009 IEEE Nuclear Science Symposium and Medical Imaging Conference (NSS/MIC 2009), 2009 IEEE Nuclear Science Symposium Conference Record (NSS/MIC)
  • https://doi.org/10.1109/NSSMIC.2009.5402265

Energy transfer in Ba1−xSrxFBr:Eu storage phosphors as a function of Sr and Eu concentration
journal, October 2001


Optical and EPR study of BaY2F8 single crystals doped with Yb
journal, December 2009


Europium-doped barium halide X-ray scintillators
journal, March 2007


Cerium-Doped Orthophosphate Scintillators
journal, January 1994


Irradiation Damage on BaLiF[sub 3] Crystallites and Its Suppression by Rare-Earth Ion Doping
journal, January 1997


Effects of gamma irradiation and air annealing on Yb-doped YAlO 3 single crystals
journal, May 2005


Effects of gamma-irradiation and air annealing on Yb-doped Y3Al5O12 single crystal
journal, March 2008


Laser cooling of Yb3+-doped BaY2F8 single crystal
journal, August 2006


EPR Identification of coupled Yb3+ ion pairs in optically bistable compound CsCdBr3:Yb
journal, July 2001