Crystalline 1H-1,2,3-triazol-5-ylidenes

Title: Crystalline 1H-1,2,3-triazol-5-ylidenes

The present invention provides novel and stable crystalline 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of making 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of using 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes in catalytic reactions.

Inventors:: Bertrand, Guy; Gulsado-Barrios, Gregorio; Bouffard, Jean; Donnadieu, Bruno

Issue Date:: 2016-08-02

OSTI Identifier:: 1281093

Assignee:: The Regents of the University of California (Oakland, CA) CHO

Patent Number(s):: 9,403,781

Application Number:: 13/643,262

Contract Number:: FG02-09ER16069

Resource Relation:: Patent File Date: 2011 Apr 26

Research Org:: The Regents of the University of California, Oakland, CA (United States)

Sponsoring Org:: USDOE

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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Other works cited in this record:

Palladium complexes with abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazolium ions and their application in Suzuki coupling
journal, October 2009

Karthikeyan, Thandavamurthy; Sankararaman, Sethuraman
Tetrahedron Letters, Vol. 50, Issue 42, p. 5834-5837
DOI: 10.1016/j.tetlet.2009.08.002

Stability and reactivity of N-heterocyclic carbene complexes
journal, December 2004

Crudden, Cathleen M.; Allen, Daryl P.
Coordination Chemistry Reviews, Vol. 248, Issue 21-24, p. 2247-2273
DOI: 10.1016/j.ccr.2004.05.013

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