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Title: Mesoporous metal oxide graphene nanocomposite materials


A nanocomposite material formed of graphene and a mesoporous metal oxide having a demonstrated specific capacity of more than 200 F/g with particular utility when employed in supercapacitor applications. A method for making these nanocomposite materials by first forming a mixture of graphene, a surfactant, and a metal oxide precursor, precipitating the metal oxide precursor with the surfactant from the mixture to form a mesoporous metal oxide. The mesoporous metal oxide is then deposited onto a surface of the graphene.

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Issue Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
OSTI Identifier:
Patent Number(s):
Application Number:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
Resource Type:
Resource Relation:
Patent File Date: 2009 Sep 03
Country of Publication:
United States

Citation Formats

Liu, Jun, Aksay, Ilhan A., Kou, Rong, and Wang, Donghai. Mesoporous metal oxide graphene nanocomposite materials. United States: N. p., 2016. Web.
Liu, Jun, Aksay, Ilhan A., Kou, Rong, & Wang, Donghai. Mesoporous metal oxide graphene nanocomposite materials. United States.
Liu, Jun, Aksay, Ilhan A., Kou, Rong, and Wang, Donghai. Tue . "Mesoporous metal oxide graphene nanocomposite materials". United States.
title = {Mesoporous metal oxide graphene nanocomposite materials},
author = {Liu, Jun and Aksay, Ilhan A. and Kou, Rong and Wang, Donghai},
abstractNote = {A nanocomposite material formed of graphene and a mesoporous metal oxide having a demonstrated specific capacity of more than 200 F/g with particular utility when employed in supercapacitor applications. A method for making these nanocomposite materials by first forming a mixture of graphene, a surfactant, and a metal oxide precursor, precipitating the metal oxide precursor with the surfactant from the mixture to form a mesoporous metal oxide. The mesoporous metal oxide is then deposited onto a surface of the graphene.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {5}


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Works referenced in this record:

Biomimetic Pathways for Assembling Inorganic Thin Films
journal, August 1996

Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005

  • Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
  • Nature Materials, Vol. 4, Issue 5, p. 366-377
  • DOI: 10.1038/nmat1368

TiO2-B Nanowires
journal, April 2004

  • Armstrong, A. Robert; Armstrong, Graham; Canales, Jesús
  • Angewandte Chemie International Edition, Vol. 43, Issue 17, p. 2286-2288
  • DOI: 10.1002/anie.200353571

TiO2(B) Nanowires as an Improved Anode Material for Lithium-Ion Batteries Containing LiFePO4 or LiNi0.5Mn1.5O4 Cathodes and a Polymer Electrolyte
journal, October 2006

  • Armstrong, G.; Armstrong, A. R.; Bruce, P. G.
  • Advanced Materials, Vol. 18, Issue 19, p. 2597-2600
  • DOI: 10.1002/adma.200601232

Periodic mesoporous organosilicas with organic groups inside the channel walls
journal, December 1999

  • Asefa, Tewodros; MacLachlan, Mark J.; Coombs, Neil
  • Nature, Vol. 402, Issue 6764
  • DOI: 10.1038/47229

Self-Assembly of a Nonionic Surfactant at the Graphite/Ionic Liquid Interface
journal, August 2005

  • Atkin, Rob; Warr, Gregory G.
  • Journal of the American Chemical Society, Vol. 127, Issue 34
  • DOI: 10.1021/ja053904z

Mesoporous Platinum Films from Lyotropic Liquid Crystalline Phases
journal, October 1997

Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants
journal, September 1995

Structural evolution during the reaction of Li with nano-sized rutile type TiO2 at room temperature
journal, February 2007

Electronic Confinement and Coherence in Patterned Epitaxial Graphene
journal, May 2006

Purification and size-selection of carbon nanotubes
journal, January 1997

  • Bonard, Jean-Marc; Stora, Thierry; Salvetat, Jean-Paul
  • Advanced Materials, Vol. 9, Issue 10, p. 827-831
  • DOI: 10.1002/adma.19970091014

Semiconducting superlattices templated by molecular assemblies
journal, March 1996

  • Braun, Paul V.; Osenar, Paul; Stupp, Samuel I.
  • Nature, Vol. 380, Issue 6572
  • DOI: 10.1038/380325a0

Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper
journal, July 2008

  • Chen, Haiqun; Müller, Marc B.; Gilmore, Kerry J.
  • Advanced Materials, Vol. 20, Issue 18, p. 3557-3561
  • DOI: 10.1002/adma.200800757

Reducing Carbon in LiFePO[sub 4]/C Composite Electrodes to Maximize Specific Energy, Volumetric Energy, and Tap Density
journal, January 2002

  • Chen, Zhaohui; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 149, Issue 9
  • DOI: 10.1149/1.1498255

Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites
journal, August 1997

Preparation and characterization of graphene oxide paper
journal, July 2007

  • Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J.
  • Nature, Vol. 448, Issue 7152, p. 457-460
  • DOI: 10.1038/nature06016

Impact of the Carbon Coating Thickness on the Electrochemical Performance of LiFePO[sub 4]/C Composites
journal, January 2005

  • Dominko, R.; Bele, M.; Gaberscek, M.
  • Journal of The Electrochemical Society, Vol. 152, Issue 3
  • DOI: 10.1149/1.1860492

RuO2-wired high-rate nanoparticulate TiO2 (anatase): Suppression of particle growth using silica
journal, June 2008

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets
journal, November 2007

  • Gomez-Navarro, Cristina; Weitz, R. Thomas; Bittner, Alexander M.
  • Nano Letters, Vol. 7, Issue 11, p. 3499-3503
  • DOI: 10.1021/nl072090c

Poly(pyrrole) and poly(thiophene)/vanadium oxide interleaved nanocomposites: positive electrodes for lithium batteries
journal, April 1998

Superior Electrode Performance of Nanostructured Mesoporous TiO2 (Anatase) through Efficient Hierarchical Mixed Conducting Networks
journal, August 2007

  • Guo, Y.-G.; Hu, Y.-S.; Sigle, W.
  • Advanced Materials, Vol. 19, Issue 16, p. 2087-2091
  • DOI: 10.1002/adma.200602828

Nano-network electronic conduction in iron and nickel olivine phosphates
journal, February 2004

  • Herle, P. Subramanya; Ellis, B.; Coombs, N.
  • Nature Materials, Vol. 3, Issue 3
  • DOI: 10.1038/nmat1063

High Lithium Electroactivity of Nanometer-Sized Rutile TiO2
journal, June 2006

  • Hu, Y.-S.; Kienle, L.; Guo, Y.-G.
  • Advanced Materials, Vol. 18, Issue 11, p. 1421-1426
  • DOI: 10.1002/adma.200502723

Improved Electrode Performance of Porous LiFePO4 Using RuO2 as an Oxidic Nanoscale Interconnect
journal, August 2007

  • Hu, Y.-S.; Guo, Y.-G.; Dominko, R.
  • Advanced Materials, Vol. 19, Issue 15, p. 1963-1966
  • DOI: 10.1002/adma.200700697

Self-organizing high-density single-walled carbon nanotube arrays from surfactant suspensions
journal, August 2004

Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposite Biphase Arrays
journal, August 1994

  • Huo, Qisheng; Margolese, David I.; Ciesla, Ulrike
  • Chemistry of Materials, Vol. 6, Issue 8
  • DOI: 10.1021/cm00044a016

Nanocrystalline Rutile TiO[sub 2] Electrode for High-Capacity and High-Rate Lithium Storage
journal, January 2007

  • Jiang, Chunhai; Honma, Itaru; Kudo, Tetsuichi
  • Electrochemical and Solid-State Letters, Vol. 10, Issue 5
  • DOI: 10.1149/1.2712041

Nanocrystalline TiO[sub 2] (Anatase) Electrodes: Surface Morphology, Adsorption, and Electrochemical Properties
journal, January 1996

  • Kavan, L.
  • Journal of The Electrochemical Society, Vol. 143, Issue 2
  • DOI: 10.1149/1.1836455

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
journal, October 1992

  • Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.
  • Nature, Vol. 359, Issue 6397, p. 710-712
  • DOI: 10.1038/359710a0

Electrochemical Lithium Intercalation into a Polyaniline/V[sub 2]O[sub 5] Nanocomposite
journal, January 1996

  • Leroux, F.
  • Journal of The Electrochemical Society, Vol. 143, Issue 9
  • DOI: 10.1149/1.1837078

Processable aqueous dispersions of graphene nanosheets
journal, January 2008

Oriented Nanostructures for Energy Conversion and Storage
journal, September 2008

  • Liu, Jun; Cao, Guozhong; Yang, Zhenguo
  • ChemSusChem, Vol. 1, Issue 8-9, p. 676-697
  • DOI: 10.1002/cssc.200800087

Template-Free Synthesis of SnO2 Hollow Nanostructures with High Lithium Storage Capacity
journal, September 2006

  • Lou, X. W.; Wang, Y.; Yuan, C.
  • Advanced Materials, Vol. 18, Issue 17, p. 2325-2329
  • DOI: 10.1002/adma.200600733

Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005

  • Maier, J.
  • Nature Materials, Vol. 4, Issue 11, p. 805-815
  • DOI: 10.1038/nmat1513

Structural, electronic and magnetic properties of manganese doping in the upper layer of bilayer graphene
journal, April 2008

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007

  • McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H.
  • Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404
  • DOI: 10.1021/cm0630800

A Mesoporous Nanocomposite of TiO2 and Carbon Nanotubes as a High-Rate Li-Intercalation Electrode Material
journal, January 2006

  • Moriguchi, I.; Hidaka, R.; Yamada, H.
  • Advanced Materials, Vol. 18, Issue 1, p. 69-73
  • DOI: 10.1002/adma.200501366

Citrate-Derived Carbon Nanocoatings for Poorly Conducting Cathode
journal, January 2006

  • Moskon, J.; Dominko, R.; Gaberscek, M.
  • Journal of The Electrochemical Society, Vol. 153, Issue 10
  • DOI: 10.1149/1.2221864

Graphite Oxide-Intercalated Anionic Clay and Its Decomposition to Graphene−Inorganic Material Nanocomposites
journal, August 2008

  • Nethravathi, C.; Rajamathi, Jacqueline T.; Ravishankar, N.
  • Langmuir, Vol. 24, Issue 15
  • DOI: 10.1021/la8000027

Carbon-coated mesoporous silica with hydrophobicity and electrical conductivity
journal, January 2008

Solution Properties of Graphite and Graphene
journal, June 2006

  • Niyogi, Sandip; Bekyarova, Elena; Itkis, Mikhail E.
  • Journal of the American Chemical Society, Vol. 128, Issue 24
  • DOI: 10.1021/ja060680r

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004

Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Improved electrochemical performance of a LiFePO4-based composite cathode
journal, August 2001

Functionalized graphene sheets for polymer nanocomposites
journal, May 2008

  • Ramanathan, T.; Abdala, A. A.; Stankovich, S.
  • Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331
  • DOI: 10.1038/nnano.2008.96

SnO2-carbon composites for lithium-ion battery anodes
journal, June 2001

Room temperature synthesis and Li insertion into nanocrystalline rutile TiO2
journal, August 2006

  • Reddy, M. Anji; Kishore, M. Satya; Pralong, V.
  • Electrochemistry Communications, Vol. 8, Issue 8, p. 1299-1303
  • DOI: 10.1016/j.elecom.2006.05.021

Supramolecular Self-Assembly of Lipid Derivatives on Carbon Nanotubes
journal, May 2003

Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide
journal, May 2006

  • Schniepp, Hannes C.; Li, Je-Luen; McAllister, Michael J.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 17
  • DOI: 10.1021/jp060936f

Self-Healing of Surfactant Surface Micelles on Millisecond Time Scales
journal, September 2006

  • Schniepp, Hannes C.; Saville, Dudley A.; Aksay, Ilhan A.
  • Journal of the American Chemical Society, Vol. 128, Issue 38
  • DOI: 10.1021/ja0624826

Synthesis of Water Soluble Graphene
journal, June 2008

  • Si, Yongchao; Samulski, Edward T.
  • Nano Letters, Vol. 8, Issue 6
  • DOI: 10.1021/nl080604h

Molecular Dynamics Simulations of Surfactant Self-Organization at a Solid−Liquid Interface
journal, January 2006

  • Srinivas, Goundla; Nielsen, Steven O.; Moore, Preston B.
  • Journal of the American Chemical Society, Vol. 128, Issue 3
  • DOI: 10.1021/ja054846k

Graphene-based composite materials
journal, July 2006

  • Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B.
  • Nature, Vol. 442, Issue 7100, p. 282-286
  • DOI: 10.1038/nature04969

Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate)
journal, January 2006

  • Stankovich, Sasha; Piner, Richard D.; Chen, Xinqi
  • J. Mater. Chem., Vol. 16, Issue 2
  • DOI: 10.1039/B512799H

Graphene-Based Ultracapacitors
journal, October 2008

  • Stoller, Meryl D.; Park, Sungjin; Zhu, Yanwu
  • Nano Letters, Vol. 8, Issue 10
  • DOI: 10.1021/nl802558y

H–T phase diagram and the nature of vortex-glass phase in a quasi-two-dimensional superconductor: Sn-metal layer sandwiched between graphene sheets
journal, February 2004

  • Suzuki, Masatsugu; Suzuki, Itsuko S.; Walter, Jürgen
  • Physica C: Superconductivity, Vol. 402, Issue 3
  • DOI: 10.1016/j.physc.2003.10.001

Characteristics of graphene-layer encapsulated nanoparticles fabricated using laser ablation method
journal, April 2008

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Surface-Mediated Growth of Transparent, Oriented, and Well-Defined Nanocrystalline Anatase Titania Films
journal, October 2006

  • Wang, Donghai; Liu, Jun; Huo, Qisheng
  • Journal of the American Chemical Society, Vol. 128, Issue 42
  • DOI: 10.1021/ja0655993

Low-Temperature Synthesis of Tunable Mesoporous Crystalline Transition Metal Oxides and Applications as Au Catalyst Supports
journal, August 2008

  • Wang, Donghai; Ma, Zhen; Dai, Sheng
  • The Journal of Physical Chemistry C, Vol. 112, Issue 35
  • DOI: 10.1021/jp804250f

Synthesis and Li-Ion Insertion Properties of Highly Crystalline Mesoporous Rutile TiO 2
journal, May 2008

  • Wang, Donghai; Choi, Daiwon; Yang, Zhenguo
  • Chemistry of Materials, Vol. 20, Issue 10
  • DOI: 10.1021/cm8002589

Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene
journal, July 2008

  • Wang, Xinran; Tabakman, Scott M.; Dai, Hongjie
  • Journal of the American Chemical Society, Vol. 130, Issue 26
  • DOI: 10.1021/ja8023059

Graphene−Silica Composite Thin Films as Transparent Conductors
July 2007

  • Watcharotone, Supinda; Dikin, Dmitriy A; Stankovich, Sasha
  • Nano Letters, Vol. 7, Issue 7, p. 1888–1892
  • DOI: 10.1021/nl070477+

Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures
journal, November 1991

TiO 2 -Graphene Nanocomposites. UV-Assisted Photocatalytic Reduction of Graphene Oxide
journal, July 2008

  • Williams, Graeme; Seger, Brian; Kamat, Prashant V.
  • ACS Nano, Vol. 2, Issue 7
  • DOI: 10.1021/nn800251f

Flexible Graphene Films via the Filtration of Water-Soluble Noncovalent Functionalized Graphene Sheets
journal, May 2008

  • Xu, Yuxi; Bai, Hua; Lu, Gewu
  • Journal of the American Chemical Society, Vol. 130, Issue 18
  • DOI: 10.1021/ja800745y

Crystal Phase Control for Titanium Dioxide Films by Direct Deposition in Aqueous Solutions
journal, February 2002

  • Yamabi, Satoshi; Imai, Hiroaki
  • Chemistry of Materials, Vol. 14, Issue 2
  • DOI: 10.1021/cm010559d

Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
journal, November 1998

  • Yang, Peidong; Zhao, Dongyuan; Margolese, David I.
  • Nature, Vol. 396, Issue 6707
  • DOI: 10.1038/24132

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries
journal, August 2008

  • Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji
  • Nano Letters, Vol. 8, Issue 8, p. 2277-2282
  • DOI: 10.1021/nl800957b

Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores
journal, January 1998

Lithium Insertion into TiO[sub 2] Nanotube Prepared by the Hydrothermal Process
journal, January 2003

  • Zhou, Ying-ke; Cao, Lin; Zhang, Fei-bao
  • Journal of The Electrochemical Society, Vol. 150, Issue 9
  • DOI: 10.1149/1.1597883

Pseudocapacitive Lithium Storage in TiO2(B)
journal, March 2005

  • Zukalová, Markéta; Kalbáč, Martin; Kavan, Ladislav
  • Chemistry of Materials, Vol. 17, Issue 5, p. 1248-1255
  • DOI: 10.1021/cm048249t

Magnetically directed self-assembly of submicron spheres with a Fe3O4 nanoparticle shell
journal, February 2002

Surface Modification of Graphene Nanosheets with Gold Nanoparticles: The Role of Oxygen Moieties at Graphene Surface on Gold Nucleation and Growth
journal, October 2009

  • Goncalves, Gil; Marques, Paula A. A. P.; Granadeiro, Carlos M.
  • Chemistry of Materials, Vol. 21, Issue 20
  • DOI: 10.1021/cm901052s

Low-Temperature Solution Processing of Graphene−Carbon Nanotube Hybrid Materials for High-Performance Transparent Conductors
journal, May 2009

  • Tung, Vincent C.; Chen, Li-Min; Allen, Matthew J.
  • Nano Letters, Vol. 9, Issue 5
  • DOI: 10.1021/nl9001525

Microemulsion Syntheses of Sn and SnO[sub 2]-Graphite Nanocomposite Anodes for Li-Ion Batteries
journal, January 2004

  • Wang, Yong; Lee, Jim Yang; Chen, Bing-Hung
  • Journal of The Electrochemical Society, Vol. 151, Issue 4
  • DOI: 10.1149/1.1647571

Self-Assembled TiO 2 –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion
journal, March 2009

  • Wang, Donghai; Choi, Daiwon; Li, Juan
  • ACS Nano, Vol. 3, Issue 4, p. 907-914
  • DOI: 10.1021/nn900150y

Tin Nanoparticle Loaded Graphite Anodes for Li-Ion Battery Applications
journal, January 2004

  • Wang, Yong; Lee, Jim Y.; Deivaraj, Theivanayagam C.
  • Journal of The Electrochemical Society, Vol. 151, Issue 11
  • DOI: 10.1149/1.1799491

Assembly of chemically modified graphene: methods and applications
journal, January 2011

Dispersion of Sn and SnO on carbon anodes
journal, September 2000

Electron Transfer Kinetics of Aquated Fe[sup +3∕+2], Eu[sup +3∕+2], and V[sup +3∕+2] at Carbon Electrodes
journal, January 1993

  • McDermott, Christie Allred
  • Journal of The Electrochemical Society, Vol. 140, Issue 9
  • DOI: 10.1149/1.2220868

Sonochemical Synthesis of Nanostructured Molybdenum Sulfide
journal, June 1998

  • Mdleleni, Millan M.; Hyeon, Taeghwan; Suslick, Kenneth S.
  • Journal of the American Chemical Society, Vol. 120, Issue 24
  • DOI: 10.1021/ja9800333

Structural changes of a pyrolytic graphite surface oxidized by electrochemical and plasma treatment
journal, June 1994

  • Nakahara, Masanori; Sanada, Yuzo
  • Journal of Materials Science, Vol. 29, Issue 12
  • DOI: 10.1007/BF00356662

Thermal Conductivity of Pure and Impure Silicon, Silicon Carbide, and Diamond
journal, December 1964

  • Slack, Glen A.
  • Journal of Applied Physics, Vol. 35, Issue 12
  • DOI: 10.1063/1.1713251

Sonochemical synthesis of amorphous iron
journal, October 1991

  • Suslick, Kenneth S.; Choe, Seok-Burm; Cichowlas, Andrzej A.
  • Nature, Vol. 353, Issue 6343
  • DOI: 10.1038/353414a0

In situ chemical synthesis of SnO2–graphene nanocomposite as anode materials for lithium-ion batteries
journal, October 2009

Mesoporous tin oxides as lithium intercalation anode materials
journal, January 2002

Li-ion batteries from LiFePO4 cathode and anatase/graphene composite anode for stationary energy storage
journal, March 2010

  • Choi, Daiwon; Wang, Donghai; Viswanathan, Vish V.
  • Electrochemistry Communications, Vol. 12, Issue 3, p. 378-381
  • DOI: 10.1016/j.elecom.2009.12.039

Optimized Lithium Iron Phosphate for High-Rate Electrochemical Applications
journal, January 2004

  • Franger, S.; Bourbon, C.; Le Cras, F.
  • Journal of The Electrochemical Society, Vol. 151, Issue 7
  • DOI: 10.1149/1.1758721

Direct synthesis of uniform mesoporous carbons from the carbonization of as-synthesized silica/triblock copolymer nanocomposites
journal, January 2004

Surfactant-Mediated Synthesis of a Novel Nanoporous Carbon−Silica Composite
journal, July 2003

  • Wang, Z. -M.; Hoshinoo, K.; Shishibori, K.
  • Chemistry of Materials, Vol. 15, Issue 15
  • DOI: 10.1021/cm020965c

Electrochemical characteristics of graphite coated with tin-oxide and copper by fluidised-bed chemical vapour deposition
journal, April 2002

Synthesis of hierarchically mesoporous anatase spheres and their application in lithium batteries
journal, January 2006

  • Guo, Yu-Guo; Hu, Yong-Sheng; Maier, Joachim
  • Chemical Communications, Issue 26
  • DOI: 10.1039/B605090E

From graphene to graphite: Electronic structure around the K point
journal, August 2006