Barium iodide and strontium iodide crystals and scintillators implementing the same
Abstract
In one embodiment, a crystal includes at least one metal halide; and an activator dopant comprising ytterbium. In another general embodiment, a scintillator optic includes: at least one metal halide doped with a plurality of activators, the plurality of activators comprising: a first activator comprising europium, and a second activator comprising ytterbium. In yet another general embodiment, a method for manufacturing a crystal suitable for use in a scintillator includes mixing one or more salts with a source of at least one dopant activator comprising ytterbium; heating the mixture above a melting point of the salt(s); and cooling the heated mixture to a temperature below the melting point of the salts. Additional materials, systems, and methods are presented.
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1325007
- Patent Number(s):
- 9441154
- Application Number:
- 14/220,904
- Assignee:
- Lawrence Livermore National Security, LLC (Livermore, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
G - PHYSICS G21 - NUCLEAR PHYSICS G21K - TECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Mar 20
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Payne, Stephen A., Cherepy, Nerine, Pedrini, Christian, and Burger, Arnold. Barium iodide and strontium iodide crystals and scintillators implementing the same. United States: N. p., 2016.
Web.
Payne, Stephen A., Cherepy, Nerine, Pedrini, Christian, & Burger, Arnold. Barium iodide and strontium iodide crystals and scintillators implementing the same. United States.
Payne, Stephen A., Cherepy, Nerine, Pedrini, Christian, and Burger, Arnold. Tue .
"Barium iodide and strontium iodide crystals and scintillators implementing the same". United States. https://www.osti.gov/servlets/purl/1325007.
@article{osti_1325007,
title = {Barium iodide and strontium iodide crystals and scintillators implementing the same},
author = {Payne, Stephen A. and Cherepy, Nerine and Pedrini, Christian and Burger, Arnold},
abstractNote = {In one embodiment, a crystal includes at least one metal halide; and an activator dopant comprising ytterbium. In another general embodiment, a scintillator optic includes: at least one metal halide doped with a plurality of activators, the plurality of activators comprising: a first activator comprising europium, and a second activator comprising ytterbium. In yet another general embodiment, a method for manufacturing a crystal suitable for use in a scintillator includes mixing one or more salts with a source of at least one dopant activator comprising ytterbium; heating the mixture above a melting point of the salt(s); and cooling the heated mixture to a temperature below the melting point of the salts. Additional materials, systems, and methods are presented.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {9}
}
Works referenced in this record:
Optical and EPR study of BaY2F8 single crystals doped with Yb
journal, December 2009
- Kaczmarek, S. M.; Leniec, G.; Typek, J.
- Journal of Luminescence, Vol. 129, Issue 12, p. 1568-1574
Laser cooling of Yb3+-doped BaY2F8 single crystal
journal, August 2006
- Bigotta, Stefano; Parisi, Daniela; Bonelli, Lucia
- Optical Materials, Vol. 28, Issue 11, p. 1321-1324
EPR Identification of coupled Yb3+ ion pairs in optically bistable compound CsCdBr3:Yb
journal, July 2001
- Mehta, V.; Guillot-Noël, O.; Simons, D.
- Journal of Alloys and Compounds, Vol. 323-324, p. 308-311
Die Kristallstruktur der monoklinen Form von Europium(II)jodid EuJ 2
journal, June 1969
- Bärnighausen, H.; Schulz, N.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 6, p. 1104-1110
Luminescence and scintillation properties of the small band gap compound LaI3:Ce3+
journal, January 2005
- Bessiere, A.; Dorenbos, P.; van Eijk, C. W. E.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 537, Issue 1-2, p. 22-26
The Crystal Structures of Barium Chloride, Barium Bromide, and Barium Iodide
journal, October 1963
- Brackett, Elizabeth B.; Brackett, Thomas E.; Sass, Ronald L.
- The Journal of Physical Chemistry, Vol. 67, Issue 10
Determination of Europium(II) and Total Europium in Europium-Activated Lithium Iodide Scintillation Crystals.
journal, September 1964
- Constanzo, D. A.
- Analytical Chemistry, Vol. 36, Issue 10
CaI2 and CaI2(Eu) Scintillation Crystals
journal, June 1964
- Hofstadter, R.; O'Dell, E. W.; Schmidt, C. T.
- IEEE Transactions on Nuclear Science, Vol. 11, Issue 3
Heterogeneous Halide-Silica Phosphors
journal, January 1975
- Lehmann, Willi
- Journal of The Electrochemical Society, Vol. 122, Issue 6
Potential for RbGd2Br7:Ce, LaBr3:Ce, LaBr3:Ce, and LuI3:Ce in nuclear medical imaging
journal, January 2005
- Moses, William W.; Shah, Kanai S.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 537, Issue 1-2, p. 317-320
Scintillation characteristics of thin-film calcium iodide crystal x-ray detectors
journal, August 1998
- Novosad, S. S.
- Technical Physics, Vol. 43, Issue 8
Cerium-doped barium halide scintillators for x-ray and γ-ray detections
journal, October 2007
- Selling, J.; Schweizer, S.; Birowosuto, M. D.
- Journal of Applied Physics, Vol. 102, Issue 7, Article No. 074915
Europium‐doped alkali halides as a selective ultraviolet dosimeter material in the actinic region
journal, April 1991
- Aguirre de Carcer, I.; Lifante, G.; Cussó, F.
- Applied Physics Letters, Vol. 58, Issue 17
Properties of Yb:YAG scintillators
journal, June 2002
- Antonini, P.; Belogurov, S.; Bressi, G.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 486, Issue 1-2
Scintillation properties of Yb-doped yttrium–aluminum garnets
journal, August 2002
- Antonini, P.; Belogurov, S.; Bressi, G.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 488, Issue 3, p. 591-603
Properties of Yb-doped scintillators: YAG, YAP, LuAG
journal, January 2004
- Belogurov, S.; Bressi, G.; Carugno, G.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 516, Issue 1, p. 58-67
Ytterbium-based compounds as fast and dense inorganic scintillators
conference, January 2002
- Chipaux, R.; Cribier, M.; Dujardin, C.
- 2001 IEEE Nuclear Science Symposium Conference Record (Cat. No.01CH37310)
Growth of Yb-doped Y2O3, Sc2O3, and Lu2O3 single crystals by the micro-pulling-down technique and their optical and scintillation characterization
journal, August 2012
- Fukabori, Akihiro; Chani, Valery; Kamada, Kei
- Journal of Crystal Growth, Vol. 352, Issue 1, p. 124-128
Effects of gamma-irradiation and air annealing on Yb-doped Y3Al5O12 single crystal
journal, March 2008
- Zeng, Xionghui; Xu, Xiaodong; Wang, Xiaodan
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 69, Issue 3, p. 860-864
Effects of gamma irradiation and air annealing on Yb-doped YAlO 3 single crystals
journal, May 2005
- Zeng, Xionghui; Zhao, Guangjun; Xu, Jun
- physica status solidi (a), Vol. 202, Issue 6
Irradiation Damage on BaLiF[sub 3] Crystallites and Its Suppression by Rare-Earth Ion Doping
journal, January 1997
- Xia, Chang-Tai
- Journal of The Electrochemical Society, Vol. 144, Issue 10
Cerium-Doped Orthophosphate Scintillators
journal, January 1994
- Wojtowicz, A. J.; Lempicki, A.; Wisniewski, D.
- MRS Proceedings, Vol. 348
A New Lanthanide Activator for Iodide Based Scintillators: <formula formulatype="inline"><tex Notation="TeX">${\hbox {Yb}}^{2+}$</tex></formula>
journal, April 2013
- Rowe, E.; Bhattacharya, P.; Tupitsyn, E.
- IEEE Transactions on Nuclear Science, Vol. 60, Issue 2
Bridgman growth of large SrI2:Eu2+ single crystals: A high-performance scintillator for radiation detection applications
journal, September 2013
- Boatner, L. A.; Ramey, J. O.; Kolopus, J. A.
- Journal of Crystal Growth, Vol. 379, p. 63-68
Scintillation properties of Eu2+-activated barium fluoroiodide
conference, October 2009
- Gundiah, G.; Bourret-Courchesne, E.; Bizarri, G.
- 2009 IEEE Nuclear Science Symposium and Medical Imaging Conference (NSS/MIC 2009), 2009 IEEE Nuclear Science Symposium Conference Record (NSS/MIC)
Eu2+-doped Ba2CsI5, a new high-performance scintillator
journal, December 2009
- Bourret-Courchesne, E. D.; Bizarri, G.; Borade, R.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 612, Issue 1, p. 138-142
Cerium Activated Scintillation in Yttrium Halides: First Principles Theory and Prediction
journal, June 2009
- Boutchko, Rostyslav; Canning, Andrew; Chaudhry, Anurag
- IEEE Transactions on Nuclear Science, Vol. 56, Issue 3
Scintillators With Potential to Supersede Lanthanum Bromide
journal, June 2009
- Cherepy, Nerine J.; Payne, Steve A.; Asztalos, Stephen J.
- IEEE Transactions on Nuclear Science, Vol. 56, Issue 3, p. 873-880
Strontium and barium iodide high light yield scintillators
journal, February 2008
- Cherepy, Nerine J.; Hull, Giulia; Drobshoff, Alexander D.
- Applied Physics Letters, Vol. 92, Issue 8, Article No. 083508
Design and Implementation of a Facility for Discovering New Scintillator Materials
journal, June 2008
- Derenzo, Stephen E.; Boswell, Martin S.; Bourret-Courchesne, Edith
- IEEE Transactions on Nuclear Science, Vol. 55, Issue 3
The quest for the ideal inorganic scintillator
journal, June 2003
- Derenzo, S. E.; Weber, M. J.; Bourret-Courchesne, E.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 505, Issue 1-2, p. 111-117
Europium-doped barium bromide iodide
journal, October 2009
- Gundiah, Gautam; Hanrahan, Stephen M.; Hollander, Frederick J.
- Acta Crystallographica Section E Structure Reports Online, Vol. 65, Issue 11
Scintillation properties of Eu2+-activated barium fluoroiodide
conference, October 2009
- Gundiah, G.; Bourret-Courchesne, E.; Bizarri, G.
- 2009 IEEE Nuclear Science Symposium and Medical Imaging Conference (NSS/MIC 2009), 2009 IEEE Nuclear Science Symposium Conference Record (NSS/MIC)
Energy transfer in Ba1−xSrxFBr:Eu storage phosphors as a function of Sr and Eu concentration
journal, October 2001
- Hackenschmied, P.; Li, H.; Epelbaum, E.
- Radiation Measurements, Vol. 33, Issue 5, p. 669-674
Europium-doped barium halide X-ray scintillators
journal, March 2007
- Selling, J.; Birowosuto, M. D.; Dorenbos, P.
- physica status solidi (c), Vol. 4, Issue 3
Scintillation properties and self absorption in SrI2 :Eu2+
conference, October 2010
- Alekhin, M. S.; de Haas, J. T. M.; Kramer, K. W.
- 2010 IEEE Nuclear Science Symposium and Medical Imaging Conference (2010 NSS/MIC), IEEE Nuclear Science Symposuim & Medical Imaging Conference