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Title: Compositions comprising free-standing two-dimensional nanocrystals


The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.

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Issue Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
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OSTI Identifier:
Patent Number(s):
Application Number:
Drexel University (Philadelphia, PA)
DOE Contract Number:  
Resource Type:
Resource Relation:
Patent File Date: 2015 Oct 13
Country of Publication:
United States

Citation Formats

Barsoum, Michel W., Gogotsi, Yury, Abdelmalak, Michael Naguib, and Mashtalir, Olha. Compositions comprising free-standing two-dimensional nanocrystals. United States: N. p., 2016. Web.
Barsoum, Michel W., Gogotsi, Yury, Abdelmalak, Michael Naguib, & Mashtalir, Olha. Compositions comprising free-standing two-dimensional nanocrystals. United States.
Barsoum, Michel W., Gogotsi, Yury, Abdelmalak, Michael Naguib, and Mashtalir, Olha. Tue . "Compositions comprising free-standing two-dimensional nanocrystals". United States.
title = {Compositions comprising free-standing two-dimensional nanocrystals},
author = {Barsoum, Michel W. and Gogotsi, Yury and Abdelmalak, Michael Naguib and Mashtalir, Olha},
abstractNote = {The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {8}


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Works referenced in this record:

Room-Temperature Deintercalation and Self-Extrusion of Ga from Cr2GaN
journal, May 1999

The Topotactic Transformation of Ti3SiC2 into a Partially Ordered Cubic Ti  (  C 0.67Si0.06 )  Phase by the Diffusion of Si into Molten Cryolite
journal, January 1999

  • Barsoum, M. W.; El‐Raghy, T.; Farber, L.
  • Journal of The Electrochemical Society, Vol. 146, Issue 10, p. 3919-3923
  • DOI: 10.1149/1.1392573

Synthesis and Characterization of a Remarkable Ceramic: Ti3SiC2
journal, July 1996

Synthesis of a new graphene-like transition metal carbide by de-intercalating Ti3AlC2
journal, October 2013

Microstructure and phase transformation of Ti3AC2 (A = Al, Si) in hydrofluoric acid solution
journal, August 2014

  • Chen, Beibei; Chang, Fangyuan; Yang, Jin
  • Crystal Research and Technology, Vol. 49, Issue 10, p. 813-819
  • DOI: 10.1002/crat.201400189

Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
journal, February 2011

The Mn+1AXn phases: Materials science and thin-film processing
journal, February 2010

  • Eklund, Per; Beckers, Manfred; Jansson, Ulf
  • Thin Solid Films, Vol. 518, Issue 8, p. 1851-1878
  • DOI: 10.1016/j.tsf.2009.07.184

Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
journal, November 2014

  • Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang
  • Nature, Vol. 516, Issue 7529
  • DOI: 10.1038/nature13970

Low temperature thermal expansion, high temperature electrical conductivity, and mechanical properties of Nb4AlC3 ceramic synthesized by spark plasma sintering
journal, November 2009

  • Hu, Chunfeng; Sakka, Yoshio; Tanaka, Hidehiko
  • Journal of Alloys and Compounds, Vol. 487, Issue 1-2, p. 675-681
  • DOI: 10.1016/j.jallcom.2009.08.036

MXene: A New Family of Promising Hydrogen Storage Medium
journal, December 2013

  • Hu, Qianku; Sun, Dandan; Wu, Qinghua
  • The Journal of Physical Chemistry A, Vol. 117, Issue 51
  • DOI: 10.1021/jp409585v

Two-dimensional Sc2C: A reversible and high-capacity hydrogen storage material predicted by first-principles calculations
journal, July 2014

  • Hu, Qianku; Wang, Haiyan; Wu, Qinghua
  • International Journal of Hydrogen Energy, Vol. 39, Issue 20, p. 10606-10612
  • DOI: 10.1016/j.ijhydene.2014.05.037

The structure of multilayered titania nanotubes based on delaminated anatase
journal, July 2008

  • Mogilevsky, Gregory; Chen, Qiang; Kleinhammes, Alfred
  • Chemical Physics Letters, Vol. 460, Issue 4-6, p. 517-520
  • DOI: 10.1016/j.cplett.2008.06.063

New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries
journal, October 2013

  • Naguib, Michael; Halim, Joseph; Lu, Jun
  • Journal of the American Chemical Society, Vol. 135, Issue 43
  • DOI: 10.1021/ja405735d

Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011

  • Naguib, Michael; Kurtoglu, Murat; Presser, Volker
  • Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
  • DOI: 10.1002/adma.201102306

Two-Dimensional Transition Metal Carbides
journal, January 2012

  • Naguib, Michael; Mashtalir, Olha; Carle, Joshua
  • ACS Nano, Vol. 6, Issue 2
  • DOI: 10.1021/nn204153h

MXene: a promising transition metal carbide anode for lithium-ion batteries
journal, March 2012

  • Naguib, Michael; Come, Jérémy; Dyatkin, Boris
  • Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64
  • DOI: 10.1016/j.elecom.2012.01.002

25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials
journal, December 2013

  • Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W.
  • Advanced Materials, Vol. 26, Issue 7, p. 992-1005
  • DOI: 10.1002/adma.201304138

Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-Dimensional Titanium Carbide
journal, March 2014

  • Peng, Qiuming; Guo, Jianxin; Zhang, Qingrui
  • Journal of the American Chemical Society, Vol. 136, Issue 11
  • DOI: 10.1021/ja500506k

A study of the synthetic methods and properties of graphenes
journal, October 2010

  • Rao, C. N. R.; Subrahmanyam, K. S.; Ramakrishna Matte, H. S. S.
  • Science and Technology of Advanced Materials, Vol. 11, Issue 5
  • DOI: 10.1088/1468-6996/11/5/054502

Carbon nanoscrolls produced from acceptor-type graphite intercalation compounds
journal, November 2007

  • Savoskin, Michael V.; Mochalin, Vadym N.; Yaroshenko, Alexander P.
  • Carbon, Vol. 45, Issue 14, p. 2797-2800
  • DOI: 10.1016/j.carbon.2007.09.031

XPS studies of amino acids adsorbed on titanium dioxide surfaces
journal, January 1991

  • Schmidt, Martin; Steinemann, Samuel G.
  • Fresenius' Journal of Analytical Chemistry, Vol. 341, Issue 5-6
  • DOI: 10.1007/BF00321947

Vibrational behavior of the M n + 1 A X n phases from first-order Raman scattering ( M = Ti , V , Cr , A = Si , X = C , N )
journal, January 2005

Graphene-based composite materials
journal, July 2006

  • Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B.
  • Nature, Vol. 442, Issue 7100, p. 282-286
  • DOI: 10.1038/nature04969

High-Quality Thin Graphene Films from Fast Electrochemical Exfoliation
journal, February 2011

  • Su, Ching-Yuan; Lu, Ang-Yu; Xu, Yanping
  • ACS Nano, Vol. 5, Issue 3
  • DOI: 10.1021/nn200025p

Lithium Intercalation in Porous Carbon Electrodes
journal, January 1995

The corrosion behavior of Ti3SiC2 in common acids and dilute NaOH
journal, June 2003

Synthesis and Characterization of Ti3AlC2
journal, April 2000

A Chemical Route to Carbon Nanoscrolls
journal, February 2003

Intercalation and exfoliation routes to graphite nanoplatelets
journal, January 2005

  • Viculis, Lisa M.; Mack, Julia J.; Mayer, Oren M.
  • Journal of Materials Chemistry, Vol. 15, Issue 9
  • DOI: 10.1039/B413029D