Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2
Abstract
Flowing supercritical CO.sub.2 is used to activate metal organic framework materials (MOF). MOFs are activated directly from N,N-dimethylformamide (DMF) thus avoiding exchange with a volatile solvent. Most MCPs display increased surface areas directly after treatment although those with coordinatively unsaturated metal centers benefit from additional heating.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Michigan, Ann Arbor, MI (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1264476
- Patent Number(s):
- 9393548
- Application Number:
- 14/139,184
- Assignee:
- The Regents Of The University Of Michigan (Ann Arbor, MI)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- SC0004888
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Dec 23
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Matzger, Adam J., Liu, Baojian, and Wong-Foy, Antek G. Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2. United States: N. p., 2016.
Web.
Matzger, Adam J., Liu, Baojian, & Wong-Foy, Antek G. Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2. United States.
Matzger, Adam J., Liu, Baojian, and Wong-Foy, Antek G. Tue .
"Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2". United States. https://www.osti.gov/servlets/purl/1264476.
@article{osti_1264476,
title = {Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2},
author = {Matzger, Adam J. and Liu, Baojian and Wong-Foy, Antek G.},
abstractNote = {Flowing supercritical CO.sub.2 is used to activate metal organic framework materials (MOF). MOFs are activated directly from N,N-dimethylformamide (DMF) thus avoiding exchange with a volatile solvent. Most MCPs display increased surface areas directly after treatment although those with coordinatively unsaturated metal centers benefit from additional heating.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {7}
}
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