Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions

Oyola, Yatsandra; Tian, Chengcheng; Bauer, John Christopher; Dai, Sheng

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Title: Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions

Abstract

An acid-functionalized polyolefin material that can be used as an acid catalyst in a wide range of acid-promoted chemical reactions, wherein the acid-functionalized polyolefin material includes a polyolefin backbone on which acid groups are appended. Also described is a method for the preparation of the acid catalyst in which a precursor polyolefin is subjected to ionizing radiation (e.g., electron beam irradiation) of sufficient power and the irradiated precursor polyolefin reacted with at least one vinyl monomer having an acid group thereon. Further described is a method for conducting an acid-promoted chemical reaction, wherein an acid-reactive organic precursor is contacted in liquid form with a solid heterogeneous acid catalyst comprising a polyolefin backbone of at least 1 micron in one dimension and having carboxylic acid groups and either sulfonic acid or phosphoric acid groups appended thereto.

Inventors:: Oyola, Yatsandra; Tian, Chengcheng; Bauer, John Christopher; Dai, Sheng

Issue Date:: 2016-06-07

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1256010

Patent Number(s):: 9359320

Application Number:: 14/032,727

Assignee:: UT-BATTELLE, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D307/48 - Furfural

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Sep 20

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Oyola, Yatsandra, Tian, Chengcheng, Bauer, John Christopher, and Dai, Sheng. Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions.  United States: N. p., 2016. 
        Web.

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                    Oyola, Yatsandra, Tian, Chengcheng, Bauer, John Christopher, & Dai, Sheng. Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions.  United States.

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                    Oyola, Yatsandra, Tian, Chengcheng, Bauer, John Christopher, and Dai, Sheng. Tue .  
        "Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions".  United States.  https://www.osti.gov/servlets/purl/1256010.

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@article{osti_1256010,

  title        = {Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions},

  author       = {Oyola, Yatsandra and Tian, Chengcheng and Bauer, John Christopher and Dai, Sheng},

  abstractNote = {An acid-functionalized polyolefin material that can be used as an acid catalyst in a wide range of acid-promoted chemical reactions, wherein the acid-functionalized polyolefin material includes a polyolefin backbone on which acid groups are appended. Also described is a method for the preparation of the acid catalyst in which a precursor polyolefin is subjected to ionizing radiation (e.g., electron beam irradiation) of sufficient power and the irradiated precursor polyolefin reacted with at least one vinyl monomer having an acid group thereon. Further described is a method for conducting an acid-promoted chemical reaction, wherein an acid-reactive organic precursor is contacted in liquid form with a solid heterogeneous acid catalyst comprising a polyolefin backbone of at least 1 micron in one dimension and having carboxylic acid groups and either sulfonic acid or phosphoric acid groups appended thereto.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {6}

}

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Works referenced in this record:

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Enhanced production of hydroxymethylfurfural from fructose with solid acid catalysts by simple water removal methods
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Covalently linked ethylmercaptophenyl sulfonic acid and ethylmercaptobenzyl sulfonic acid silica materials—Synthesis and catalytic activity
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Environmentally benign, one-pot synthesis of pyrans by domino Knoevenagel/6π-electrocyclization in water and application to natural products
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Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica
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Preparation of hydrophilic amidoxime fibers by cografting acrylonitrile and methacrylic acid from an optimized monomer composition
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Nb₂O₅·nH₂O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites
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Similar Records

Title: Acid-functionalized polyolefin materials and their use in acid-promoted chemical reactions

Abstract

Citation Formats

Atrazine transformation using synthetic enzymes prepared by molecular imprinting journal, January 2004

Synthesis of a cation-exchange fabric with sulfonate groups by radiation-induced graft copolymerization from binary monomer mixtures journal, February 2008

Enhanced production of hydroxymethylfurfural from fructose with solid acid catalysts by simple water removal methods journal, August 2009

Oxidation of alcohols using cerium(IV) alkyl phosphonate modified silica journal, January 2003

Covalently linked ethylmercaptophenyl sulfonic acid and ethylmercaptobenzyl sulfonic acid silica materials—Synthesis and catalytic activity journal, February 2008

Environmentally benign, one-pot synthesis of pyrans by domino Knoevenagel/6π-electrocyclization in water and application to natural products journal, January 2010

Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica journal, May 2003

A new solid acid catalyst: the first phosphonate and phosphonic acid functionalised microporous polysilsesquioxanes journal, January 2001

Preparation of hydrophilic amidoxime fibers by cografting acrylonitrile and methacrylic acid from an optimized monomer composition journal, October 2000

Nb2O5·nH2O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites journal, March 2011

Poly(vinylsulfonic acid)-grafted solid catalysts: new materials for acid-catalysed organic synthetic reactions journal, January 2010

Preparation of a novel poly(vinylsulfonic acid)-grafted solid phase acid catalyst and its use in esterification reactions journal, January 2009

Uranium adsorbing material and process for preparing the same patent, November 1986

Catalytic process for producing furan derivatives in a biphasic reactor patent, August 2009

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Atrazine transformation using synthetic enzymes prepared by molecular imprinting
journal, January 2004

Synthesis of a cation-exchange fabric with sulfonate groups by radiation-induced graft copolymerization from binary monomer mixtures
journal, February 2008

Enhanced production of hydroxymethylfurfural from fructose with solid acid catalysts by simple water removal methods
journal, August 2009

Oxidation of alcohols using cerium(IV) alkyl phosphonate modified silica
journal, January 2003

Covalently linked ethylmercaptophenyl sulfonic acid and ethylmercaptobenzyl sulfonic acid silica materials—Synthesis and catalytic activity
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Environmentally benign, one-pot synthesis of pyrans by domino Knoevenagel/6π-electrocyclization in water and application to natural products
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Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica
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A new solid acid catalyst: the first phosphonate and phosphonic acid functionalised microporous polysilsesquioxanes
journal, January 2001

Preparation of hydrophilic amidoxime fibers by cografting acrylonitrile and methacrylic acid from an optimized monomer composition
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Nb₂O₅·nH₂O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites
journal, March 2011

Poly(vinylsulfonic acid)-grafted solid catalysts: new materials for acid-catalysed organic synthetic reactions
journal, January 2010

Preparation of a novel poly(vinylsulfonic acid)-grafted solid phase acid catalyst and its use in esterification reactions
journal, January 2009

Uranium adsorbing material and process for preparing the same
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Catalytic process for producing furan derivatives in a biphasic reactor
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Functional Filter Medium
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Fiber-Based Adsorbents Having High Adsorption Capacities for Recovering Dissolved Metals and Methods Thereof
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