High energy density aluminum battery

Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

Title: High energy density aluminum battery

Abstract

Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.

Inventors:: Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

Issue Date:: 2016-10-11

Research Org.:: UT-Battelle LLC/ORNL, Oak Ridge, TN (United States); Board of Regents, The University of Texas System, Austin, TX (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1328682

Patent Number(s):: 9466853

Application Number:: 13/247,417

Assignee:: Board of Regents, The University of Texas System (Austin, TX)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0568 - characterised by the solutes
H01M4/38 - of elements or alloys

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0569 - characterised by the solvents
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/058 - Construction or manufacture
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/50 - of manganese
H01M4/463 - {Aluminium based}
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M2300/0028 - characterised by the solvent
H01M6/16 - with organic electrolyte

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DOE Contract Number:: FOA-0000207

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Sep 28

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Brown, Gilbert M., Paranthaman, Mariappan Parans, Dai, Sheng, Dudney, Nancy J., Manthiram, Arumugan, McIntyre, Timothy J., Sun, Xiao-Guang, and Liu, Hansan. High energy density aluminum battery.  United States: N. p., 2016. 
        Web.

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                    Brown, Gilbert M., Paranthaman, Mariappan Parans, Dai, Sheng, Dudney, Nancy J., Manthiram, Arumugan, McIntyre, Timothy J., Sun, Xiao-Guang, & Liu, Hansan. High energy density aluminum battery.  United States.

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                    Brown, Gilbert M., Paranthaman, Mariappan Parans, Dai, Sheng, Dudney, Nancy J., Manthiram, Arumugan, McIntyre, Timothy J., Sun, Xiao-Guang, and Liu, Hansan. Tue .  
        "High energy density aluminum battery".  United States.  https://www.osti.gov/servlets/purl/1328682.

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@article{osti_1328682,

  title        = {High energy density aluminum battery},

  author       = {Brown, Gilbert M. and Paranthaman, Mariappan Parans and Dai, Sheng and Dudney, Nancy J. and Manthiram, Arumugan and McIntyre, Timothy J. and Sun, Xiao-Guang and Liu, Hansan},

  abstractNote = {Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {10}

}

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Works referenced in this record:

Electrochemical study of nickel–aluminium–manganese spinel Ni_xAl_1−xMn₂O₄. Electrocatalytical properties for the oxygen evolution reaction and oxygen reduction reaction in alkaline media
journal, August 2001

Ponce, J.; Rehspringer, J.-L.; Poillerat, G.
Electrochimica Acta, Vol. 46, Issue 22, p. 3373-3380
https://doi.org/10.1016/S0013-4686(01)00530-8

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt
journal, January 1992

Carlin, Richard T.; Crawford, Wayne; Bersch, Michael
Journal of The Electrochemical Society, Vol. 139, Issue 10, p. 2720-2727
https://doi.org/10.1149/1.2068970

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS
journal, January 1990

Dent, Andrew J.; Seddon, Kenneth R.; Welton, Thomas
Journal of the Chemical Society, Chemical Communications, Vol. 0, Issue 4, p. 315-316
https://doi.org/10.1039/C39900000315

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte
journal, January 1988

Gifford, P. R.; Palmisano, J. B.
Journal of The Electrochemical Society, Vol. 135, Issue 3, p. 650-654
https://doi.org/10.1149/1.2095685

Preparation of a new crystal form of manganese dioxide: λ-MnO₂
journal, September 1981

Hunter, James C.
Journal of Solid State Chemistry, Vol. 39, Issue 2, p. 142-147
https://doi.org/10.1016/0022-4596(81)90323-6

Non-conventional electrolytes for electrochemical applications
journal, May 2000

Ito, Yasuhiko; Nohira, Toshiyuki
Electrochimica Acta, Vol. 45, Issue 15-16, p. 2611-2622
https://doi.org/10.1016/S0013-4686(00)00341-8

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl₃)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids
journal, September 2006

Jiang, T.; Chollier Brym, M. J.; Dubé, G.
Surface and Coatings Technology, Vol. 201, Issue 1-2, p. 1-9
https://doi.org/10.1016/j.surfcoat.2005.10.046

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride
journal, July 1988

Lai, P. K.; Skyllas-Kazacos, M.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 248, Issue 2, p. 431-440
https://doi.org/10.1016/0022-0728(88)85103-9

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes
journal, July 1994

Legrand, L.; Tranchant, A.; Messina, R.
Electrochimica Acta, Vol. 39, Issue 10, p. 1427-1431
https://doi.org/10.1016/0013-4686(94)85054-2

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions
journal, January 1996

Legrand, L.; Tranchant, A.; Messina, R.
Inorganic Chemistry, Vol. 35, Issue 5, p. 1310-1312
https://doi.org/10.1021/ic941455q

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

Li, Qingfeng; Bjerrum, Niels J.
Journal of Power Sources, Vol. 110, Issue 1, p. 1-10
https://doi.org/10.1016/S0378-7753(01)01014-X

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves
journal, June 1999

Luan, Zhaohua; Hartmann, Martin; Zhao, Dongyuan
Chemistry of Materials, Vol. 11, Issue 6, p. 1621-1627
https://doi.org/10.1021/cm9900756

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts
journal, January 1990

Melton, Tammy J.; Joyce, Jennifer; Maloy, J. T.
Journal of The Electrochemical Society, Vol. 137, Issue 12, p. 3865-3869
https://doi.org/10.1149/1.2086315

The effect of cosolvents and additives on the electrochemical properties of [(Me)₃PhN][Al₂Cl₇] melts
journal, February 1993

Papageorgiou, Nicholas; Emmenegger, Franz-Peter
Electrochimica Acta, Vol. 38, Issue 2-3, p. 245-252
https://doi.org/10.1016/0013-4686(93)85134-K

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes
journal, May 2008

Peng, Chengxin; Yang, Li; Zhang, Zhengxi
Electrochimica Acta, Vol. 53, Issue 14, p. 4764-4772
https://doi.org/10.1016/j.electacta.2008.01.080

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts
journal, January 1992

Scordilis-Kelley, C.; Fuller, J.; Carlin, R. T.
Journal of The Electrochemical Society, Vol. 139, Issue 3, p. 694-699
https://doi.org/10.1149/1.2069286

Electrochemistry of Room-Temperature Ionic Liquids and Melts
book, January 2009

Tsuda, Tetsuya; Hussey, Charles L.; White, Ralph E.
Modern Aspects of Electrochemistry, Vol. 45, p. 63-174
https://doi.org/10.1007/978-1-4419-0655-7_2

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt
journal, January 2003

Tsuda, Tetsuya; Hussey, Charles L.; Stafford, Gery R.
Journal of The Electrochemical Society, Vol. 150, Issue 4, p. C234-C243
https://doi.org/10.1149/1.1554915

Development of non-flammable lithium secondary battery with ambient-temperature molten salt electrolyte
journal, August 2005

Ui, Koichi; Minami, Takuto; Ishikawa, Kohei
Journal of Power Sources, Vol. 146, Issue 1-2, p. 698-702
https://doi.org/10.1016/j.jpowsour.2005.03.160

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes
journal, January 1993

Vestergaard, B.; Bjerrum, N. J.; Petrushina, I.
Journal of The Electrochemical Society, Vol. 140, Issue 11, p. 3108-3113
https://doi.org/10.1149/1.2220994

Ionic Liquids for Lithium Ion and Related Batteries
book, January 2002

Webber, Andrew; Blomgren, George E.; van Schalkwijk, Walter A.
Advances in Lithium-Ion Batteries, p. 185-232
https://doi.org/10.1007/0-306-47508-1_7

Lithium Batteries and Cathode Materials
journal, October 2004

Whittingham, M. Stanley
Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
https://doi.org/10.1021/cr020731c

Design and analysis of aluminum/air battery system for electric vehicles
journal, October 2002

Yang, Shaohua; Knickle, Harold
Journal of Power Sources, Vol. 112, Issue 1, p. 162-173
https://doi.org/10.1016/S0378-7753(02)00370-1

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports
journal, November 2005

Zeng, Shuangqin; Blanchard, Juliette; Breysse, Michèle
Microporous and Mesoporous Materials, Vol. 85, Issue 3, p. 297-304
https://doi.org/10.1016/j.micromeso.2005.06.031

Novel operation and control of an electric vehicle aluminum/air battery system
journal, April 2004

Zhang, Xin; Yang, Shao Hua; Knickle, Harold
Journal of Power Sources, Vol. 128, Issue 2, p. 331-342
https://doi.org/10.1016/j.jpowsour.2003.09.058

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Similar Records

Title: High energy density aluminum battery

Abstract

Citation Formats

Electrochemical study of nickel–aluminium–manganese spinel NixAl1−xMn2O4. Electrocatalytical properties for the oxygen evolution reaction and oxygen reduction reaction in alkaline media journal, August 2001

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt journal, January 1992

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS journal, January 1990

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte journal, January 1988

Preparation of a new crystal form of manganese dioxide: λ-MnO2 journal, September 1981

Non-conventional electrolytes for electrochemical applications journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl3)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids journal, September 2006

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride journal, July 1988

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes journal, July 1994

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions journal, January 1996

Aluminum as anode for energy storage and conversion: a review journal, July 2002

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves journal, June 1999

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts journal, January 1990

The effect of cosolvents and additives on the electrochemical properties of [(Me)3PhN][Al2Cl7] melts journal, February 1993

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes journal, May 2008

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts journal, January 1992

Electrochemistry of Room-Temperature Ionic Liquids and Melts book, January 2009

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt journal, January 2003

Development of non-flammable lithium secondary battery with ambient-temperature molten salt electrolyte journal, August 2005

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes journal, January 1993

Ionic Liquids for Lithium Ion and Related Batteries book, January 2002

Lithium Batteries and Cathode Materials journal, October 2004

Design and analysis of aluminum/air battery system for electric vehicles journal, October 2002

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports journal, November 2005

Novel operation and control of an electric vehicle aluminum/air battery system journal, April 2004

Electrochemical study of nickel–aluminium–manganese spinel Ni_xAl_1−xMn₂O₄. Electrocatalytical properties for the oxygen evolution reaction and oxygen reduction reaction in alkaline media
journal, August 2001

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt
journal, January 1992

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS
journal, January 1990

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte
journal, January 1988

Preparation of a new crystal form of manganese dioxide: λ-MnO₂
journal, September 1981

Non-conventional electrolytes for electrochemical applications
journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl₃)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids
journal, September 2006

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride
journal, July 1988

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes
journal, July 1994

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions
journal, January 1996

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves
journal, June 1999

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts
journal, January 1990

The effect of cosolvents and additives on the electrochemical properties of [(Me)₃PhN][Al₂Cl₇] melts
journal, February 1993

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes
journal, May 2008

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts
journal, January 1992

Electrochemistry of Room-Temperature Ionic Liquids and Melts
book, January 2009

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt
journal, January 2003

Development of non-flammable lithium secondary battery with ambient-temperature molten salt electrolyte
journal, August 2005

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes
journal, January 1993

Ionic Liquids for Lithium Ion and Related Batteries
book, January 2002

Lithium Batteries and Cathode Materials
journal, October 2004

Design and analysis of aluminum/air battery system for electric vehicles
journal, October 2002

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports
journal, November 2005

Novel operation and control of an electric vehicle aluminum/air battery system
journal, April 2004