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Title: Ruthenium or osmium complexes and their uses as catalysts for water oxidation

The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.
Inventors:
; ; ; ; ;
Issue Date:
OSTI Identifier:
1256048
Assignee:
The University of North Carolina at Chapel Hill (Chapel Hill, NC) CHO
Patent Number(s):
9,359,680
Application Number:
14/492,887
Contract Number:
FG02-06ER15788; SC0001011
Resource Relation:
Patent File Date: 2014 Sep 22
Research Org:
The University of North Carolina at Chapel Hill, Chapel Hill, NC (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Works referenced in this record:

Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
journal, April 2010
  • Chen, Z.; Concepcion, J. J.; Hu, X.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 16, p. 7225-7229
  • DOI: 10.1073/pnas.1001132107

Single-Site, Catalytic Water Oxidation on Oxide Surfaces
journal, November 2009
  • Chen, Zuofeng; Concepcion, Javier J.; Jurss, Jonah W.
  • Journal of the American Chemical Society, Vol. 131, Issue 43, p. 15580-15581
  • DOI: 10.1021/ja906391w

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts
journal, February 2010
  • Concepcion, Javier J.; Jurss, Jonah W.; Norris, Michael R.
  • Inorganic Chemistry, Vol. 49, Issue 4, p. 1277-1279
  • DOI: 10.1021/ic901437e

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010
  • Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T.
  • Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557
  • DOI: 10.1021/ja904906v

Ruthenium monoterpyridine complexes with 2,6-bis(benzoxazol-2-yl)pyridine as an ancillary ligand: Synthesis, structure and spectral studies
journal, August 2008