Hyperhalogens and highly electronegative compositions

Jena, Puru; Gantefoer, Gerd

Title: Hyperhalogens and highly electronegative compositions

Abstract

Hyperhalogens, a new class of highly electronegative species, are now invented. A hyperhalogen is a superhalogen-containing composition in which the electron affinity (EA) of the hyperhalogen is even larger than that of the superhalogens they are composed of. Novel production methods are provided in which highly electronegative species are produced by surrounding a central metal atom by superhalogen moieties.

Inventors:: Jena, Puru; Gantefoer, Gerd

Issue Date:: 2016-08-16

Research Org.:: Virginia Commonwealth Univ., Richmond, VA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1298045

Patent Number(s):: 9416016

Application Number:: 13/820,574

Assignee:: Virginia Commonwealth University (Richmond, VA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B35/127 - {of heavy metals}

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
A61K33/34 - Copper

A - HUMAN NECESSITIES A01 - AGRICULTURE A01N - PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF
A01N59/20 - Copper
A01N59/16 - Heavy metals

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B35/1027 - {Oxides}

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
A61K33/24 - Heavy metals

C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
C09K3/00 - Materials not provided for elsewhere

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DOE Contract Number:: FG02-96ER45579

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Sep 08

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Jena, Puru, and Gantefoer, Gerd. Hyperhalogens and highly electronegative compositions.  United States: N. p., 2016. 
        Web.

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                    Jena, Puru, & Gantefoer, Gerd. Hyperhalogens and highly electronegative compositions.  United States.

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                    Jena, Puru, and Gantefoer, Gerd. Tue .  
        "Hyperhalogens and highly electronegative compositions".  United States.  https://www.osti.gov/servlets/purl/1298045.

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@article{osti_1298045,

  title        = {Hyperhalogens and highly electronegative compositions},

  author       = {Jena, Puru and Gantefoer, Gerd},

  abstractNote = {Hyperhalogens, a new class of highly electronegative species, are now invented. A hyperhalogen is a superhalogen-containing composition in which the electron affinity (EA) of the hyperhalogen is even larger than that of the superhalogens they are composed of. Novel production methods are provided in which highly electronegative species are produced by surrounding a central metal atom by superhalogen moieties.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {8}

}

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Works referenced in this record:

Origin of the Unusual Properties of Au _n (BO ₂ ) Clusters
journal, February 2010

Götz, Matthias; Willis, Mary; Kandalam, Anil K.
ChemPhysChem, Vol. 11, Issue 4
https://doi.org/10.1002/cphc.200901027

Hyperhalogens: Discovery of a New Class of Highly Electronegative Species
journal, October 2010

Willis, Mary; Götz, Matthias; Kandalam, Anil K.
Angewandte Chemie International Edition, Vol. 49, Issue 47, p. 8966-8970
https://doi.org/10.1002/anie.201002212

Structures and photoelectron spectroscopy of Cu _n (BO ₂ ) _m ⁻ ( n, m = 1, 2) clusters: Observation of hyperhalogen behavior
journal, March 2011

Feng, Yuan; Xu, Hong-Guang; Zheng, Weijun
The Journal of Chemical Physics, Vol. 134, Issue 9
https://doi.org/10.1063/1.3556818

Vibrationally Resolved Photoelectron Spectroscopy of BO ^- and BO ₂ ^- : A Joint Experimental and Theoretical Study
journal, February 2007

Zhai, Hua-Jin; Wang, Lei-Ming; Li, Si-Dian
The Journal of Physical Chemistry A, Vol. 111, Issue 6
https://doi.org/10.1021/jp0666939

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Similar Records

Title: Hyperhalogens and highly electronegative compositions

Abstract

Citation Formats

Origin of the Unusual Properties of Au n (BO 2 ) Clusters journal, February 2010

Hyperhalogens: Discovery of a New Class of Highly Electronegative Species journal, October 2010

Structures and photoelectron spectroscopy of Cu n (BO 2 ) m − ( n, m = 1, 2) clusters: Observation of hyperhalogen behavior journal, March 2011

Vibrationally Resolved Photoelectron Spectroscopy of BO - and BO 2 - : A Joint Experimental and Theoretical Study journal, February 2007

Origin of the Unusual Properties of Au _n (BO ₂ ) Clusters
journal, February 2010

Hyperhalogens: Discovery of a New Class of Highly Electronegative Species
journal, October 2010

Structures and photoelectron spectroscopy of Cu _n (BO ₂ ) _m ⁻ ( n, m = 1, 2) clusters: Observation of hyperhalogen behavior
journal, March 2011

Vibrationally Resolved Photoelectron Spectroscopy of BO ^- and BO ₂ ^- : A Joint Experimental and Theoretical Study
journal, February 2007