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Title: Synthesis of substituted pyrazines

Abstract

A method for synthesizing a pyrazine-containing material according to one embodiment includes contacting an iminodiacetonitrile derivative with a base and a reagent selected from a group consisting of hydroxylamine, a hydroxylamine salt, an aliphatic primary amine, a secondary amine, an aryl-substituted alkylamine a heteroaryl-substituted alkyl amine, an alcohol, an alkanolamine and an aryl alcoholamine. Additional methods and several reaction products are presented. ##STR00001##

Inventors:
;
Issue Date:
Research Org.:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1327969
Patent Number(s):
9458115
Application Number:
12/426,774
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
DOE Contract Number:  
AC52-07NA27344
Resource Type:
Patent
Resource Relation:
Patent File Date: 2009 Apr 20
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Pagoria, Philip F., and Zhang, Mao Xi. Synthesis of substituted pyrazines. United States: N. p., 2016. Web.
Pagoria, Philip F., & Zhang, Mao Xi. Synthesis of substituted pyrazines. United States.
Pagoria, Philip F., and Zhang, Mao Xi. Tue . "Synthesis of substituted pyrazines". United States. https://www.osti.gov/servlets/purl/1327969.
@article{osti_1327969,
title = {Synthesis of substituted pyrazines},
author = {Pagoria, Philip F. and Zhang, Mao Xi},
abstractNote = {A method for synthesizing a pyrazine-containing material according to one embodiment includes contacting an iminodiacetonitrile derivative with a base and a reagent selected from a group consisting of hydroxylamine, a hydroxylamine salt, an aliphatic primary amine, a secondary amine, an aryl-substituted alkylamine a heteroaryl-substituted alkyl amine, an alcohol, an alkanolamine and an aryl alcoholamine. Additional methods and several reaction products are presented. ##STR00001##},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 04 00:00:00 EDT 2016},
month = {Tue Oct 04 00:00:00 EDT 2016}
}

Works referenced in this record:

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The unusually mild and facile basic hydrolysis of N-nitroso-2-(methylamino)acetonitrile
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Theoretical Calculation and Molecular Design for High Explosives: Theoretical Study on Polynitropyrazines and TheirN-oxides
journal, August 2004


New synthesis of 2-amino-6-alkoxypyrazines from N-nitrosobis (cyanomethyl) amine and alkoxides
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Molecular design of analogues of 2,6-diamino-3,5-dinitropyrazine-1-oxide
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MATERIALS SCIENCE: Muscles Made from Metal
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Surface-Stress Induced Macroscopic Bending of Nanoporous Gold Cantilevers
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Charge-Induced Reversible Strain in a Metal
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