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Title: Crystalline 1H-1,2,3-triazol-5-ylidenes

The present invention provides novel and stable crystalline 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of making 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of using 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes in catalytic reactions.
Inventors:
; ; ;
Issue Date:
OSTI Identifier:
1281093
Assignee:
The Regents of the University of California (Oakland, CA) CHO
Patent Number(s):
9,403,781
Application Number:
13/643,262
Contract Number:
FG02-09ER16069
Resource Relation:
Patent File Date: 2011 Apr 26
Research Org:
The Regents of the University of California, Oakland, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Works referenced in this record:

Palladium complexes with abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazolium ions and their application in Suzuki coupling
journal, October 2009
  • Karthikeyan, Thandavamurthy; Sankararaman, Sethuraman
  • Tetrahedron Letters, Vol. 50, Issue 42, p. 5834-5837
  • DOI: 10.1016/j.tetlet.2009.08.002

Stability and reactivity of N-heterocyclic carbene complexes
journal, December 2004
  • Crudden, Cathleen M.; Allen, Daryl P.
  • Coordination Chemistry Reviews, Vol. 248, Issue 21-24, p. 2247-2273
  • DOI: 10.1016/j.ccr.2004.05.013