Global to push GA events into
skip to main content

Title: Methods of three-dimensional electrophoretic deposition for ceramic and cermet applications and systems thereof

A ceramic, metal, or cermet according to one embodiment includes a first layer having a gradient in composition, microstructure and/or density in an x-y plane oriented parallel to a plane of deposition of the first layer. A ceramic according to another embodiment includes a plurality of layers comprising particles of a non-cubic material, wherein each layer is characterized by the particles of the non-cubic material being aligned in a common direction. Additional products and methods are also disclosed.
; ;
Issue Date:
OSTI Identifier:
Lawrence Livermore National Security, LLC (Livermore, CA) LLNL
Patent Number(s):
Application Number:
Contract Number:
Resource Relation:
Patent File Date: 2011 Apr 12
Research Org:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org:
Country of Publication:
United States

Works referenced in this record:

Phase Characterization of Partially Stabilized Zirconia by Raman Spectroscopy
journal, August 1985

Enhanced Order of Block Copolymer Cylinders in Single-Layer Films Using a Sweeping Solidification Front
journal, September 2007
  • Angelescu, D. E.; Waller, J. H.; Adamson, D. H.
  • Advanced Materials, Vol. 19, Issue 18, p. 2687-2690
  • DOI: 10.1002/adma.200602904

Electric-field-induced rupture of polymer-stabilized oil films
journal, October 1999
  • Anklam, M. R.; Saville, D. A.; Prud'homme, R. K.
  • Colloid & Polymer Science, Vol. 277, Issue 10, p. 957-964
  • DOI: 10.1007/s003960050475

Contactless Electrofunctionalization of a Single Pore
journal, October 2009
  • Bouchet, Aurélie; Descamps, Emeline; Mailley, Pascal
  • Small, Vol. 5, Issue 20, p. 2297-2303
  • DOI: 10.1002/smll.200900482

Orientational Switching of Mesogens and Microdomains in Hydrogen-Bonded Side-Chain Liquid-Crystalline Block Copolymers Using AC Electric Fields
journal, April 2004
  • Chao, C.-Y.; Li, X.; Ober, C. K.
  • Advanced Functional Materials, Vol. 14, Issue 4, p. 364-370
  • DOI: 10.1002/adfm.200305159

Anisotropic alignment of non-modified BN nanosheets in polysiloxane matrix under nano pulse width electricity
journal, January 2010
  • Cho, Hong-Baek; Shoji, Makoto; Fujiwara, Takesi
  • Journal of the Ceramic Society of Japan, Vol. 118, Issue 1373, p. 66-69
  • DOI: 10.2109/jcersj2.118.66

Microdomain patterns from directional eutectic solidification and epitaxy
journal, May 2000
  • De Rosa, Claudio; Park, Cheolmin; Thomas, Edwin L.
  • Nature, Vol. 405, Issue 6785, p. 433-437
  • DOI: 10.1038/35013018

Microstructure of Side Chain Liquid Crystalline Polymers and their Alignment Using Electric Fields and Surfaces
journal, July 1993
  • Findlay, R. B.
  • Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 231, Issue 1, p. 137-151
  • DOI: 10.1080/10587259308032500

Micro-Flow Control and Micropump by Applying Electric Fields through a Porous Membrane
journal, January 2004
  • Hasegawa, Tomiichi; Toga, Shinji; Morita, Makoto
  • JSME International Journal Series B, Vol. 47, Issue 3, p. 557-563
  • DOI: 10.1299/jsmeb.47.557

Integrated Preconcentration SDS−PAGE of Proteins in Microchips Using Photopatterned Cross-Linked Polyacrylamide Gels
journal, July 2006
  • Hatch, Anson V.; Herr, Amy E.; Throckmorton, Daniel J.
  • Analytical Chemistry, Vol. 78, Issue 14, p. 4976-4984
  • DOI: 10.1021/ac0600454

Reorientation of a liquid crystalline side-chain polymer in electric and magnetic fields investigated by solid-state 1H-NMR
journal, October 1998

Soft porous crystals
journal, November 2009
  • Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu
  • Nature Chemistry, Vol. 1, Issue 9, p. 695-704
  • DOI: 10.1038/nchem.444

Synthesis and characterizations of monodispersed micron-sized polyaniline composite particles for electrorheological fluid materials
journal, August 2002
  • Jun, Jung-Bae; Lee, Chung-Hyuk; Kim, Jin-Woong
  • Colloid & Polymer Science, Vol. 280, Issue 8, p. 744-750
  • DOI: 10.1007/s00396-002-0680-5

Memory effects in liquid crystal elastomers
journal, October 1991
  • Legge, C. H.; Davis, F. J.; Mitchell, G. R.
  • Journal de Physique II, Vol. 1, Issue 10, p. 1253-1261
  • DOI: 10.1051/jp2:1991131

Controlled Deposition of Crystalline Organic Semiconductors for Field-Effect-Transistor Applications
journal, March 2009
  • Liu, Shuhong; Wang, Wechung Maria; Briseno, Alejandro L.
  • Advanced Materials, Vol. 21, Issue 12, p. 1217-1232
  • DOI: 10.1002/adma.200802202

Electric Field Alignment in Thin Films of Cylinder-Forming Diblock Copolymer
journal, August 2006
  • Matsen, M. W.
  • Macromolecules, Vol. 39, Issue 16, p. 5512-5520
  • DOI: 10.1021/ma060456m

Optimization of Electroactive Hydrogel Actuators
journal, December 2009
  • O’Grady, Megan L.; Kuo, Po-ling; Parker, Kevin Kit
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 2, p. 343-346
  • DOI: 10.1021/am900755w

Electrofluorescence of dye-tagged polynucleotides
journal, October 1996

Poly(d,l-lactide)/poly(methyl methacrylate) interpenetrating polymer networks: Synthesis, characterization, and use as precursors to porous polymeric materials
journal, November 2007

Electrooptical properties of a nematic liquid crystal adsorbed in cellulose membrane
journal, March 2000

Electric-Field-Responsive Lithium-Ion Conductors of Propylenecarbonate-Based Columnar Liquid Crystals
journal, April 2009
  • Shimura, Harutoki; Yoshio, Masafumi; Hamasaki, Atsushi
  • Advanced Materials, Vol. 21, Issue 16, p. 1591-1594
  • DOI: 10.1002/adma.200802252

Block Copolymers in Electric Fields: A Comparison of Single-Mode and Self-Consistent-Field Approximations
journal, January 2006
  • Tsori, Yoav; Andelman, David; Lin, Chin-Yet
  • Macromolecules, Vol. 39, Issue 1, p. 289-293
  • DOI: 10.1021/ma051715v

Anisotropic Electrical Transport Properties of Aligned Carbon Nanotube/PMMA Films Obtained by Electric-Field-Assisted Thermal Annealing
journal, November 2008
  • Valentini, Luca; Bon, Silvia Bittolo; Kenny, Josè M.
  • Macromolecular Materials and Engineering, Vol. 293, Issue 11, p. 867-871
  • DOI: 10.1002/mame.200800218

Porous polytetrafluoroethylene (PTFE) electret films: porosity and time dependent charging behavior of the free surface
journal, December 2006
  • Wegener, Michael; Wirges, Werner; Tiersch, Brigitte
  • Journal of Porous Materials, Vol. 14, Issue 1, p. 111-118
  • DOI: 10.1007/s10934-006-9015-0

Orientation and Dynamics of ZnO Nanorod Liquid Crystals in Electric Fields
journal, May 2010
  • Zorn, Matthias; Tahir, Muhammad Nawaz; Bergmann, Björn
  • Macromolecular Rapid Communications, Vol. 31, Issue 12, p. 1101-1107
  • DOI: 10.1002/marc.201000049

Functionally graded microceramic components
journal, May 2010

ZrO2 ceramics with aligned pore structure by EPD and their characterisation by X-ray computed tomography
journal, March 2010

3-D micro-ceramic components from hydrothermally processed carbon nanotube–boehmite powders by electrophoretic deposition
journal, July 2010

Layer-by-layer templated growth of colloidal crystals with packing and pattern control
journal, June 2009
  • Dziomkina, Nina V.; Hempenius, Mark A.; Vancso, G. Julius
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 342, Issue 1-3, p. 8-15
  • DOI: 10.1016/j.colsurfa.2009.03.049

Infiltration of a 3-D Fabric for the Production of SiC/SiC Composites by Means of Electrophoretic Deposition
journal, June 2009

Triply Periodic Bicontinuous Structures as Templates for Photonic Crystals: A Pinch-off Problem
journal, June 2007
  • Moon, J. H.; Xu, Y.; Dan, Y.
  • Advanced Materials, Vol. 19, Issue 11, p. 1510-1514
  • DOI: 10.1002/adma.200700147

Laminated and Functionally Graded Ceramics by Electrophoretic Deposition
journal, January 2007

3D Particle Assembly in Micro-Scale by Using Electrophoretic Micro-Fabrication Technique
journal, January 2006

The control of crystal orientation in ceramics by imposition of a high magnetic field
journal, April 2006
  • Li, Shuqin; Wu, Cunyou; Sassa, Kensuke
  • Materials Science and Engineering: A, Vol. 422, Issue 1-2, p. 227-231
  • DOI: 10.1016/j.msea.2006.02.004

Preparation of zirconia dental crowns via electrophoretic deposition
journal, November 2006
  • Oetzel, Christian; Clasen, Rolf
  • Journal of Materials Science, Vol. 41, Issue 24, p. 8130-8137
  • DOI: 10.1007/s10853-006-0621-7

Investigation on the electrophoretic deposition of a FGM piezoelectric monomorph actuator
journal, January 2003
  • Chen, Y. H.; Li, T.; Ma, J.
  • Journal of Materials Science, Vol. 38, Issue 13, p. 2803-2807
  • DOI: 10.1023/A:1024468015242

Formation process of three-dimensional arrays from silica spheres
journal, May 2003
  • Ishikawa, Keiji; Harada, Hironori; Okubo, Tatsuya
  • AIChE Journal, Vol. 49, Issue 5, p. 1293-1299
  • DOI: 10.1002/aic.690490520

Complex and oriented ZnO nanostructures
journal, November 2003
  • Tian, Zhengrong R.; Voigt, James A.; Liu, Jun
  • Nature Materials, Vol. 2, Issue 12, p. 821-826
  • DOI: 10.1038/nmat1014

Transparent Polycrystalline Alumina Ceramic with Sub-Micrometre Microstructure by Means of Electrophoretic Deposition
journal, April 2006
  • Braun, A.; Falk, G.; Clasen, R.
  • Materialwissenschaft und Werkstofftechnik, Vol. 37, Issue 4, p. 293-297
  • DOI: 10.1002/mawe.200600003

Gradient profile prediction in functionally graded materials processed by electrophoretic deposition
journal, December 2003

Fabrication of Net-Shape Functionally Graded Composites by Electrophoretic Deposition and Sintering: Modeling and Experimentation
journal, October 2007

A review on fundamentals and applications of electrophoretic deposition (EPD)
journal, January 2007

Electrophoretic deposition from aqueous suspensions for near-shape manufacturing of advanced ceramics and glasses—applications
journal, February 2004

Electric-Field-Assisted Assembly of Perpendicularly Oriented Nanorod Superlattices
journal, July 2006
  • Ryan, Kevin M.; Mastroianni, Alex; Stancil, Kimani A.
  • Nano Letters, Vol. 6, Issue 7, p. 1479-1482
  • DOI: 10.1021/nl060866o

Centimetre scale assembly of vertically aligned and close packed semiconductor nanorods from solution
journal, January 2009
  • Ahmed, S.; Ryan, Kevin M.
  • Chemical Communications, Vol. 0, Issue 42, p. 6421-6423
  • DOI: 10.1039/B914478A

The Use of Electrophoretic Deposition for the Fabrication of Ceramic Matrix Composites
journal, January 2004

Electrophoretic Deposition of Ceramic Powders-Influence of Suspension and Processing Parameters
journal, January 2006