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Title: Ruthenium or osmium complexes and their uses as catalysts for water oxidation

Abstract

The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
The University of North Carolina at Chapel Hill, Chapel Hill, NC (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1256048
Patent Number(s):
9,359,680
Application Number:
14/492,887
Assignee:
The University of North Carolina at Chapel Hill (Chapel Hill, NC)
DOE Contract Number:  
FG02-06ER15788; SC0001011
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Sep 22
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Corbea, Javier Jesus Concepcion, Chen, Zoufeng, Jurss, Jonah Wesley, Templeton, Joseph L., Hoertz, Paul, and Meyer, Thomas J. Ruthenium or osmium complexes and their uses as catalysts for water oxidation. United States: N. p., 2016. Web.
Corbea, Javier Jesus Concepcion, Chen, Zoufeng, Jurss, Jonah Wesley, Templeton, Joseph L., Hoertz, Paul, & Meyer, Thomas J. Ruthenium or osmium complexes and their uses as catalysts for water oxidation. United States.
Corbea, Javier Jesus Concepcion, Chen, Zoufeng, Jurss, Jonah Wesley, Templeton, Joseph L., Hoertz, Paul, and Meyer, Thomas J. Tue . "Ruthenium or osmium complexes and their uses as catalysts for water oxidation". United States. https://www.osti.gov/servlets/purl/1256048.
@article{osti_1256048,
title = {Ruthenium or osmium complexes and their uses as catalysts for water oxidation},
author = {Corbea, Javier Jesus Concepcion and Chen, Zoufeng and Jurss, Jonah Wesley and Templeton, Joseph L. and Hoertz, Paul and Meyer, Thomas J.},
abstractNote = {The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {6}
}

Patent:

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Works referenced in this record:

Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
journal, April 2010

  • Chen, Z.; Concepcion, J. J.; Hu, X.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 16, p. 7225-7229
  • DOI: 10.1073/pnas.1001132107

Single-Site, Catalytic Water Oxidation on Oxide Surfaces
journal, November 2009

  • Chen, Zuofeng; Concepcion, Javier J.; Jurss, Jonah W.
  • Journal of the American Chemical Society, Vol. 131, Issue 43, p. 15580-15581
  • DOI: 10.1021/ja906391w

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts
journal, February 2010

  • Concepcion, Javier J.; Jurss, Jonah W.; Norris, Michael R.
  • Inorganic Chemistry, Vol. 49, Issue 4, p. 1277-1279
  • DOI: 10.1021/ic901437e

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010

  • Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T.
  • Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557
  • DOI: 10.1021/ja904906v

Ruthenium monoterpyridine complexes with 2,6-bis(benzoxazol-2-yl)pyridine as an ancillary ligand: Synthesis, structure and spectral studies
journal, August 2008