Crystalline 1H-1,2,3-triazol-5-ylidenes

Title: Crystalline 1H-1,2,3-triazol-5-ylidenes

Abstract

The present invention provides novel and stable crystalline 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of making 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of using 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes in catalytic reactions.

Inventors:: Bertrand, Guy; Gulsado-Barrios, Gregorio; Bouffard, Jean; Donnadieu, Bruno

Issue Date:: 2016-08-02

Research Org.:: Univ. of California, Oakland, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1281093

Patent Number(s):: 9403781

Application Number:: 13/643,262

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J31/2295 - {Cyclic compounds, e.g. cyclopentadienyls}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D249/06 - with aryl radicals directly attached to ring atoms

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F15/0033 - {Iridium compounds}

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DOE Contract Number:: FG02-09ER16069

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Apr 26

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Bertrand, Guy, Gulsado-Barrios, Gregorio, Bouffard, Jean, and Donnadieu, Bruno. Crystalline 1H-1,2,3-triazol-5-ylidenes.  United States: N. p., 2016. 
        Web.

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                    Bertrand, Guy, Gulsado-Barrios, Gregorio, Bouffard, Jean, & Donnadieu, Bruno. Crystalline 1H-1,2,3-triazol-5-ylidenes.  United States.

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                    Bertrand, Guy, Gulsado-Barrios, Gregorio, Bouffard, Jean, and Donnadieu, Bruno. Tue .  
        "Crystalline 1H-1,2,3-triazol-5-ylidenes".  United States.  https://www.osti.gov/servlets/purl/1281093.

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@article{osti_1281093,

  title        = {Crystalline 1H-1,2,3-triazol-5-ylidenes},

  author       = {Bertrand, Guy and Gulsado-Barrios, Gregorio and Bouffard, Jean and Donnadieu, Bruno},

  abstractNote = {The present invention provides novel and stable crystalline 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of making 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes. The present invention also provides methods of using 1H-1,2,3 triazolium carbenes and metal complexes of 1H-1,2,3 triazolium carbenes in catalytic reactions.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {8}

}

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Works referenced in this record:

Palladium complexes with abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazolium ions and their application in Suzuki coupling
journal, October 2009

Karthikeyan, Thandavamurthy; Sankararaman, Sethuraman
Tetrahedron Letters, Vol. 50, Issue 42, p. 5834-5837
https://doi.org/10.1016/j.tetlet.2009.08.002

1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals
journal, October 2008

Mathew, Paulson; Neels, Antonia; Albrecht, Martin
Journal of the American Chemical Society, Vol. 130, Issue 41
https://doi.org/10.1021/ja805781s

Stability and reactivity of N-heterocyclic carbene complexes
journal, December 2004

Crudden, Cathleen M.; Allen, Daryl P.
Coordination Chemistry Reviews, Vol. 248, Issue 21-24, p. 2247-2273
https://doi.org/10.1016/j.ccr.2004.05.013

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Similar Records

Title: Crystalline 1H-1,2,3-triazol-5-ylidenes

Abstract

Citation Formats

Palladium complexes with abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazolium ions and their application in Suzuki coupling journal, October 2009

1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals journal, October 2008

Stability and reactivity of N-heterocyclic carbene complexes journal, December 2004

Palladium complexes with abnormal N-heterocyclic carbene ligands derived from 1,2,3-triazolium ions and their application in Suzuki coupling
journal, October 2009

1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals
journal, October 2008

Stability and reactivity of N-heterocyclic carbene complexes
journal, December 2004