Sorohalide scintillators, phosphors, and uses thereof
Abstract
The present invention relates to sorohalide compounds having formula A.sub.3B.sub.2X.sub.9, where A is an alkali metal, B is a rare earth metal, and X is a halogen. Optionally, the sorohalide includes a dopant D. Such undoped and doped sorohalides are useful as scintillation materials or phosphors for any number of uses, including for radiation detectors, solid-state light sources, gamma-ray spectroscopy, medical imaging, and drilling applications.
- Inventors:
- Issue Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1252452
- Patent Number(s):
- 9334444
- Application Number:
- 14/177,737
- Assignee:
- Sandia Corporation (Albuquerque, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
G - PHYSICS G01 - MEASURING G01T - MEASUREMENT OF NUCLEAR OR X-RADIATION
- DOE Contract Number:
- AC04-94AL85000
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Feb 11
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY
Citation Formats
Yang, Pin, Deng, Haoran, Doty, F. Patrick, and Zhou, Xiaowang. Sorohalide scintillators, phosphors, and uses thereof. United States: N. p., 2016.
Web.
Yang, Pin, Deng, Haoran, Doty, F. Patrick, & Zhou, Xiaowang. Sorohalide scintillators, phosphors, and uses thereof. United States.
Yang, Pin, Deng, Haoran, Doty, F. Patrick, and Zhou, Xiaowang. Tue .
"Sorohalide scintillators, phosphors, and uses thereof". United States. https://www.osti.gov/servlets/purl/1252452.
@article{osti_1252452,
title = {Sorohalide scintillators, phosphors, and uses thereof},
author = {Yang, Pin and Deng, Haoran and Doty, F. Patrick and Zhou, Xiaowang},
abstractNote = {The present invention relates to sorohalide compounds having formula A.sub.3B.sub.2X.sub.9, where A is an alkali metal, B is a rare earth metal, and X is a halogen. Optionally, the sorohalide includes a dopant D. Such undoped and doped sorohalides are useful as scintillation materials or phosphors for any number of uses, including for radiation detectors, solid-state light sources, gamma-ray spectroscopy, medical imaging, and drilling applications.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 10 00:00:00 EDT 2016},
month = {Tue May 10 00:00:00 EDT 2016}
}
Works referenced in this record:
Inelastic neutron scattering and optical spectroscopy of Dy3+ single ions and dimers in Cs3Y2Br9:10% Dy3+ and Cs3Dy2Br9
journal, March 1994
- Aebersold, M. A.; Guedel, H. U.; Furrer, A.
- Inorganic Chemistry, Vol. 33, Issue 6
Cooperative Bistability in Dense, Excited Atomic Systems
journal, August 1994
- Hehlen, M. P.; Güdel, H. U.; Shu, Q.
- Physical Review Letters, Vol. 73, Issue 8
Infrared to visible upconversion in Cs3Yb2Cl9:Tm3+
journal, April 1995
- Riedener, Toni; Güdel, Hans U.; Valley, George C.
- Journal of Luminescence, Vol. 63, Issue 5-6, p. 327-337
Near-infrared to visible upconversion in -doped and excited at 1.54 μm
journal, July 1999
- Lüthi, Stefan R.; Pollnau, Markus; Güdel, Hans U.
- Physical Review B, Vol. 60, Issue 1
The Role of Laser Heating in the Intrinsic Optical Bistability of Yb 3+ -Doped Bromide Lattices
journal, November 2000
- Gamelin, Daniel R.; Lüthi, Stefan R.; Güdel, Hans U.
- The Journal of Physical Chemistry B, Vol. 104, Issue 47
Luminescence upconversion mechanisms in Yb3+–Tb3+ systems
journal, December 2001
- Salley, G. M.; Valiente, R.; Guedel, H. U.
- Journal of Luminescence, Vol. 94-95, p. 305-309
Scintillation and luminescence properties of Ce 3+ doped ternary cesium rare-earth halides
journal, March 2007
- Birowosuto, M. D.; Dorenbos, P.; van Eijk, C. W. E.
- physica status solidi (a), Vol. 204, Issue 3
Structure and properties of lanthanide halides
conference, September 2007
- Doty, F. P.; McGregor, Douglas; Harrison, Mark
- Optical Engineering + Applications, SPIE Proceedings
Fracture and deformation behavior of common and novel scintillating single crystals
conference, September 2007
- Findley, K. O.; Johnson, J.; Bahr, D. F.
- Optical Engineering + Applications, SPIE Proceedings
Initial investigation of strengthening agents for lanthanide halide scintillators
conference, September 2007
- Harrison, M. J.; Doty, F. P.
- Optical Engineering + Applications, SPIE Proceedings
Horizontal gradient-freeze growth of InP crystals under controlled pressure
conference, January 1990
- Iseler, G. W.; Clark, H. R.
- International Conference on Indium Phosphide and Related Materials
Yield Strength and Dislocation Mobility of KCl–KBr Solid Solution Single Crystals
journal, July 1977
- Kataoka, Toshihiko; Yamada, Tomoharu
- Japanese Journal of Applied Physics, Vol. 16, Issue 7
Development and characterization of highly efficient new cerium doped rare earth halide scintillator materials
journal, January 2006
- Krämer, K. W.; Dorenbos, P.; Güdel, H. U.
- J. Mater. Chem., Vol. 16, Issue 27
Comparative measurements on LaBr/sub 3/(Ce) and LaCl/sub 3/(Ce) scintillators coupled to PSPMT
journal, August 2005
- Wonho Lee, ; Wehe, D. K.
- IEEE Transactions on Nuclear Science, Vol. 52, Issue 4
Ternary Chlorides and Bromides of the Rare Earth Elements
book, January 1984
- Meyer, Gerd; Hwu, S. -J.; Corbett, J. D.
- Inorganic Synthesis
Growth and characterization of polycrystalline lanthanide halide scintillators
journal, October 2011
- Nagarkar, V. V.; Miller, S. R.; Gelfandbein, V.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 652, Issue 1, p. 271-274
Crystal Growth and Scintillation Properties of <formula formulatype="inline"><tex Notation="TeX">${\rm Cs}_{2}{\rm NaGdBr}_{6}{:}{\rm Ce}^{3+}$</tex></formula>
journal, April 2013
- Pin Yang,
- IEEE Transactions on Nuclear Science, Vol. 60, Issue 2
The Synthesis and Structures of Elpasolite Halide Scintillators
journal, January 2009
- Yang, Pin; Doty, F. Patrick; Rodriguez, Mark A.
- MRS Proceedings, Vol. 1164
Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties
journal, December 2010
- Ye, S.; Xiao, F.; Pan, Y. X.
- Materials Science and Engineering: R: Reports, Vol. 71, Issue 1, p. 1-34
Divalent fluoride doped cerium fluoride scintillator
patent, August 1991
- Anderson, David F.; Sparrow, Robert W.
- US Patent Document 5,039,858
Scintillator crystals and their applications and manufacturing process
patent, August 2002
- Pauwels, Damien; Viana, Bruno; Kahn-Harari, Andree
- US Patent Document 6,437,336
Rare earth doped host materials
patent, March 2004
- Riman, Richard E.; Ballato, John
- US Patent Document 6,699,406
Scintillator crystals and their applications and manufacturing process
patent, November 2004
- Pauwels, Damien; Viana, Bruno; Kahn-Harari, Andree
- US Patent Document 6,818,896
Fluoride single crystal for detecting radiation, scintillator and radiation detector using the single crystal, and method for detecting radiation
patent, June 2006
- Ichinose, Noboru; Shimamura, Kiyoshi; Nakakita, Satoshi
- US Patent Document 7,060,982
Scintillator crystal, method for making same use thereof
patent, June 2006
- Dorenbos, Pieter; Van Eijk, Carel Wilhelm Eduard; Gudel, Hans-Ulrich
- US Patent Document 7,067,815
Scintillator crystals, method for making same, user thereof
patent, June 2006
- Dorenbos, Pieter; Van Eijk, Carel Wilhelm Eduard; Guedel, Hans-Ulrich
- US Patent Document 7,067,816
Scintillator compositions, and related processes and articles of manufacture
patent, August 2006
- Srivastava, Alok Mani; Duclos, Steven Jude; Deng, Qun
- US Patent Document 7,084,403
Very fast doped LaBr3 scintillators and time-of-flight PET
patent, October 2006
- Shah, Kanai S.
- US Patent Document 7,129,494
Scintillator crystals, method for making same, use thereof
patent, June 2007
- Dorenbos, Pieter; Van Eijk, Carel Wilhelm Eduard; Gudel, Hans-Ulrich
- US Patent Document 7,233,006
Scintillator crystals, method for making same, use thereof
patent, July 2007
- Dorenbos, Pieter; Van Eijk, Carel Wilhelm Eduard; Gudel, Hans-Ulrich
- US Patent Document 7,250,609
Scintillator crystals, method for making same, use thereof
patent, January 2009
- Dorenbos, Pieter; Van Eijk, Carel Wilhelm Eduard; Gudel, Hans-Ulrich
- US Patent Document 7,479,637
Scintillator material based on rare earth with a reduced nuclear background
patent, October 2009
- Iltis, Alain
- US Patent Document 7,608,201
Method for preparing rare-earth halide blocks
patent, March 2010
- Iltis, Alain
- US Patent Document 7,670,578
Fracture-resistant lanthanide scintillators
patent, January 2011
- Doty, F. Patrick
- US Patent Document 7,863,572
Preparation of rare-earth halide blocks
patent, September 2011
- Iltis, Alain
- US Patent Document 8,021,636