Synthesis of substituted pyrazines
Abstract
A method for synthesizing a pyrazine-containing material according to one embodiment includes contacting an iminodiacetonitrile derivative with a base and a reagent selected from a group consisting of hydroxylamine, a hydroxylamine salt, an aliphatic primary amine, a secondary amine, an aryl-substituted alkylamine a heteroaryl-substituted alkyl amine, an alcohol, an alkanolamine and an aryl alcoholamine. Additional methods and several reaction products are presented. ##STR00001##
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1327969
- Patent Number(s):
- 9458115
- Application Number:
- 12/426,774
- Assignee:
- Lawrence Livermore National Security, LLC (Livermore, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2009 Apr 20
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Pagoria, Philip F., and Zhang, Mao Xi. Synthesis of substituted pyrazines. United States: N. p., 2016.
Web.
Pagoria, Philip F., & Zhang, Mao Xi. Synthesis of substituted pyrazines. United States.
Pagoria, Philip F., and Zhang, Mao Xi. Tue .
"Synthesis of substituted pyrazines". United States. https://www.osti.gov/servlets/purl/1327969.
@article{osti_1327969,
title = {Synthesis of substituted pyrazines},
author = {Pagoria, Philip F. and Zhang, Mao Xi},
abstractNote = {A method for synthesizing a pyrazine-containing material according to one embodiment includes contacting an iminodiacetonitrile derivative with a base and a reagent selected from a group consisting of hydroxylamine, a hydroxylamine salt, an aliphatic primary amine, a secondary amine, an aryl-substituted alkylamine a heteroaryl-substituted alkyl amine, an alcohol, an alkanolamine and an aryl alcoholamine. Additional methods and several reaction products are presented. ##STR00001##},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 04 00:00:00 EDT 2016},
month = {Tue Oct 04 00:00:00 EDT 2016}
}
Works referenced in this record:
2-Aminopyrazines and the preparation of 2-aminopyrazines and pyrazines
patent, December 1985
- Brunnmueller, Fritz; Kroener, Michael
- US Patent Document 4,560,756
The unusually mild and facile basic hydrolysis of N-nitroso-2-(methylamino)acetonitrile
journal, November 1976
- Chang, Shaw Kong.; Harrington, George W.; Veale, Harry S.
- The Journal of Organic Chemistry, Vol. 41, Issue 23
Theoretical Calculation and Molecular Design for High Explosives: Theoretical Study on Polynitropyrazines and TheirN-oxides
journal, August 2004
- Li, Jinshan; Huang, Yigang; Dong, Haishan
- Propellants, Explosives, Pyrotechnics, Vol. 29, Issue 4
New synthesis of 2-amino-6-alkoxypyrazines from N-nitrosobis (cyanomethyl) amine and alkoxides
journal, March 1979
- Vohra, Saroj K.; Harrington, George W.; Zacharias, David E.
- The Journal of Organic Chemistry, Vol. 44, Issue 7
Molecular design of analogues of 2,6-diamino-3,5-dinitropyrazine-1-oxide
journal, January 2004
- He, Wendi; Zhou, Ge; Li, Jingshan
- Journal of Molecular Structure: THEOCHEM, Vol. 668, Issue 2-3, p. 201-208
MATERIALS SCIENCE: Muscles Made from Metal
journal, April 2003
- Baughman, R. H.
- Science, Vol. 300, Issue 5617
Surface-Stress Induced Macroscopic Bending of Nanoporous Gold Cantilevers
journal, May 2004
- Kramer, Dominik; Viswanath, Raghavan Nadar; Weissmüller, Jörg
- Nano Letters, Vol. 4, Issue 5
Charge-Induced Reversible Strain in a Metal
journal, April 2003
- Weissmuller, J.
- Science, Vol. 300, Issue 5617